• Title/Summary/Keyword: critical temperature.

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Numerical Simulation of CNTs Based Solid State Hydrogen Storage System (탄소나노튜브 기반의 고체수소저장시스템에 관한 전산해석)

  • Kim, Sang-Gon;HwangBo, Chi-Hyung;Yu, Chul Hee;Nahm, Kee-Suk;Im, Yeon-Ho
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.644-651
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    • 2011
  • Storing hydrogen in solid state hydride is one of the best promising methods for the future hydrogen economy. The total performance of such systems depends on the rate at which the amount of mass and heat migration is supplied to solid hydride. Therefore, an accurate modeling of the heat and mass transfer is of prime importance in optimizing the design of such systems. In this work, Hydrogen storage in Pt-CNTs hydrogen reactor has been intensively investigated by solving 2 dimensional mathematical models. Using a CFD computer software, systematic studies have been performed to elucidate the effect of heat and mass transfer during hydrogen charging periods. It was revealed that the optimized design of hydrogen storage vessel can prevent the increase of system temperature and the charging time due to the convective cooling effects inside the vessels at even high charging pressure. Because none has reported the critical issues of heat and mass transfer for CNT based hydrogen storage system, this work can support the first insight of the optimal design for solid state hydrogen storage system based on CNT in the near future.

Experimental Study of Pool Boiling for Enhancing the Boiling Heat Transfer by Hydrophobic Dots on Silicon Surface (실리콘 표면 위에 소수성 점을 이용한 비등 열전달 증진에 관한 실험적 연구)

  • Jo, Hang-Jin;Kim, Hyung-Mo;Ahn, Ho-Seon;Kang, Soon-Ho;Kim, Joon-Won;Shin, Jeong-Seob;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.6
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    • pp.655-663
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    • 2010
  • Wettability is important to enhance not only CHF but also nucleate boiling heat transfer, as shown by the results of different kinds of boiling experiments. In this regard, an excellent boiling performance (a high CHF and heat transfer performance) could be achieved in the case of pool boiling by some favorable surface modifications that can satisfy the optimized wettability condition. To determine the optimized boiling condition, we design special heaters to examine how two materials, which have different wettabilities (e.g., hydrophilic and hydrophobic materials), affect the boiling phenomena. The special heaters have hydrophobic dots on a hydrophilic surface. The contact angle of the hydrophobic surface is $120^{\circ}$ to water at the room temperature. The contact angle of the hydrophilic surface is $60^{\circ}$ at same conditions. Experiments involving micro hydrophobic dots and two types of milli hydrophobic dots are performed, and the results are compared with a reference surface.

Color and Carotenoid Changes During Storage of Dried Red Pepper (건조(乾燥) 고추 저장(貯藏) 중(中)의 변색(變色)에 관(關)한 연구(硏究))

  • Kim, Dong-Youn;Rhee, Chong-Ouk
    • Korean Journal of Food Science and Technology
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    • v.12 no.1
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    • pp.53-58
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    • 1980
  • The effects of water activity, oxygen, light and storage temperature on the color degradation of dried red pepper were investigated during storage. Some packing materials were used for improving the storage life of red pepper by minimizing those factors. The results obtained were summarized as follows: 1. The critical water activity to the capsanthin of red pepper was 0.75. 2. Color degradation of dried red pepper was the most severe by U.V. light among 100 watt infra-red lamp, 15 watt U.V. lamp and 200 watt glow lamp. 3. Effect of light was not significant in the presence of nitrogen, Main factor of color degradation of red pepper in storage appeared spontaneous oxidation by the existence of oxygen. 4. The capsanthin content and the lightness as hunter value in powder type storage of red pepper was higher than that in whole pod type during 3 month's storage. 5. The air and damp-proof packing materials showed better results than polyethylene film packing in capsanthin content and lightness during 3 month's storage.

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Crystal growth and transport current properties of cylindrical (YSmNd)-Ba-Cu-O superconductors by zone melt growth method (존멜팅법을 이용한 원통형 (YSmNd)-Ba-Cu-O계 초전도체의 결정성장 및 수송 전류 특성)

  • Kim, So-Jung;Park, Jong-Kuk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.5
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    • pp.199-204
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    • 2011
  • $(YSmNd)_{1.8}Ba_{2.4}Cu_{3.4}O_{7-x}$ [(YSN)1.8] high $T_c$ superconductor was directionally grown by zone melt growth process, in air atmosphere. In this study, optimum melting temperature and growth rate were $1100^{\circ}C$ and 3.5 mm/hr, respectively. The microstructure of well-textured (YSN)1.8 samples were examined by XRD, optical microscopy, TEM and SQUID magnetometer. The critical current density of these samples were measured by the direct transporting current method. In the observation using an optical microscopy, nonsuperconducting $(YSmNd)_2BaCuO_5$[(YSN)211] inclusions of (YSN)1.8 superconductor uniformly distributed within the superconducting (YSmNd)$Ba_2Cu_3O_x$[(YSN)123] matrix. The directionally melt-textured (YSN)1.8 superconductor showed an onset $T_c{\geq}90\;K$ and sharp superconducting transition. The transport $J_c$ values were 830 A and $3.93{\times}10^4$ (A/$cm^2$) at 77 K self-field, respectively.

