• Title/Summary/Keyword: corrosion resistance property

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A Electrochemical Study on the Effect of Post-Weld Heat Treatment about Corrosion Resistance Property of SS400 Steel for Ship's Materials (선박재료용 SS400강의 내식성에 대한 용접후열처리효과에 관한 전기화학적 연구(I))

  • 김진경
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.6
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    • pp.806-813
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    • 1999
  • The effect of Post-Weld Heat Treatment(PWHT) of SS400 Steel was investigated with parameters such as micro vickers hardness corrosion potential polarization behaviors galvanic current Al anode generating current Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM)by PWHT is lower than that of each parts by Non Post-Weld Heat Treatment(NPWHT) However hardness of WM of HAZ part was the highest among those three parts and HAZ area were also acted as cathode without any case of heat treatment. Potential difference between each three parts by PWHT was also smaller compared to NPWHT. Therefore it is suggested that Corrosion resistance property is increased by PWHT. However both Al anode generating current and anode weight loss was also decreased by PWHT compared to NPWHT when SS400 steel is cathodically protected by Al anode.

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Effects of Sealing Solution for Anodized Mg-Al Alloys and Its Corrosion Resistance Property (양극산화한 Mg-Al합금에 대한 봉공처리액 조성의 효과와 그 내식성)

  • 장석기;김정일;김성종
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.5
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    • pp.782-792
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    • 2004
  • The effects of sealing solution for anodized Mg-Al alloys and their corrosion resistance property were investigated. focusing on the effects of anodizing potentials aluminum contents and sealing solutions. All of the anodized specimens showed better corrosion resistance than that of non-anodized specimens, regardless of applied potentials. It was found that the anodic film formed at 4 V had the best corrosion resistance. The sealing effects were improved by increasing the temperature of distilled water. the pH of solution and the relative intensity ratio of $Mg(OH)_2$.

Development of Metallic Bipolar Plate Material with W-addition in Austenitic Stainless Steel for PEMFC Environment

  • Kim, Kwang Min;Koh, Sung Ung;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.5 no.5
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    • pp.153-159
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    • 2006
  • Austenitic stainless steels with addition of various amounts of Mo and W were evaluated in terms of corrosion and contact resistance to determine optimum alloy composition of metallic bipolar plate for PEMFC. The corrosion property was evaluated by both acid fume exposure test at $130^{\circ}C$ and by electrochemical polarization tests in $H_3PO_4$ solution at $80^{\circ}C$. Austenitic stainless steel with proper amount of Mo and W demonstrated not only good corrosion resistance but also low contact resistance. Analyses on the passive film show that partial substitution of Mo by W enhances passive film stability and repassivation property. Test results suggest that austenitic stainless steel with 2 wt%Mo and 4 wt%W has optimum composition for metallic bipolar plate used in PEMFC.

Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets

  • Jo, Du-Hwan;Kwon, Moonjae;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.15-19
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    • 2012
  • Both electrogalvanized and hot-dip galvanized steel sheets have been finally produced via organic-inorganic surface coating process on the zinc surface to enhance corrosion resistance and afford additional functional properties. Recently, POSCO has been developed a variety of chromate-free coated steels that are widely used in household, construction and automotive applications. New organic-inorganic hybrid coating solutions as chromate alternatives are comprised of surface modified silicate with silane coupling agent and inorganic corrosion inhibitors as an aqueous formulation. In this paper we have prepared new type of hybrid coatings and evaluated quality performances such as corrosion resistance, spot weldability, thermal tolerance, and paint adhesion property etc. The electrogalvanized steels with these coating solutions exhibit good anti-corrosion property compared to those of chromate coated steels. Detailed components composition of coating solutions and experimental results suggest that strong binding between organic-inorganic hybrid coating layer and zinc surface plays a key role in the advanced quality performances.

The Effect of Microstructural Evolution on Corrosion Property of Ti Plate with Heat Treatment (열처리에 따른 미세구조 변화가 Ti 판재의 부식특성에 미치는 영향)

  • Kim, Min Gyu;Lee, Chan Soo;Kim, Tae Gyu;Kim, Hye Sung
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.1
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    • pp.12-17
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    • 2018
  • We investigated the corrosion behavior of commercially pure cold working processed (CP)-Ti with coarse-grained (CG) microstructure heat-treated at $400^{\circ}C$ and $600^{\circ}C$, respectively. It is observed that corrosion resistance of as-received CP-Ti heat-treated at $400^{\circ}C$, at which recrystallization proceeds, is largely improved. Interestingly, the mechanical property of CP-Ti sample at $400^{\circ}C$ was scarcely deteriorated. It is attributed to the decrease of the defects such as strain variance and dislocation density. On the other hand, the annealing treatment at $600^{\circ}C$ of CP-Ti plate causes to grain growth with the noticeable reduction of mechanical property. Hence, it is considered that defect density such as strain and dislocation density is important microstructural parameter for the improvement of corrosion resistance. The introduction of proper annealing treatment can help to improve corrosion resistance without scarifying mechanical property of CP-Ti.

