• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.515-518
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• 2004

The Piezoelectric ceramics for AE(Acoustic Emission) sensor are desired large electromechanical coupling factor, high mechanical quality factor and good characteristic resonance frequency. In this study, the empirical formula of specimens is used $0.9Pb(Zr_xTi_{1-x})O_3-0.1Pb(Mn_{1/3}Nb_{1/3}Sb_{1/3})O_3$ (PZT-PMNS). The piezoelectric and dielectric characteristic are investigated by sintering temperature and value of x as functions of $Ti^{2+},\;Zi^{2+}$ mol rate. MPB(morphotropic Phase boundary) is defined in the x=0.522. Because it is appeared to the best piezoelectric and dielectric characteristic in the x=0.522, it can be application by AE sensor. PZT-PMNS ceramics without pre-amplifier and filter are tested for detecting of arc signal. The detection characteristic is evaluated wave form, frequency distribution.

• Journal of Photoscience
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• v.2 no.1
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• pp.19-25
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• 1995

Picosecond time-resolved and static protein fluorescence spectra and absorption spectra of octopus rhodopsin, a photorecepting protein, are measured and compared with those of bacteriorhodopsin, a photon-induced proton pumping protein, to understand the protein conformations and functions of octopus rhodopsin and its deprotonated photocycle intermediate. The bluer and weaker absorption of retinal indicates that octopus rhodopsin is better in thermal noise suppression but less efficient in light harvesting than bacteriorhodopsin. The protein fluorescence of octopus rhodopsin shows the characteristic of Trp only and the uantum efficiency and lifetime variations may result primarily from variations in the coupling strength with the retinal. The stronger intensity by four times and larger red shift by 12 nm of fluorescence suggest that octopus rhodopsin has more open and looser structure compared with bacteriorhodopsin. Fluorescence decay profiles reveal two decay components of 300 ps (60%) and 2 ns (40%). The deprotonation of protonated Schiff's base increases the shorter decay time to 500 ps and enhances the fluorescence intensity by 20%. The fluorescence and its decay time from Trp residues near retinal are influenced more by the deprotonation. The increase of fluorescence intimates that protein structure becomes loosened and relaxed further by the deprotonation of protonated Schiff's base. The driving force of sequential changes initiated by absorption of a photon is too exhausted after the deprotonation to return the intermediate to the ground state of the begun rhodopsin form.

• Steel and Composite Structures
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• v.39 no.2
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• pp.149-158
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• 2021

In this research paper, the free vibrational response of laminated composite plates is investigated using a non-polynomial refined shear deformation theory (NP-RSDT). The most interesting feature of this theory is the parabolic distribution of transverse shear deformations while ensuring the conditions of nullity of shear stresses at the free surfaces of the plate without requiring the Shear correction factor "Ks". A fourth-nodded isoparametric element with four degrees of freedom per node is employed for laminated composite plates. The numerical analysis of simply supported square anti-symmetric cross-ply and angle-ply laminated plate is carried out using a special discretization based on four-node finite element method which four degrees of freedom per node. Several numerical results are presented to show the effect of the coupling parameters of the plate such as the modulus ratios, the thickness ratio and the plate layers number on adimensional eigen frequencies. All numerical results presented using the current finite element method (FEM) is presented in 3D curve form.

• Coupled systems mechanics
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• v.13 no.2
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• pp.95-113
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• 2024

In this paper, we will analyse the thermo-elastic behavior of the plate element of a structure arranged in a climatically aggressive environment (extreme temperature), we use a refined four-variable thick plate theory to take the shear effect into consideration, the proposed theory less computationally expensive and more accurate so that it incorporates the shear effect into the formulation. The plate is assumed to be simply supported on its four edges, so exact (closed-form) solutions are found according to the Navier expansion, and the governing stability equations and associated boundary conditions of the problem are obtained via the virtual works principle. The plate studied ismade of laminated composite materials, so a parametric study is needed to see the effect of different types of parameters and coupling on the critical temperature value causing thermo-elastic instability of the plate and also on the natural frequency of free vibration, as well as for other parameters such as anisotropy, slenderness and aspect ratio of the plate and finally the lamination angle. Numerical results are obtained for specially orthotropic and antisymmetrical plates and are compared with those obtained by othertheoriesin the literature to validate the analysis approach used.

• Tunnel and Underground Space
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• v.17 no.2 s.67
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• pp.109-118
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• 2007

The excavation damaged zone (EDZ) is an area around an excavation where in situ rock mass properties, stress condition. displacement. groundwater flow conditions have been altered due to the excavation. Various studies have been carried out on EDZ, but most studies have been focused on the mechanical bahavior of EDZ by in situ experiment. Even though the EDZ could potentially form a high permeable pathway of groundwater flow, only a few studies were performed on the analysis of groundwater flow in EDZ. In this study, the' hydraulic EDZ' was defined as the rock Lone adjacent to the excavation where the hydraulic aperture has been changed due to the excavation. And hydraulic EDZ (hydraulic aperture changed zone) estimated by two-dimensional DEM program was considered in three-dimensional DFN model. From this approach the groundwater flow characteristics corresponding to hydraulic aperture change were examined. Together. a parametric study was performed to examine the boundary conditions that frequently used in DFN analysis such as constant head or constant flux condition. According to the numerical analysis, hydraulic aperture change induced by the hydraulic-mechanical interaction becomes one of the most important factors Influencing the hydraulic behavior of jointed rock masses. And also from this study, we suggest the proper boundary condition in three-dimensional DFN model.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.3
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• pp.426-434
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• 2000

