• Title/Summary/Keyword: crossover/non-crossover

Search Result 84, Processing Time 0.028 seconds

Rheology of hydrophobic-alkali-soluble-emulsions (HASE) and the effects of surfactants

  • Lau, A.K.M.;Tiu, C.;Kealy, T.;Tam, K.C.
    • Korea-Australia Rheology Journal
    • /
    • v.14 no.1
    • /
    • pp.1-9
    • /
    • 2002
  • Steady and dynamic shear properties of two hydrophobically modified alkali soluble emulsions (HASE), NPJI and NPJ2, were experimentally investigated. At the same polymer concentration, NPJ1 is appreciably more viscous and elastic than NPJ2. The high hydrophobicity of NPJ1 allows hydrophobic associations and more junction sites to be created, leading to the formation of a network structure. Under shear deformation, NPJ1 exhibits shear-thinning behaviour as compared with Newtonian characteristics of NPJ2. NPJ1 and NPJ2 exhibit a very high and a low level of elasticity respectively over the frequency range tested. For NPJ1, a crossover frequency appears, which is shifted to lower frequencies and hence, longer relaxation times, as concentration increases. Three different surfactants anionic SDS, cationic CTAB, and non-ionic TX-100 were employed to examine the effects of surfactants on the rheology of HASE. Due to the different ionic behaviour of the surfactant, each type of surfactant imposed different electrostatic interactions on the two HASE polymers. In general, at low surfactant concentration, a gradual increase in viscosity is observed until a maximum is reached, beyond which a continuous reduction of viscosity ensues. Viscosity development is a combined result of HASE-surfactant interactions, accompanied by constant rearrangement of the hydrophobic associative junctions, and electrostatic interactions.

Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances (고분자 연료전지용 세공충진막의 제조 및 연료전지 특성)

  • Choi, Young-Woo;Park, Jin-Soo;Lee, Mi-Soon;Park, Seok-Hee;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.278-281
    • /
    • 2009
  • Proton exchange membrane is the key material for proton exchange membrane fuel cells (PEMFC). Currently widely-used perfluorosulfonic acid membranes have some disadvantages, such as low thermal stability, easy swelling, excessive crossover of methanol and high price etc. Other membranes, including sulfonated polymer, radiation grafted membranes, organic-inorganic hybrids and acid-base blends, do not satisfy the criteria for PEMFC, which set a barrier to the development and commercialization of PEMFC. Pore-filling type proton exchange membrane is a new proton exchange membrane, which is formed by filling porous substrate with electrolytes. Compared with traditional perfluorosulfonic acid membranes, pore-filling type proton exchange membranes have many advantages, such as non- swelling, low methanol permeation, high proton conductivity, low cost and a wide range of materials to choose. In this research, preparation methodology of pore-filling membranes by particularly using all hydrocarbon polymers and fuel cell performances with the membranes are evaluated.

  • PDF

A Study on the Structure of Turbulent non-Premixed Oxy-fuel Flame Using CMC Model-based Simulation (CMC 모델 기반 수치해석을 사용한 순산소 난류확산화염 구조 연구)

  • Kim, Jong-Soo;Sreedhara, S.;Huh, Kang-Yeol;Yang, Won
    • Journal of the Korean Society of Combustion
    • /
    • v.13 no.1
    • /
    • pp.31-43
    • /
    • 2008
  • Oxy-fuel flame has a significantly different structure from that of air-fuel flame because of its high temperature. This study is aimed to find out the difference of the oxy-fuel flame structure in order to understand reaction mechanism closely, which is crucial to design real-scale oxy-fuel combustion system. By examining pictures of counterflow flame and LIF images, we found that oxy-fuel flame had two-zone structure: fuel decomposition region and distributed CO oxidation region. In the oxy-fuel flame, OH radical was distributed intensely through the whole flame due to its higher flame temperature than crossover temperature. For showing those features of the oxy-fuel flame, 1 MW scale IFRF oxy-natural gas burner was simulated by conditional moment closure(CMC) model. Calculation results were compared with experimental data, and showed agreements in trend. In the simulated distributions of fuel decomposition/CO oxidation rates, CO oxidation region was also separated from fuel decomposition zone considerably, which showed the two-zone structure in the oxy-fuel flame.