Properties of the Flowability and Strength of Cementless Alkali-Activated Mortar Using the Mixed Fly Ash and Ground Granulated Blast-Furnace Slag (플라이애쉬와 고로슬래그 미분말의 혼합 사용한 무시멘트 알칼리 활성 모르터의 유동성 및 강도 특성)

  • Koh, Kyung-Taek;Ryu, Gum-Sung;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.114-121
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    • 2010
  • Portland cement production is under critical review due to high amount of CO2 gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated ground granulated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/ blast furnace slag tand curing condition on the flowability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/blast furnace slag always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% ground granulated blast furnace slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

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Heat Stress Assessment and the Establishment of a Forecast System to Provide Thermophysiological Indices for Harbor Workers in Summer (하계 항만열환경정보 제공을 위한 열환경 평가 및 예보시스템 구축)

  • Hwang, Mi-Kyoung;Yun, Jinah;Kim, Hyunsu;Kim, Young-Jun;Lim, Yeon-Ju;Lee, Young-Mi;Kim, Youngnam;Yoon, Euikyung;Kim, Yoo-Keun
    • Journal of Environmental Health Sciences
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    • v.42 no.2
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    • pp.92-101
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    • 2016
  • Objectives: Outdoor workers are exposed to thermally stressful work environments. In this study, heat stress indices for harbor workers in summer were calculated to evaluate thermal comfort based on a human heat balance model. These indices are Physiological Subjective Temperature (PST), Dehydration Risk (DhR), and Overheating Risk (OhR) according to respective stage of cargo work in a harbor. In addition, we constructed a forecast system to provide heat stress information. Methods: Thermophysiological indices in this study were calculated using the MENEX model (i.e. the human heat balance model), which used as inputs the meteorological parameters, clothing insulation, and metabolic rate for each stage of cargo work in the harbor of Masan over the course of seven days, including a four-day heat wave. The forecast heat stress information constructed for Masan harbor was based on meteorological data supported by the Dong-Nae Forecast from the KMA (Korea Metrological Administration) and other input parameters. Results: According to higher metabolic rate, thermophysiological indices showed a critical level. In particular, PST was evaluated as reaching the 'Very hot' or 'Hot' level during all seven days, despite the heat occurring over only four. It is important in a regard to consider the work environment conditions (i.e. labor intensity and clothing in harbor). On a webpage, the forecast thermophysiological indices show as infographics to be easily understand. This webpage is comprised of indices for both current conditions and the forecast, with brief guidance. Conclusion: Thermophysiological indices show the risk level to health during a heat wave period. Heat stress information could help to protect the health of harbor workers. Further, this study could extend the applicability of these indices to a variety of outdoor workers in consideration of work environments.

Prediction of Potential Distributions of Two Invasive Alien Plants, Paspalum distichum and Ambrosia artemisiifolia, Using Species Distribution Model in Korean Peninsula (한반도에서 종 분포 모델을 이용한 두 침입외래식물, 돼지풀과 물참새피의 잠재적 분포 예측)

  • Lee, SeungHyun;Cho, Kang-Hyun;Lee, Woojoo
    • Ecology and Resilient Infrastructure
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    • v.3 no.3
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    • pp.189-200
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    • 2016
  • The species distribution model would be a useful tool for understanding how invasive alien species spread over the country and what environmental variables contribute to their distributions. This study is focused on the potential distribution of two invasive alien species, the common ragweed (Ambrosia artemisiifolia) and knotgrass (Paspalum distichum) in the Korean Peninsula. The maximum entropy (Maxent) model was used for the prediction of their distribution by inferring their climatic environmental requirements from localities where they are currently known to occur. We obtained their presence data from the Global Biodiversity Information Facility and the Korean plant species databases and bioclimatic data from the WorldClim dataset. As a results of the modelling, the potential distribution predicted by global occurrence data was more accurate than that by native occurrence data. The variables determining the common ragweed distribution were precipitation of the driest month and annual mean temperature. Both annual and the coldest quarter mean temperatures were critical factors in determining the knotgrass distribution. The Maxent model could be a useful tool for the prediction of alien species invasion and the management of their expansion.

