• Title/Summary/Keyword: couplings

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Application of BMPI / HOBT Reagent in Solid-Phase Peptide Synthesis

  • Hong Nam Joo;Choi Soo Kwan;Koock Soon Uoong
    • Bulletin of the Korean Chemical Society
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    • v.10 no.1
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    • pp.19-22
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    • 1989
  • The suitability of BMPI (2-bromo-N-methyl pyridinium iodide) for solid-phase peptide synthesis was investigated. The coupling rate of BMPI/HOBT procedure. BMPI/HOBT was superior to DCC/HOBT couplings using the solid-phase peptide bond formation proceeded to a greater degree of completion than DCC/HOBT method did. Double couplings with 2 equiv. of Bocamino acids and 1.5 equiv. of BMPI and $NEt_3$ and 2 equiv. of HOBT in DMF/MC (1:1 v/v) gave the best result for the preparation of a model compound. Stepwise solid phase peptide synthesis using BMPI/HOBT procedure was successfully utilized for the preparation of $(D-Ala)^2$-dynorphine A. BMPI/HOBT procedure for the synthesis of $(D-Ala)^2$-dynorphine gave better yield (20%) than DCC/HOBT procedure did.

Study on Reliability Evaluation for a Taper Grid Coupling (테이퍼 그리드 커플링의 신뢰성 평가에 관한 연구)

  • Jung, Dong Soo
    • Journal of Applied Reliability
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    • v.17 no.4
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    • pp.343-354
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    • 2017
  • Purpose: This paper evaluates the reliability of tapered grid couplings and presents test results through performance and life tests. Methods: The performance and life test method were presented by analyzing the failure modes for the tapered grid coupling. Zero failure test time was calculated to evaluate the reliability of tapered grid couplings and the test was performed under accelerated conditions. The nondestructive test and wear analysis using weighing were also carried out to check the failure modes of the field conditions. Conclusion: This study can be provided to improve the product reliability through failure analysis of a tapered grid coupling. The performance test results of before and after the accelerated life test were presented to confirm the improved reliability of the tapered grid coupling.

THE CUPID CODE DEVELOPMENT AND ASSESSMENT STRATEGY

  • Jeong, J.J.;Yoon, H.Y.;Park, I.K.;Cho, H.K.
    • Nuclear Engineering and Technology
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    • v.42 no.6
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    • pp.636-655
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    • 2010
  • A thermal-hydraulic code, named CUPID, has been being developed for the realistic analysis of transient two-phase flows in nuclear reactor components. The CUPID code development was motivated from very practical needs, including the analyses of a downcomer boiling, a two-phase flow mixing in a pool, and a two-phase flow in a direct vessel injection system. The CUPID code adopts a two-fluid, three-field model for two-phase flows, and the governing equations are solved over unstructured grids with a semi-implicit two-step method. This paper presents an overview of the CUPID code development and assessment strategy. It also presents the code couplings with a system code, MARS, and, a three-dimensional reactor kinetics code, MASTER.

Low-energy band structure very sensitive to the interlayer distance in Bernal-stacked tetralayer graphene

  • Lee, Kyu Won;Lee, Cheol Eui
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1393-1398
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    • 2018
  • We have investigated Bernal-stacked tetralayer graphene as a function of interlayer distance and perpendicular electric field by using density functional theory calculations. The low-energy band structure was found to be very sensitive to the interlayer distance, undergoing a metal-insulator transition. It can be attributed to the nearest-layer coupling that is more sensitive to the interlayer distance than are the next-nearest-layer couplings. Under a perpendicular electric field above a critical field, six electric-field-induced Dirac cones with mass gaps predicted in tight-binding models were confirmed, however, our density functional theory calculations demonstrate a phase transition to a quantum valley Hall insulator, contrasting to the tight-binding model prediction of an ordinary insulator.

Impedance-Based Stability Analysis of DC-DC Boost Converters Using Harmonic State Space Model

  • Park, Bumsu;Heryanto, Nur A.;Lee, Dong-Choon
    • KEPCO Journal on Electric Power and Energy
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    • v.7 no.2
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    • pp.255-261
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    • 2021
  • This paper proposes impedance-based stability analysis of DC-DC boost converters, where a harmonic state space (HSS) modeling technique is used. At first, the HSS model of the boost converter is developed. Then, the closed-loop output impedance of the converter is derived in frequency domain using small signal modeling including frequency couplings, where harmonic transfer function (HTF) matrices of the open-loop output impedance, the duty-to-output, and the voltage controller are involved. The frequency response of the output impedance reveals a resonance frequency at low frequency region and frequency couplings at sidebands of switching frequency which agree with the simulation and experimental result.

A Non-linear Model for Dynamic Analysis of Reactor Internals (원자로내부구조물의 동적해석을 위한 비선형모델)

  • Myung-J.Jhun;Sang-G.Chang;Song, Heuy-G.
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1993.04a
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    • pp.165-172
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    • 1993
  • A non-linear mathematical model has been developed for the dynamic analysis of the reactor internals. The model includes a lumped mass and stiffness with non-linear members such as gap-spring. As hydrodynamic couplings have also been considered in the model, the effect of fluid/structure interaction between internals components due to their immersion in a confining fluid can be studied for the dynamic response analysis. The reactor internals responses for seismic and pipe break excitations have been calculated for the case of with-and without-hydrodynamic couplings.

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Analytical Solution of Magnetic Field in Permanent-Magnet Eddy-Current Couplings by Considering the Effects of Slots and Iron-Core Protrusions

  • Dai, Xin;Liang, Qinghua;Ren, Chao;Cao, Jiayong;Mo, Jinqiu;Wang, Shigang
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.273-283
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    • 2015
  • In this study, we propose an analytical model for studying magnetic fields in radial-flux permanent-magnet eddy-current couplings by considering the effects of slots and iron-core protrusions on the eddy currents. We focus on the analytical prediction of the air-gap field by considering the influence of eddy currents induced in conducting bars. In the proposed model, the permanent magnet region is treated as the source of a time-varying magnetic field and the moving-conductor eddy current problem is solved based on the resolution of time-harmonic Helmholtz equations. The spatial harmonics in the air gap and in slots, as well as the time harmonics are all considered in the analytical calculation. Based on the proposed field model, the electromagnetic torque is computed by using the Maxwell stress tensor method. Nonlinear finite element analysis is performed to validate the analytical model. The proposed model can be used for permanent-magnet eddy-current couplings with any slot-pole combination.