• Journal of the Korea Concrete Institute
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• v.14 no.6
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• pp.851-863
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• 2002

Corrosion products of reinforcement in concrete induce pressure to the adjacent concrete due to the expansion of steel. This expansion causes tensile stresses around the reinforcing bar and eventually induces cracking through the concrete cover The cracking of concrete cover will adversely affect the safety as well as the service life of concrete structures. The purpose of the this study is to examine the critical corrosion amount which causes the cracking of concrete cover. To this end, a comprehensive experimental and theoretical study has been conducted. Major test variables include concrete strength and cover thickness. The strains at the surface of concrete cover have been measured according to the amount of steel corrosion. The corrosion products which penetrate into the pores and cracks around the steel bar have been considered in the calculation of expansive pressure due to steel corrosion. The present study indicates that the critical amount of corrosion, which causes the initiation of cracking, increases with an increase of compressive strength. A realistic relation between the expansive pressure and average strain of corrosion product layer in the corrosion region has been derived and the representative stiffness of corrosion layer was determined. A concept of pressure-free strain of corrosion product layer was introduced to explain the relation between the expansive pressure and corrosion strain. The proposed theory agrees well with experimental data and may be a good base for the realistic durability design of concrete structures.

• Corrosion Science and Technology
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• v.23 no.2
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• pp.154-165
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• 2024

Acetic acid and acetonitrile produced in the chemical process of petrochemical plants are used at high temperatures and pressures. They are exposed to harsh corrosive environments. The present investigation aimed to evaluate corrosion characteristics of metals with excellent corrosion resistance by performing immersion and electrochemical experiments with different composition ratios of acetic acid and acetonitrile in a high-temperature and high-pressure environment. Results of immersion experiment revealed that as acetic acid concentration increased, surface damage and corrosion also increased. In immersion experiments under all conditions, super austenitic stainless steel (UNS N08367) had the best corrosion resistance among various metals. The maximum damage depth under the most severe immersion conditions was observed to be 4.19 ㎛, which was approximately 25.25 ㎛ smaller than that of highly damaged stainless steel (UNS S31804). As a result of electrochemical experiments, electrochemical characteristics of various metals presented some differences with different composition ratios of acetic acid and acetonitrile. However, super austenitic stainless steel (UNS N08367) had the best corrosion resistance at a high pressure condition with a high concentration of acetic acid.

• Journal of the Korean institute of surface engineering
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• v.52 no.6
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• pp.293-297
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• 2019

Quasi-nano-hardness and corrosion behaviors of neutron-irradiated reactor pressure vessel (RPV) steels such as 15Ch2MFA (Ni<0.4, 2.520 n/㎠ (En>1.0 MeV) for 32 days. Quasi-nano-hardnesses of the 15Ch2MFA and 15Cr2NHFA steels were 183.8 and 179.8 Hv, respectively. Their corrosion rates and corrosion potentials were 2.4×10^-4Acm^-2, -515.9 mV_SHE and 6.8×10^-4 Acm^-2, -523.6 mV_SHE in NACE standard TM0284-96 solution at room temperature, respectively. 15Ch2MFA steel showed better quasi-nano-hardness and corrosion resistance than 15Cr2NHFA steel in this test condition.

• Corrosion Science and Technology
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• v.6 no.3
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• pp.112-119
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• 2007

This paper presents the importance of corrosion control and protection technology with a real case study of heater tube rupture damaged by High temperature H2S-H2 corrosion in the refinery. The heater was operated at the Hydrocracking unit and the operation temperature and pressure was $340^{\circ}C$ and $18kg/cm^{3}$ respectively. Top side of the convection tube was thinned by high temperature hydrogen sulfide and hydrogen gas as a uniform corrosion and finally ruptured under operation pressure. Damaged area (Convection tube zone) was blocked by protection wall, so it was impossible to inspect with conventional nondestructive examination. Instead the elbow area which is out of the protection wall was inspected regularly to evaluate the corrosion rate of convection tube indirectly. However the operation temperature and the phase of the process stream was different between inside the chamber and outside the chamber. As a result, it caused severe corrosion to the horizontal convection tube inside the chamber comparing to the elbow outside the chamber. Finally convection tube was corroded more rapidly than the elbow and ruptured after 13 years operation. Because of the rupture, the heater was totally burned and the operation was stopped for 3 months until it has been reconstructed. To prevent this kind of corrosion problem and accident, corrosion control should be strengthened and protection technology should be improved.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.92-98
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• 2008

This paper describes the experiments of the corrosion and the sliding tests of the nickel-based alloys for the gate valve seating materials used at high pressure and temperature. The general corrosion rates and IGC susceptibility are tested in pressurized water at 533 K and 575 K and in Strauss test solution. The sliding tests have been done in pressurized water at 293 k, 473 K and 573 k. The alloys containing above 10% chromium may have the anti-corrosion properties that could be applied to the valve seats for the power plants. The good sliding performance and the good pressure tightness are obtained when the disc specimens that have hardness 500 to 600 Hv combined with the seat specimens that have hardness 250 to 410 Hv containing about 40 percent of iron. The large size gate valves sliding tests have certified the test results. The anti-wear properties of the seat alloy and the anti-IGC susceptibility of the disc alloy could be improved by the addition of silicon and niobium, respectively.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.361-366
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• 2002

The deterioration of concrete structure due to corrosion of the reinforcement has created big financial losses on the overall industries. The volume expansion of the corrosion products causes internal pressure to concrete wall around reinforcing bar. If the maximum principal stress induced by internal pressure exceeds the tensile strength of the concrete at any point of time, a crack forms at any point of material. Therefore, in terms of life assessment of concrete structure, it is very important to predict the amount of corrosion products which induces initial concrete cracking. With this objective, this paper proposes the critical amount of corrosion products at interface between reinforcement and concrete using finite element analysis. If an actual survey of corrosion rates could be made, the model might supply information for condition assessment of existing concrete structure. As the mechanical properties of corrosion product and instantaneous geometry of corroded steel are considered in the analysis, the value obtained will be more realistic.