  • PDF

Mobile ATM: A Generic and flexible network infrastructure for 3G mobile services

  • Jun Li;Roy Yates;Dipankar Raychaudhuri
    • Journal of Communications and Networks
    • /
    • v.2 no.1
    • /
    • pp.35-45
    • /
    • 2000
  • this paper presents the concept of "mobile ATM', a proposal for third-generation (3G) mobile communication network infrastructure capable of supporting flexible evolution of radio technologies from today's cellular and data services towards future wireless multimedia services. Mobile ATM provides generic mobility management and QoS-based transport capabilities suitable for integration of multiple radio access technologies including cellular voice. wireless data, and future broadband wireless services. The architecture of a mobile ATM network is outlined in terms of the newly-defined "W-UNI" interface at the radio link and "M-UNI"and "M-UNI" interface which supports unified access for WATM and non-ATM mobile terminals through corresponding interworking functions (IWF) is explained. leading to an understanding of how different radio access technologies are supported by the same ATM-based core network infrastructure. Generic mechanisms for handoff and location management within the core mobile network are discussed. and related protocol extensions over the "W-UNI" and "M-UNI/NNI"interfaces are proposed. the issue of "crossover switch (COS)" selection in mobile ATM is considered, and a unified handoff signaling syntax which supports flexibility in COS selection is described. Typical signaling sequences for call connection and handoff using the proposed protocols are outlined. Experimental results form a proof-of-concept mobile ATM network prototype are presented in conclusion.

  • PDF

Current status and prospects of the meiosis-specific function of recombinase in plants (식물의 감수분열에서 상동 재조합 효소 특이 기능의 연구현황 및 전망)

  • Jung, Yu Jin;Nam, Ki Hong;Kim, Tae Sung;Lee, In Hae;Cho, Yong-Gu;Kang, Kwon Kyoo
    • Journal of Plant Biotechnology
    • /
    • v.45 no.1
    • /
    • pp.1-8
    • /
    • 2018
  • Meiosis is a specialized cell division, essential in most reproducing organisms to halve the number of chromosomes, thereby enabling the restoration of ploidy levels during fertilization. A key step in meiosis is homologous recombination, which promotes homologous pairing and generates crossovers (COs) to connect homologous chromosomes until their separation at anaphase I. These CO sites, seen cytologically as chiasmata, represent a reciprocal exchange of genetic information between two homologous non-sister chromatids. RAD51, the eukaryotic homolog of the bacterial RecA recombinase, plays a central role in homologous recombination (HR) in yeast and animals. Loss of RAD51 function causes lethality in the flowering plant, Arabidopsis thaliana, suggesting that RAD51 has a meiotic stage-specific function that is different from homologous pairing activity.

A MULTIOBJECTIVE MODEL OF WHOLESALER-RETAILERS' PROBLEM VIA GENETIC ALGORITHM

  • MAHAPATRA NIRMAL KUMAR;BHUNIA ASOKE KUMAR;MAITI MANORANJAN
    • Journal of applied mathematics & informatics
    • /
    • v.19 no.1_2
    • /
    • pp.397-414
    • /
    • 2005
  • In the existing literature, most of the purchasing models were developed only for retailers problem ignoring the constraint of storage capacity of retailers shop/showroom. In this paper, we have developed a deterministic model of wholesaler-retailers' problem of single product. The storage capacity of wholesaler's warehouse/showroom and retailers' showroom/shop are assumed to be finite. The items are transported from wholesaler's warehouse to retailers' Own Warehouse (OW) in a lot. The customer's demand is assumed to be displayed inventory level dependent. Demands are met from OW and that spaces of OW will immediately be filled by shifting the same amount from the Rented Warehouse (RW) till the RW is empty. The time duration between selling from OW and filling up its space by new ones from RW is negligible. According to relative size of the retailers' existing (own) warehouse capacity and the demand factors, different scenarios are identified. Our objectives are to optimize the cost functions of wholesaler and two retailers separately. To solve this problem, a real coded Genetic Algorithm (GA) with roulette wheel selection/reproduction, whole arithmetic crossover and non-uniform mutation is developed. Finally a numerical example is presented to illustrate the results for different scenarios. To compare the results of GA, Generalised Reduced Gradient Method has been used for the problem. Also, a sensitivity analysis has been performed to study the variations of the optimal average cost with respect to the different parameters.

Effects of Simulation on Nursing Students' Knowledge, Clinical Reasoning, and Self-confidence: A Quasi-experimental Study

  • Kim, Ji Young;Kim, Eun Jung
    • Korean Journal of Adult Nursing
    • /
    • v.27 no.5
    • /
    • pp.604-611
    • /
    • 2015
  • Purpose: Knowledge, clinical reasoning, and self-confidence are the basis for undergraduate education, and determine students' level of competence. The purpose of this study was to assess the effects of the addition of a one-time simulation experience to the didactic curriculum on nursing students' knowledge acquisition, clinical reasoning skill, and self-confidence. Methods: Using a quasi-experimental crossover design consisted of intervention and wait-list control groups. Participants were non-randomly assigned to the first intervention group (Group A, n=48) or the wait-list control group (Group B, n=46). Knowledge level was assessed through a multiple choice written test, and clinical reasoning skill was measured using a nursing process model-based rubric. Self-confidence was measured using a self-reported questionnaire. Results: Results indicated that students in the simulation group scored significantly higher on clinical reasoning skill and related knowledge than those in the didactic lecture group; no difference was found for self-confidence. Conclusion: Findings suggest that undergraduate nursing education requires a simulation-based curriculum for clinical reasoning development and knowledge acquisition.

