• 제목/요약/키워드: critical temperature (Tc)

검색결과 81건 처리시간 0.022초

고온하에서 암석의 열충격, 열팽창 및 열파괴에 관한 연구 (A Study on Thermal Shock, Thermal Expansion and Thermal Cracking of Rocks under High Temperature)

  • 이형원;이정인
    • 터널과지하공간
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    • 제5권1호
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    • pp.22-40
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    • 1995
  • Thermomechanical characteristics of rocks such as thermal shock, thermal expansion, thermal cracking were experimentally investigaed using Iksan granite, Cheonan tonalite and Chung-ju dolomite to obtain the basic data for proper design and Chung-ju dolomite to obtain the basic data for proper design and stability analysis of underground structures subjected to temperature changes. The effect of thermal shock did not appear when the heating speed was under 3$^{\circ}C$/min. and there existed little difference between multi-staged cyclic heating and single-cycled heating. Thermal expansion of rocks was affected by mineral composition, crack porosity and the degree of thermal craking. In quartz-beraring multimineralic rocks such as Iksan granite and Cheonan tonalite, the thermal expansion coefficient increaseed continuously with temperature rise, but that of Chung-ju dolomite which was a monomineralic rock showed a constant value for the temperature above 250$^{\circ}C$, Chung-ju dolomite yielded the lowest critical threshold temperature(Tc) of 100$^{\circ}C$ and unstable thermal cracking was initiated above the new threshold temperature(Tc')of 300$^{\circ}C$. Above Tc' thermal cracks grew but they were not interconnected. Iksan granite showed closing of microcracks to the temperature of 100$^{\circ}C$, then expanded linearly to Tc of 200$^{\circ}C$. Above Tc, thermal cracking was initiated and progressed rapidly and almost all the grain boundaries were cracked at 600$^{\circ}C$. Cheonan tonalite also showed similar behavior to iksan granite except that Tc was 350$^{\circ}C$ and that thermal cracks propagated more rapidly. Thermal expansions calculated by Turner's equation were found to be valid in predicting the thermal expansion and cracking behavior of rocks.

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Analysis of Excluded Volume Effect in Theta Solvent Systems of Polymethyl Methacrylate and Polystyrene by Means of a Modified Scaled Temperature Parameter

  • 김명주;박일현
    • Bulletin of the Korean Chemical Society
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    • 제22권11호
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    • pp.1255-1260
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    • 2001
  • The expansion of two different kinds of hydrodynamic size of polymethyl methacrylate (PMMA Mw: 1.56- 2.04 ${\times}$ 106 g/mol) has been measured by dynamic light scattering and viscometry above the Flory $\theta$ temperature of the variou s solvents such as n-butyl chloride, 3-heptanone, and 4-heptanone. The expansion of PMMA chains was analyzed in terms of universal temperature parameters and also compared with previous results of polystyrene (PS) system. First it was found that simple $\tau/{\tau}c$ parameter no longer had its universality for the expansion behavior of hydrodynamic size in the chemically different linear polymer chains. However after modifying ${\tau}/{\tau}c$ parameter into $(Mw/Ro2)3}2(\tau/\tauc)$, we observed a much better universality for both PMMA and PS systems. Here Mw, Ro, $\tau[=(T-{\theta}$)/${\theta}$]$, and ${\tau}c[=({\theta}-Tc)/Tc]$ are defined as the weight average molecular weight, the unperturbed end-to-end distance, the reduced temperature and the reduced critical temperature, respectively.

Bi-2223 고온초전도 전류리드의 제조 (Fabrication of Bi-2223 high-Tc superconducting current lead)

  • 하동우;오상수;류강식;장현만
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1660-1662
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    • 1996
  • Superconducting current lead is one of the promising applications of the oxide high-Tc superconductors, because they have the advantage of decreasing heat conduction to low temperature region, comparing with a conventional cooper alloy lead. High critical current density is a key factor for the applications such as current lead. $(Bi,Pb)_{2}Sr_{2}Ca_{2}Cu_{3}O_{x}$ high Tc superconductor hase been investigated in terms of critical current density. Bi-2223 superconducting current lead made by CIP and solid state sintering process. Bi-2223 current lead that heat treated at $836\;^{\circ}C$ for 240 h in 1/13 $PO_2$ had over $500\;A/cm^2$ of critical current density at 77K. We knew that the superconducting properties of tube type current leads were better than rods type of them. And we investigated the relation of Bi-2223 formation and heat treatment condition by XRD and SEM analysis.

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화학공정을 이용한 초전도 나노 분말 활성 (Fabrication of High Tc Superconducting Nano Powder Using Chemical Process)

  • 이상헌;김찬중;장건익
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.547-548
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    • 2006
  • In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBaCuO bulk superconductor with high mechanical strength and critical current density. In this project, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of YBaCuO superconductor, and we reported the production of the YBaCuO high Tc superconductor by the pyrolysis method.