• Corrosion Science and Technology
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• v.7 no.4
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• pp.237-242
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• 2008

Physical properties of water, such as dielectric constant and ionic product, significantly vary with the density of water. In the supercritical conditions, since density of water widely varies with pressure, pressure has a strong influence on physical properties of water. Dielectric constant represents a character of water as a solvent, which determines solubility of an inorganic compound including metal oxides. Dissociation equilibrium of an acid is also strongly dependent on water density. Dissociation constant of acid rises with increased density of water, resulting in drop of pH. Density of water and the density-related physical properties of water, therefore, are the major governing factors of corrosion and environmentally assisted cracking of metals in supercritical aqueous solutions. This paper discusses importance of "physical properties of water" in understanding corrosion and cracking behavior of alloys in supercritical water environments, based on experimental data and estimated solubility of metal oxides. It has been pointed out that the water density can have significant effects on stress corrosion cracking (SCC) susceptibility of metals in supercritical water, when dissolution of metal plays the key role in the cracking phenomena.

• Journal of Advanced Marine Engineering and Technology
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• v.18 no.2
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• pp.54-63
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• 1994

Mg thin films were prepared on SPCC(cold-rolled steel) substrates by vasuum evapoaration and ion-plating. The influence of argon gas pressure and substrates bias voltage on the crystal orientation and morphology of the film was determined by using X-ray diffraction and scanning electron micrography (SEM), respectively. And the effect of crystal orientation and morphology of the Mg thin films on corrosion behavior was estimated by measuring the anodic polarization curves in deaerated 3% NaCl solution. The crystal orientation of the Mg films deposited at high argon gas pressure exhibited a (002) preferred orientation, regardless of the substrate bias voltage. Film morphology changed from a columnar to a granular structure with the increase of argon gas pressure. The morphology of the films depended not only on argon gas pressure but also bias voltage ; i.e., the effect of increasing bias voltage was similar to that of decreasing argon gas pressure. The influences of argon gas pressure and bias voltage were explained by applying the adsorption inhibitor theory and the sputter theory. And also, this showed that the corrosion resistance of the Mg thin films can be changed by controlling the crystal orientaton and morphology.

• Corrosion Science and Technology
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• v.3 no.6
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• pp.233-239
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• 2004

Primary water stress corrosion cracking of steam generator tubings occur on many tubes in pressurized water reactors(PWRs), and they are repaired using sleeves or plugs. In order to develop proper repair criteria, it is necessary to know the leak behavior of the tubes, which have stress corrosion cracks. Crack development tests were carried out on the tubes at room temperature, and leak rate and burst pressure were measured on the degraded tubes at room temperature and a high temperature. No leakage was detected on the tubes where 100 % through wall crack developed, at 1560 psi, which is an operating pressure difference of pressurized water reactors(PWRs). In some tests, leak rates of the tubes increased with time at a constant internal water pressure. A test tube showed a very small amount of leakage at 2700 psi in a high temperature pressure test at $282^{\circ}C$, but it disappeared after the pressure increased slightly. Even cracks are 100 % through wall, they need to open in order to reach a certain amount of leak rate at the operating pressure difference.

• Journal of the Korean institute of surface engineering
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• v.51 no.2
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• pp.95-103
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• 2018

Recently, many types of constructional steels have been often exposed to under severe corrosive environments due to acid rain with increasing environmental contamination. In order to inhibit their corrosion in severe corrosive environments, a painting method has been widely applied to numerous constructional steels of land as well as marine. Therefore, development of paint having a good quality of corrosion resistance is considered to be very important. In this study, four types of anti-corrosive paints (AP: Phenol epoxy, AC: Ceramic epoxy, AT: Coal tar epoxy, AH: High solid epoxy) were coated to the specimens, and then, were immerged in various salt solutions (0.1, 0.3, 3, 6, 9 and 15% NaCl solutions) for 11 days. And, the corrosion resistance of these samples by effect of osmotic pressure with salt concentration was investigated with electrochemical methods such as measurement of corrosion potential, impedance and corrosion current density. The corrosion current densities of all samples (AC, AT and AH) submerged in 3% NaCl solution exhibited the smallest values compared to other salt solutions. However, in the case of lower values of salt solutions than 3% NaCl solution, the corrosion current density increased again because it makes easier for water, dissolved oxygen and chloride ion etc. to invade toward inner side of coating film due to increasing of the osmotic pressure than 3% NaCl solution, but in the case of higher values of salt solutions than 3% NaCl solution, the coating film is easily deteriorated due to high concentration of chloride ion rather than the osmotic pressure, which resulted in increasing the corrosion current density. In particular, the AC sample indicated the best corrosion resistance in 6% NaCl solution compared to other samples. Consequently, it is considered that the corrosion mechanism of the coated steel plate is completely different from bare steel plate, and the corrosion resistance of coating film by osmotic pressure and chloride ion depend on various types of epoxy of paint in NaCl solution.