A Genetic Algorithm to Solve the Optimum Location Problem for Surveillance Sensors

  • Kim, NamHoon;Kim, Sang-Pil;Kim, Mi-Kyeong;Sohn, Hong-Gyoo
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
    • /
    • v.34 no.6
    • /
    • pp.547-557
    • /
    • 2016
  • Due to threats caused by social disasters, operating surveillance devices are essential for social safety. CCTV, infrared cameras and other surveillance equipment are used to observe threats. This research proposes a method for searching for the optimum location of surveillance sensors. A GA (Genetic Algorithm) was used, since this algorithm is one of the most reasonable and efficient methods for solving complex non-linear problems. The sensor specifications, a DEM (Digital Elevation Model) and VITD (Vector Product Interim Terrain Data) maps were used for input data. We designed a chromosome using the sensor pixel location, and used elitism selection and uniform crossover for searching final solution. A fitness function was derived by the number of detected pixels on the borderline and the sum of the detection probability in the surveillance zone. The results of a 5-sensor and a 10-sensor were compared and analyzed.

Evaluation of bioequivalence of two enrofloxacin formulations after intramuscular administration in goats

  • Aboubakr, Mohamed Hafez
    • Korean Journal of Veterinary Research
    • /
    • v.53 no.2
    • /
    • pp.77-82
    • /
    • 2013
  • The present study was planned to evaluate the bioequivalence of two commercial formulations of enrofloxacin, which have been marketed as 10% injectable solution after intramuscular administration at a single dose of 2.5 mg/kg body weight to 12 clinically healthy goats The study was carried out on the basis of crossover design. The two formulations were: Baytril as a reference product and Spectrama Vet as a test product. The plasma concentrations of enrofloxacin were measured by high performance liquid chromatography (HPLC) with UV detector. The pharmacokinetics of that data was performed using non-compartmental analysis. The maximum plasma concentration ($C_{max}$), time to reach peak concentration ($T_{max}$), area under concentration-time curve (AUC), elimination half-life ($t_{0.5el}$) were 1.14 and $1.05{\mu}g/mL$, 0.79 and 0.83 h, 5.70 and $5.79{\mu}g.h/mL$, 5.19 and 5.39 h for Baytril and Spectrama Vet, respectively. The 90% confidence interval for the mean ratio of $T_{max}$, $C_{max}$ and AUC were 94.72-116.2, 87.88-97.16 and 86.44-118.72%, respectively. These values falls within the European Medicines Agency bioequivalence acceptance range of 80-125% for both $T_{max}$ and AUC and between 75-133% for $C_{max}$. In conclusion, Spectrama-Vet is bioequivalent to Baytril and both products can be used as interchangeable drug in veterinary medicine practice.

Effects of Phytate and Calcium on the Reabsorption of Endogenous Zinc in Zinc-Depleted Bats

  • Sook, Kwun-In;Oberleas Donald
    • Journal of Nutrition and Health
    • /
    • v.30 no.4
    • /
    • pp.394-405
    • /
    • 1997
  • Endogenous zinc is important for maintaining zinc homeostasis because the size of endogenous zinc pool is almost 3-4 times bigger than that of dietary zinc. The purpose of this study was to examine the phytate effect on the reabsorption of endogenous zinc and the additional Ca effect on the phytate effect. Rats were fed a casein-based diet with added sodium phytate containing either high(1.6%) or low(0.8%) Ca concentrations for 4 weeks to reduce the body zinc pool. After the depletion period, $^{65}$ Zn was given by intraperitoneal injection to label the endogenous zinc pool. Rats were then assigned into phytate or non-phytate group within the same Ca group. feces were collected for 2 weeks of the initial collection period and 1 week after dietary crossover. The ratios of excreted fecal $^{65}$ Zn radioactivity of phytate group non-phytate group were determined as a measure of the phytate effect on the endogenous zinc. Mean fecal $^{65}$ Zn radioactivity was higher in the phytate group than in the non-phytate group during the entire 3 weeks of the collection period in the low Ca group, and during the initial collection period in the high Ca group(p <0.0001). This study showed an adverse phytate effect on endogenous zinc at both high and low dietary Ca levels. Elevated dietary Ca levels showed a synergistic effect on the phytate effect on endogenous zinc(p <0.05). These results imply greater phytate effect on zinc homeostasis rather than on zinc bioavailability through complexing with the endogenous zinc which is larger portion than the dietary zinc on zinc homeostasis.

  • PDF