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Rf - magnetron sputtering system을 사용한 $YBa_2Cu_3O_x$ 초전도 박막의 제조 (The preparation of $YBa_2Cu_3O_x$ superconducting thin film using rf - magnetron sputtering system)

  • 박성진;김민기;최성환;최효상;황종선;한병성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.717-720
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    • 1992
  • Since the discovery of High-Tc superconducting Y-Ba-Cu-O ceramics with critical temperature of about 90K, numerous efforts to prepare supercond ucting thin films with excellent qualities such as High-Tc and critical current density have been made. The samples were deposited onto $SiO_x$ substrates heated at 540$^{\circ}C$ - 600$^{\circ}C$ in a single target rf - magnetron sputtering system. The film thickness has 2000$\AA$ - 5000 $\AA$ with a rate of 16 $\AA$/min. and distance between target and substrate was 50 mm. The films were characterized by X - ray diffraction, scanning electron microscopy and critical temperature.

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소결체 GdBa$_2$Cu$_3$Ox의 제조 조건이 미세구조 및 전기적 특성에 미치는 영향 (Effects of Preparation conditions of sintered GdBa$_2$Cu$_3$Ox on the microstructures and electrical properties)

  • 김시열;임호빈
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1988년도 추계학술대회 논문집
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    • pp.102-104
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    • 1988
  • GdBa$_2$Cu$_3$Ox superconductors were prepared by ceramic powder compacting method. X-ray powder diffraction patterns and SEM microphotographs were taken to analyze phase and microstructure, and electrical properties were investigated by 4-point probe method. The results show that the $N_2$atmosphere enhances the formation of high Tc(critical temperature) phase, but the Tc is independent of sintering conditions.

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PLD 법에 의한 YBCO 박막의 증착 조건에 따른 특성 (Study on deposition conditions of YBGO films grown by pulsed laser deposition)

  • 최수정;정준기;박유미;고락길;송규정;박찬;유상임
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2003년도 학술대회 논문집
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    • pp.109-112
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    • 2003
  • The high temperature superconducting YBCO films were deposited on the SrTiO$_3$(100) single crystals to find out the proper deposition conditions of YBCO on biaxially-textured metal substrates. Different sets of the substrate temperature, oxygen partial pressure and laser fluence were used to investigate the effect of deposition conditions on the superconducting properties. The new apparatuses for measuring critical temperature (Tc) and critical current (Ic) were designed and manufactured, which were used to obtain Tc's and Ic's of the deposited films. The accuracy of the new apparatus was confirmed by comparing the results with those from SQUID magnetometer. The results on the YBCO films deposited on single crystal substrates which will be used to get the optimum deposition conditions of YBCO films in the coated conductor, are summarized in this report.

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알루미나 세라믹스의 열피로 거동 (Themal Fatigue Behavior of Alumina Ceramics)

  • 정우찬;한봉석;이홍림;이형직
    • 한국세라믹학회지
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    • 제35권10호
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    • pp.1094-1100
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    • 1998
  • The thermal fatigue behavior of alumina ceramics was investigated by water quenching method. Single-quench thermal shock tests were performed to decide the critical thermal shock temperature difference ($\Delta$Tc) which was found to be 225$^{\circ}C$ Cyclic thermal shock fatigue tests were performed at temperature diff-erences of 175$^{\circ}C$, 187$^{\circ}C$ and 200$^{\circ}C$ respectively. After cyclic thermal shock fatigue test the distributions of retained strength and crack were observed. Retained strength was measured by four point bending method and crack observation method bydye penetration. In terms of the retained strength distribution the critical number of thermal shock cycles(Nc) were 7 for $\Delta$T=200$^{\circ}C$, 35 for $\Delta$T=187$^{\circ}C$ and 180for $\Delta$T=175$^{\circ}C$ respec-tively. In terms of the crack observation the critical number of thermal shock cycles were 5 for $\Delta$T==200$^{\circ}C$ 20 for $\Delta$T==187$^{\circ}C$ and 150 for $\Delta$T=175$^{\circ}C$ respectively. The difference of Nc investigated by two different methods is due to the formation of the longitudinal cracks which had no effect on the four point bending strength. Therefore the thermal fatigue behavior of alumina ceramics could be more accurately described by the crack observation method than the retained strength measurement method.

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2차원 Slab 모델을 이용한 초전도체 부상력 특성의 시뮬레이션 (The Simulation of the Characteristics of the Levitation Force in Superconductor Using 2D Slab Model)

  • 유제환;임윤철
    • Tribology and Lubricants
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    • 제14권4호
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    • pp.44-50
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    • 1998
  • This paper describes the simulation of the levitation force between permanent magnet and high Tc(critical temperature) superconductor(HTSC). Levitation force is evaluated numerically on the basis of the magnetic vector potential method and the critical state model. The superconductor is approximated to 2-D slab model. By performing computations, the following characteristics have been investigated: the process of the generation of hysteresis, the various hysteretic behaviors. The characteristics of hysteresis are important for the application to magnetic bearing, for the damping and the nonlinear stiffness is related to hysteresis.