• Title/Summary/Keyword: corrosion time

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A Study of Built-Up Repair Welding for Stainless Steel Propulsion Shafting (스테인리스강 프로펠러축계의 육성 용접에 대한 연구)

  • Baik, Shin-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.4
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    • pp.119-125
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    • 2007
  • In recent days, the consumption of stainless steel in the propulsion shafting systems for small-medium class vessel is increased due to its high corrosion protection with wear resistant properties. Unfortunately the small and medium class vessel that operated in the west-south sea area of Korean peninsula experienced heavy wear down due to the role of mud. In the event of wear or broken down, the propeller shaft must be replaced by new one, but the new shaft is very expensive and time-consuming for order made supply. In this case, the methods of built up for wear and broken shaft by welding is one of the most effective cases. In this study, the built up welding for austenitic stainless steel shaft has been accomplished by various pre-surface treatment, welding methods, post heattreatment and inspection. The results confirmed that the built-up welding was one of the effective methods for stainless steel shafting.

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Development of a numerical modelling technique for evaluation of a long-term chemical deterioration of tunnel shotcrete lining (터널 숏크리트 라이닝의 장기 화학적 열화 손상 평가를 위한 수치 모델링 기법 개발)

  • Shin, Hyu-Soung;Kim, Dong-Gyou
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.3
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    • pp.299-307
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    • 2007
  • In this study, a new concept for simulating a physical damage of tunnel shotcrete lining due to a long-term chemical deterioration has been proposed. It is known that the damage takes place mainly by internal cracks, reduction of stiffness and strength, which results mainly from volume expansion of the lining and corrosion of cement materials, respectively. This damage mechanism of shotcrete lining appears similar in most kinds of chemical reactions in tunnels. Therefore, the mechanical deterioration mechanism induced by a series of chemical reactions was generalized in this study and mathematically formulated in the framework of thermodynamics. The numerical model was implemented to a 3D finite element code, which can be used to simulate behaviour of tunnel structures undergoing external loads as well as chemical deterioration in time. A number of illustrative examples were given to show a feasibility of the model in tunnel designs.

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Analysis of Iron Production Technology of Army against Japanese through Slag from Saengsoegol Iron Production Site

  • Kim, Minjae;Chung, Kwangyong
    • Journal of Conservation Science
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    • v.35 no.4
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    • pp.317-329
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    • 2019
  • Slag was collected from the iron-producing furnace site in Saengsoegol, Baegun mountain, where iron was manufactured by a righteous army against Japan in the Gwangyang region; then, the iron-manufacturing technique of the early modern period was investigated through scientific analysis. In the microstructure analysis results of the selected samples, iron bloom was mainly observed together with magnetite and fayalite. In the component analysis results of the compounds, it was confirmed that the furnace was built by using gangue of alkali feldspar or plagioclase series, and the ironmaking work was performed at a high temperature of at least 1050℃, because mullite was identified together with cristobalite and hercynite. Based on the chemical composition, it was speculated that low-grade iron ores were used as raw materials, and it seemed that the yield was low, because the total Fe content of the smelting slag samples was 37.72-49.93%. It was difficult to confirm whether a slag former was used, and it seemed that materials easily obtained nearby were used when the furnace was built, without considering the corrosion resistance. It appeared that the ironmaking work was performed at the Gwangyang Saengsoegol iron-producing furnace based on the direct ironmaking method in an environment that could escape the vigilance of the Japanese Empire to produce weapons that would be used for the resistance against Japan. It seemed that there was neither an advanced ironware production system nor a mass production system, and small-scale works were performed in short periods of time.

Design, Manufacturing, and Performance estimation of a Disposal Canister for the Ceramic Waste from Pyroprocessing (파이로 공정 세라믹 폐기물을 위한 처분용기의 설계, 제작 방안, 그리고 기능 평가)

  • Lee, Minsoo;Choi, Heui-Joo;Lee, Jong-Youl;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.209-218
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    • 2012
  • A pyroprocess is currently being developed by KAERI to cope with a highly accumulated spent nuclear fuel in Korea. The pyroprocess produces a certain amount of high-level radioactive waste (HLW), which is solidified by a ceramic binder. The produced ceramic waste will be confined in a secure disposal canister and then placed in a deep geologic formation so as not to contaminate human environment. In this paper, the development of a disposal canister was overviewed by discussing mainly its design premises, constitution, manufacturing methods, corrosion resistance in a deep geologic environment, radiation shielding, and structural stability. The disposal canister should be safe from thermal, chemical, mechanical, and biological invasions for a very long time so as not to release any kind of radionuclides.

Degradation Characteristics of Aqueous AMP Solution Containing Additives in Separation of $CO_2/H_2S$ ($CO_2/H_2S$의 분리시 첨가제에 따른 AMP 수용액의 열화특성)

  • Choi, Won-Joon;Lee, Jae-Jeong;Cho, Ki-Chul;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.280-285
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    • 2005
  • The method of chemical absorption has been presented to separate and recover acid gases like $CO_2\;and\;H_2S$. But, this method has some problems such as loss of valuable amine and operational problems (forming, corrosion and fouling) by degradation. In this study, we investigated the degradation characteristics of aqueous AMP solution containing additives such as HMDA, MDEA and piperazine. The degradation was affected by temperature and process time. AMP solution absorbing $CO_2\;and\;H_2S$ was degraded 105% and 23% more than pure AMP at $120^{\circ}C$ respectively. In addition, all the additives were degraded significantly as the temperature increased. The order of the degraded amount of additives mixed in the AMP solution containing absorbed $CO_2$ was as followings : HMDA > piperazine > MDEA.