Evaluation of Nonchromated Thin Organic Coatings for Corrosion Inhibition of Electrogalvanized Steel

  • Park, Jong Myung;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.68-73
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    • 2007
  • The toxicity of chromium that is used to impart corrosion resistance to galvanized steel created environmental and health-related concerns and generated a great deal of interest in developing chrome-free treatment coatings. In the present work, organic-inorganic composite coatings were used to coat electrogalvanized steel (EG) sheets for corrosion protection without degrading its weldability property. The new coatings composed of specially modified polyurethane dispersion hybridized with silicate and unique inorganic-organic inhibitors were developed during this work. It was found that about $1{\mu}m$ thickness of coating layer is secure enough in corrosion resistance of flat and formed part even after alkaline degreasing. Overall chemical resistances including fingerprint resistance and paint adhesion property were satisfied with the test specification of Sony technical standard of SS-00260-2002. Therefore, it is concluded that the newly developed chrome-free product can replace the conventional chromated product.

Electrochemical Study on the Effect of Post-Weld Heat Treatment Affecting to Corrosion Resistance Property of the Weldment of SCM440 Steel (SCM440강 용접부의 내식성에 미치는 용접후 열처리효과에 관한 전기화학적 연구)

  • 김성종;김진경;김종호;김기준;김영식;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.6
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    • pp.78-88
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    • 2000
  • The effect of post-weld heat treatment(PWHT) of SCM440 steel was investigated with parameters such as micro-Vickers hardness, corrosion potential, polarization behaviors, galvanic current, Al anode generating current and Al anode weight loss, etc. Each hardness of three parts(HAZ, BM, WM) by PWHT is lower than each of as-welded parts. However, hardness of WM area was the highest among those three parts in case of both PWHT and as-welded. Corrosion potential of WM part was the highest among those three parts and WM area was also acted as cathode without regard to PWHT. The magnitude of corrosion potential difference among three parts by PWHT was larger than that of three parts of as-welded, and corrosion current by galvanic cell of these three parts by PWHT was also larger compared to as-welded. Therefore, it is suggested that corrosion resistance property of SCM440 steel is decreased by PWHT than as-welded. However, both Al anode generating current and anode weight loss were also increased by PWHT compared to as-welded when SCM400 steel is cathodically protected by Al anode.

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Experimental study on the electrochemical properties of zwitterion and phosphate-based hybrid inhibitors in reinforced concrete (양쪽성 이온 및 인산염 기반 하이브리드 방청제의 전기화학적 특성에 관한 실험적 연구)

  • Tran, Duc Thanh;Jeong, Min-goo;Lee, Han-seung;Yang, Hyun-min;Singh, Jitendra Kumar
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.37-38
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    • 2022
  • During the past decades, the corrosion of the steel rebar embedded in concrete structure surrounding marine environment is actually problematic and required the suitable preventive method. An eco-friendly corrosion inhibitor mix is investigated to stifle the active corrosion in comparison with other commercial corrosion inhibitors. The hybrid inhibitor enhances the corrosion resistance and the workability of concrete. However, it reduces the compressive strength slightly after 28-day-age. The electrochemical studies and mechanical studies are pointed out the corrosion resistance property, corrosion kinetics, and the mechanical properties of all concrete samples. H-3 is the optimum dose of hybrid inhbitor that meets the demand of both electrochemical property and mechanical property. It performs the noble features due to the formation of optimum amount of P-Zwitterions-(Cl)-Fe complex onto the steel rebar surface.

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Study on Corrosion Properties of Additive Manufactured 316L Stainless Steel and Alloy 625 in Seawater

  • Jung, Geun-Su;Park, Yong-Ha;Kim, Dae-Jung;Lim, Chae-Seon
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.258-266
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    • 2019
  • The objective of this study was to evaluate corrosion resistance of additive manufactured 316L stainless steel and alloy 625 powders widely used in corrosion resistance alloys of marine industry in comparison with cast alloys. Directed Energy Deposition (DED) method was used in this work for sample production. DED parameter adjustment was also studied for optimum manufacturing and for minimizing the influence of defects on corrosion property. Additive manufactured alloys showed lower corrosion resistance in seawater compared to cast alloys. The reason for the degradation of anti-corrosion property was speculated to be due to loss of microstructural integrity intrinsic to the additive manufacturing process. Application of heat treatment with various conditions after DED was attempted. The effect of heat treatments was analyzed with a microstructure study. It was found that 316L and alloy 625 produced by the DED process could recover their expected corrosion resistance when heat treated at 1200 ℃.

Surface Treatment of Automotive Cast Parts of Magnesium Alloy

  • Sim, Yangjin;Kim, Jongmyung
    • Corrosion Science and Technology
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    • v.2 no.2
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    • pp.102-108
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    • 2003
  • The surface treatments. Chrome/Manganese and Modified Chrome Pickle, that are treated to improve the anti-corrosion property which is needed to increased the probability of prototype product enabled the sand cast Magnesium test specimens to have better corrosion resistance than non-treated one. Sand cast Magnesium specimens which was treated only with chemical conversion coating had same corrosion resistance with the Steel specimens plated by Zinc, and the another one that had the finishing treatment(painting) worked on the chemical surface treatment had the corrosion resistance property to meet to FPO-3 requirement. We also investigated the multiple finishing system(chemical surface treatment + 3 coating) to test the severe condition that magnesium should to endure.