Dystrophin Degradation in Skeletal Muscles with Lipid Enrichment in Cattle (지방 침착률이 높은 식용소에서 나타난 골격근의 디스트로핀 소실)

  • Jeon, Sung-Hwan;Kim, Ah-Young;Lee, Eun-Mi;Lee, Eun-Joo;Hong, Il-Hwa;Hwang, Ok-Kyung;Jeong, Kyu-Shik
    • Journal of Life Science
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    • v.26 no.5
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    • pp.592-602
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    • 2016
  • This study investigated the muscular dystrophin levels in freely moving Australian cattle mainly fed grass, freely moving Korean cattle fed mainly a grain diet, and Korean cattle fed a grain diet but housed in a relatively limited space of a cow house. The total skeletal muscle specimens of 244 cattle were collected and immediately fixed in 10% neutral formalin. The same area was biopsied from the cattle in both countries. The findings showed that fatty infiltration is highly correlated with membrane-associated protein degradation in skeletal muscle, and that among several membrane-associated proteins, dystrophin showed the most significant reduction in expression in the cattle with fatty infiltration. Similarly, CD36 was more highly expressed in the cattle with fatty infiltration of skeletal muscle. Various breeding factors, such as oxidative stress; the presence of oxidized lipids in the diet; and environmental factors such as exercise, temperature and amount of time spent, may have critical effects on the degradation of normal cytoskeleton proteins, which are required for maintaining normal skeletal muscle architecture. Among the sarcolemma membrane-associated proteins, dystrophin is the most sensitive membrane protein that is involved muscular dystrophy and muscular degeneration. Thus, the present findings may be useful for studies on muscular dystrophy in humans or the pathogenesis of muscular diseases in animal models.

Histopathological observation of liver in cultured black rock fish Sebastes schlegeli in low temperature season (저수온기 양식 조피볼락, Sebastes schlegeli 간에 대한 조직병리학적 연구)

  • Choi, Hye-Sung;Huh, Min-Do;Lee, Mu-Kun;Choi, Hee-Jung;Park, Myung-Ae
    • Journal of fish pathology
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    • v.24 no.3
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    • pp.225-236
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    • 2011
  • This study was aimed to determine the fish physical status according to the gross and histopathological findings of liver in cultured black rock fish, Sebastes schlegeli. All 47 fish submitted had no marked abnormalities in the external findings. 42.55% of fish showed normal liver, 25.53% yellow liver, 25.53% atrophic brown liver, 4.26% yellowish-green liver and 2.13% fatty liver in gross examination. Grossly normal liver showed no remarkable change in lobular structure but many vacuoles were found in hepatic cell. Hepatic cells took normal roundish, polygonal shapes containing spherical nuclei. In group of yellow-brown liver, many brown pigments were seen in hepatic cells, MMCs and brown-colored hyaline droplets within cytoplasm of hepatocytes. Yellowish green pigments were seen in hepatic cells and MMCs of yellow green liver and green colored hyaline droplets within hepatocytes. The dilated central veins are highlighted with atrophy of hepatic cells. Outline of atrophic hepatocyte became ambiguous and nucleus frequently become small and pyknotic. Fatty liver showed prominent vacuolar structures in cells as clear spaces or foamy cytoplasm with degenerative nuclei. From these results, it was strongly suggested that hepatic gross and histological findings could be used as important and critical health parameters of fish prior to progression to substantial manifestation as clinical disease.

Factors Affecting Foam Separation of Proteins (단백질의 기포분리에 영향을 미치는 요소들에 관한 연구)

  • Lee, Boo-Young;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.19 no.3
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    • pp.220-224
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    • 1987
  • The concentration ranges forming surface excess of bovine serum albumin(BSA) and ovalbumin solutions were determined, and the factors affecting the foam separation of BSA were investigated. The surface tension of BSA solution decreased from 72 to 61 dynelcm, when the concentration changed from $5{\times}10^{-3}$ to $3{\times}10^{-2}%$, and the critical micelle concentration was appeared to be at 0.03% of BSA. At the isoelectric point (pH 4.9) of BSA, the foamate volume was maximum, but enrichment ratio was minimum, resulting in the maximum recovery rate. When the pH deviated from the isoelectric point, the foamate volume decreased and the enrichment ratio increased. The enrichment ratio increased, while the foamate volume decreased drastically as the temperature was elevated above $20^{\circ}C$, resulting in the decrease in recovery rate. As the gas flow rate increased, the enrichment ratio decreased and the foamate volume increased. When $(NH_4)_2SO_4$ was added, the enrichment ratio decreased, but the maximum foamate was obtained at ionic strength 7. The concentration to form the surface excess of ovlbumin, which has lower surface hydrophobicity than BSA, was 200 times higher than that of BSA. This fact indicates the possibility of selective foam separation by hydrophobicity difference of proteins.

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