Electrodeposition of Nano TiO2 Powder Dispersed Nickel Composite Coating (전기도금법을 이용한 나노 산화티타늄 니켈 복합도금에 관한 연구)

  • Park, So-Yeon;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.4
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    • pp.65-69
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    • 2012
  • Composite coating can be manufactured during the electroplating with the bath containing a suspension of particles: ceramic, polymer, nanopowders. Improvement of hardness, wear resistance, corrosion resistance and lubrication properties are well-known advantage of composite coating. In this study, nano $TiO_2$ powder dispersed Ni composite plating was investigated. The improvement of surface hardness and photo decomposition effects can be expected in this coating. Zeta potential was measured with pH. The effect of ultrasonication time and types of ultrasonicator were studied to minimize the agglomeration of $TiO_2$ nanopowders in the electrolyte. Optimum conditions for nano $TiO_2$ dispersed Ni composite coating were $40mA/cm^2$ of current density, pH 3.5, and $50^{\circ}C$. At these conditions, $TiO_2$ nanoparticles contents in the Ni deposit was 15-20 at.%.

The Bisphenol A: A Modulator of Pregnancy in Rats

  • Kim, Pan-Gyi;Lee, Na-Rae;Hwang, Seong-Hee
    • Journal of Environmental Health Sciences
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    • v.29 no.4
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    • pp.27-34
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    • 2003
  • Bisphenol A is used in the manufacture of epoxy, polycarbonate, and corrosion-resistant unsaturated polyester-styrene resins required for food packaging materials in industrial processing. Some reports indicated the possibility of harmful effects on rats. In this study was used a method for the determination of bisphenol A in blood according to the OSHA High Performance Liquid Chromatography (HPLC) guideline. The method involved blood extraction using methylene chloride. And it was evaluated developmental and teratogenic effects in pregnant rats and second generation. The results obtained were as follows. There was a significant increase in the body weights and treated groups F1 female in liver, spleen, kidney, but according to dose-response. F1 female rat's relative body weight and absolute body weight are not different. There was a significant increase liver, spleen, kidney organ weight and reproductive organ weight epididymis, prostate gland in F1 male rats. There was a proestrous in pregnant rat, group 200 $\mu\textrm{g}$/kg, 2000 $\mu\textrm{g}$/kg, 20,000 $\mu\textrm{g}$/kg. The effect on rat treated with bisphenol A decrease organ weight and reproductive organ weight. Identification and quantitation were performed with using HPLC C18 column and using at retention time 5.5 min. The results of the detection of bisphenol A were at 20,000 $\mu\textrm{g}$/kg in average 1 $\mu\textrm{g}$/ml, 200 $\mu\textrm{g}$/kg average in 0.9 $\mu\textrm{g}$/ml blood samples. From those results, it could be concluded that the effects of pregnant rat and second generation(F1) by bisphenol A treatment during lactational period were estrogenic and bisphenol A was remained in serum at low level.

Long-Term Experiment of Chloride Penetration in Concrete through Cracks (콘크리트의 균열부를 통한 염소이온 침투의 장기 실험연구)

  • Yoon, In-Seok;Sung, Jae-Duck
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.809-812
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    • 2008
  • Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. The majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. Author of this study examined the effect of cracks on chloride penetration by short tem experiment. However, it is necessary to accomplish the effect by long term experiment to get reliable goal. In this study, the long term experiment was carried out and the experimental result was compared with short term experiment. Crack tends to decrease with elapsed time because of self-healing. Especially this trend was obvious in concrete sample with wide crack with.

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Deformation Characteristics of Flexible Pipe with Variation of Buried Conditions (매설조건에 따른 연성관의 변형특성)

  • Lee, Bongjik
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.10
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    • pp.53-62
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    • 2014
  • In Korea, the pipe type that has been well used as sewage pipe from the past is primarily a rigid pipe which is represented by concrete hume pipe, but the use of it is being decreased sharply because of the problems such as tube erosion and incomplete watertightness securing through the time. On the other hand, the use of flexible pipe has been increased because its construction ability is excellent on account of its light weight as well as it is resistant to corrosion. However, because there are lacks of market's confidence in flexible pipe and occurrence cases of partial damage incomplete caused by compaction control, cause analysis and management for them are needed. Therefore, this study tried to estimate the deformation characteristics of pipe caused by each condition through numerical analysis changing construction sequence, rigidity of pipe, strength of ground concrete under the pipe, relative compaction ratio of sand foundation under the pipe and relative compaction ratio of backfill material above the pipe. Evaluation result is that influence on each factor is confirmed and the quality control of sand around the pipe are turned up to be important.

The Study on the Hydrogen Embrittlement of ferrite Stainless Steel with Welding Conditions and Current Density (용접조건과 전류밀도에 따른 페라이트 스테인리스강의 수소취성에 관한 연구)

  • Choi Byung-Il;Lim Uh-Joh
    • Journal of the Korean Institute of Gas
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    • v.10 no.1 s.30
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    • pp.43-47
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    • 2006
  • This study attempted to examine how the hydrogen embrittlement susceptibility of the STS 444 stainless steel varies under different welding conditions and how its effect on hydrogen embrittlement differs by the impressed current density levels. For doing so, U bend test specimens was used to impress the current density at 5,10, 15, and 20 $mA/cm^2$ in the $0.5M\;H_2SO_4+0.001M\;As_2O_3$ solution with an electrochemical corrosion tester. The hydrogen embrittlement was assessed by observing the time to failure, and then the microphotographs of metal structures were compared to investigate the metal- related structural properties. The study findings suggest that the effect on hydrogen embrittlement for the STS 444 steel significantly depends on both the welding conditions, or variations in the amount of shield gas, and the levels of current density. In particular, as the impressed current density increases, the hydrogen embrittlement increases rapidly.

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