This paper deals with a generalized similarity solution for the one-dimensional solidification of ternary or higher-order multicomponent alloys. The present approach not only retains the existing features of binary systems such as temperature- solute coupling, shrinkage-induced flow, solid-liquid property differences, and finite back diffusion, but also is capable of handling a multicomponent alloy without restrictions on the partition coefficient and microsegregation parameter. For an alloy of N-solute species, governing equations in the mushy region reduce to (N+2) nonlinear ordinary differential equations via similarity transformation, which are to be solved along with the closed-form solutions for the solid and liquid regions. A linearized correction scheme adopted in the solution procedure facilitates to determine the solidus and liquidus positions stably. The result for a sample ternary alloy agrees excellently with the numerical prediction as well as the reported similarity solution. Additional calculations are also presented to show the utility of this study. Finally, it is concluded that the present analysis includes the previous analytical approaches as subsets.

• Progress in Medical Physics
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• v.4 no.1
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• pp.41-53
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• 1993

The electron spin resonanec of sigle crystals of L-alanine have been observed at T=300K, 100K and analyzed for different orieantations of the crystal in the magnetic field and at microwave frequency X-band. The stable free radical profuced by the irradiation is proved to be of the form CH$_3$CHR, where R is a group which has no nuclei with detectable coupling A notable dependence on temperature of the absorption was observed in the range from 1100K to 2l0K. It was concluded that the reorietation of the methy group of the radical H$_3$CCHR is quenched at low temperature.

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1276-1280
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• 2003

Thermal behavior of bromphenols was investigated by direct pyrolysis at high temperature. The thermal degradation products formed by the pyrolysis of mono-bromophenols (o-, m-, and p-) were identified by gas chromatography-mass spectrometry. During the pyrolysis reactions, several kinds of dioxins and furans were produced, and the relative ratio of pyro-products was dependent on the substituted position of bromine in phenolic structure due to the effect of symmetry and steric hindrance. The formation of dioxins can be explained by the phenoxy radical addition and Br atom elimination at an ortho-carbon site on phenolic structure. On the other hand, the formation of furans can be explained by the ortho-ortho carbon coupling of phenoxy radicals at unsubstituted sites to form o, o'-dihydroxydiphenyl intermediate via its keto-tautomer, followed by $H_2O$ elimination. The pyrolysis temperature has also a substantial effect on the dimerized products quantities but little effect on the type of pyro-products. Moreover, the formation mechanism of pyro-products was suggested on the basis of products identified.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.5
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• pp.251-255
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• 2009

Nanocomposites based on coupling $TiO_2$ matrix with nanosized noble metals (Pt,Au) particles exhibited promising photoelectrode properties. The $M/TiO_2$ (M=Pt,Au) nanocomposite thin films were deposited on quartz and ITO glass substrates using a co-sputtering method. $TiO_2$ in rutile form is the dominant crystalline phase for as-deposited nanocomposite films. Along with heat treatment up to $600^{\circ}C$, XRD peaks of the rutile phase as well as those of noble metal increased in intensity and decreased in width, indicating the growth of crystallites. The anodic photocurrents of $M/TiO_2$ (M=Au,Pt) thin films were observed not only in the UV range but also in the visible light range. The photocurrent of the nanocomnosite films extended to the visible light region by dispersion of nano-sized noble metal in the $TiO_2$ matrix.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.27 no.9
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• pp.555-560
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• 2014

In this paper, in order to develop outstanding Pb-free composition ceramics, the $Fe_2O_3$-doped ($Na_{0.525}K_{0.443}Li_{0.037}$)($Nb_{0.883}Sb_{0.08}Ta_{0.037}$)$O_3$ + 0.3 wt% $Bi_2O_3$ + x wt% $Fe_2O_3$ (x= 0~1.0 wt%)(abbreviated as NKL-NST) lead-free piezoelectric ceramics have been synthesized using the ordinary solid state reaction method. The effect of $Fe_2O_3$-doping on their microstructure and electrical properties were investigated. XRD diffraction pattern studies confirm that $Fe_2O_3$ completely diffused into the NKL-NST lattice to form a new stable soild solution with $Fe^{3+}$ entering the $Nb^{5+}$, $Sb^{5+}$ and $Ta^{5+}$ of B-site. And, phase structure of all the ceramics exhibited pure perovskite phase and no secondary phase was found in the ceramics. The ceramics doped with 0.6 wt% $Fe_2O_3$ have the optimum values of piezoelectric constant($d_{33}$), planar piezoelectric coupling coefficient($k_p$) and mechanical quality factor($Q_m$) : $d_{33}$ = 233 [pC/N], $k_p$= 0.44, $Q_m$= 95. These results indicate that the ($Na_{0.525}K_{0.443}Li_{0.037}$)($Nb_{0.883}Sb_{0.08}Ta_{0.037}$)$O_3$ +0.3 wt% $Bi_2O_3$ + 0.6 wt% $Fe_2O_3$ ceramic is a promising candidate for lead-free piezoelectric ceramics.