• Title/Summary/Keyword: corrosion phenomenon

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Prediction Model of Chloride Penetration in Concrete Bridge Deck Considering Environmental Effects (대기 환경조건을 고려한 콘크리트 교량 바닥판의 염소이온 침투 예측 모델)

  • Kim, Eui-Sung
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.59-66
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    • 2008
  • Recently, the deterioration of reinforced concrete structures, primarily due to corrosion of steel reinforcement, has become a major concern. Chloride-induced deterioration is the most important deterioration phenomenon in reinforced concrete structures in harsh environments. For the realistic prediction of chloride penetration into concrete, a mathematical model was developed in which the effects of diffusion, chloride binding and convection due to water movement can be taken into account. The aim of this research was to reach a better understanding on the physical mechanisms underlying the deterioration process of reinforced concrete associated with chloride-induced corrosion and to propose a reliable method for estimating these effects. Chloride concentrations coming from de-icing salts are significantly influenced by the exposure conditions such as salt usage, ambient temperature and repeated wet-dry cycles.

Estimation on Durability of Concrete Sewage in Kangnung City (강릉시 콘크리트 하수관거의 내구성 평가)

  • Choi, Sung-Ha;Choi, Yoon-Suk;Kim, Kang-Rea;Kim, Myung-Yu;Yang, Eun-Ik
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.229-232
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    • 2006
  • Most of sewage in our country has been made by concrete, and currently they shows gradual deterioration. One of serious problems happened in the sewage is a corrosion of sewage itself. Namely, biochemical corrosion is the most important one. Deterioration phenomenon in concrete used in sewage is occurred by environment condition of sewage, such as erosion by the acid, erosion by sulfate, corrosion by carbonation and so on several factors. However, at present, investigation data on durability of Kangnung city sewage is not sufficient. In addition, the prediction of repair time and selection of rehabilitation method is also not easy. Accordingly, in this research, investigation on durability of sewages located in Kangnung city was carried out. It will also supply the basic data for repair and rehabilitation.

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Effect of Cold Work on the Stress Corrosion Cracking in Austenitic 304 Stainless Steel (오스테나이트 304 스테인레스 강의 응력부식균열에 미치는 냉간가공의 영향)

  • 강계명;최종운
    • Journal of the Korean Society of Safety
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    • v.12 no.1
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    • pp.19-28
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    • 1997
  • This study was made of the effect of cold working on the stress corrosion cracking(SCC) of austenitlc 304 stainless steel in boiling 42% $MgCl_2$ solution. For this experiment, specimens cold-worked of 0%, 10%, 20%, 30%, 40% were fabricated respectively, and then experiments of mechanical properties and stress corrosion cracking(SCC) of these specimens were carried out. The results of these experiments indicate that the maximum resistance to SCC showed at 20% of cold working degree and that the SCC susceptibility depended on the volume fraction of deformation-induced martensite by cold working and the work hardening of matrix. On the other hand, the fracture mode was changed. This phenomenon was considered that deformation-induced martensite was grown from transgranular fracture mode to intergranular fracture mode and caused by increased of dislocation density along the slip planes.

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A Study on Prediction of Metal Loss by Flow-Accelerated Corrosion in the CANDU NPP Secondary Piping Systems (침부식에 의한 CANDU형 원전 2차측 배관의 감육 예측에 관한 연구)

  • Shim, S.H.;Song, J.S.;Yoon, K.B.;Hwang, K.M.;Jin, T.E.;Lee, S.H.;Kim, W.S.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.616-621
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    • 2001
  • Flow-accelerated corrosion(FAC) is a phenomenon that results in metal loss from piping, vessels, and equipment made of carbon steel. FAC occurs only under certain conditions of flow, chemistry, geometry, and material. Unfortunately, those conditions are in much of the high-energy piping in nuclear and fossil-fueled power plants. Also, for domestic NPP secondary pipings whose operating time become longer, more evidences of FAC have been reported. The authors are studying on FAC management using CHECWORKS, computer code developed by EPRI. This paper is on the prediction results of metal loss by FAC in the one of CANDU type NPP secondary piping systems.

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Reliability Analysis Method for Repeated UT Measurement Data in Nuclear Power Plants (원전 배관의 반복 측정 데이터에 대한 신뢰도 분석 방법)

  • Yun, Hun;Hwang, Kyeong-Mo
    • Corrosion Science and Technology
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    • v.12 no.3
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    • pp.142-148
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    • 2013
  • Safety is a major concern in Nuclear Power Plants (NPPs). Piping systems in NPPs are very complex and composed of many components such as tees, elbows, expanders and straight pipes. The high pressure and high temperature water flows inside piping components. As high speed water flows inside piping, the pipe wall thinning occurs in various reasons such as FAC (Flow Accelerated Corrosion), LDIE (Liquid Droplet Impingement Erosion) and Flashing. To inspect the wall thinning phenomenon and protect the piping from damages, piping components are checked by UT measurement in every overhaul. During every overhaul, approximately 200~300 components (40,000~60,000 UT data) are examined in NPPs. There are some methods from EPRI for evaluating wear rate of components. However, only few studies have been conducted to find out the raw data reliability for the wear rate evaluation. Securing the reliable raw data is the key factor for a reasonable evaluation. This paper suggests the reliability analysis method for the repeatedly measured data for wear rate evaluation.

A Study on the Reliability of Plastic BGA Package (플라스틱 BGA 패키지의 신뢰성에 관한 연구)

  • Kim, Gyeong Seop;Sin, Yeong Ui
    • Journal of Welding and Joining
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    • v.18 no.2
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    • pp.222-222
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    • 2000
  • PBGA(Plastic Ball Grid Array) is composed of some materials such as PCB(Printed Circuit Board), epoxy molding compound, die attach and so on. Reliability of PBGA package is weak compared with plastic packages. The weak points of reliability are the lower resistance to popcorn cracking, which is induced by moisture absorption in PCB, and the pressure cooker test corrosion, which is the basic problem due to the material characteristics of PCB. Introducing the PCB baking and the plasma treatment cleared the popcorn cracking phenomenon. The PCB baking and plasma treatment reduced the epoxy void by eliminating the source of moisture vaporization during the epoxy curing and enhanced the adhesion between PCB and epoxy. Also, plasma treatment enhanced the wettability of epoxy on PCB. The problem of corrosion is cleared using multi-functional epoxy. This type of EMC(Epoxy Molding Compound) is recommended in package using PCB as a substrate. (Received November 19, 1999)

A Study on the Reliability of Plastic BGA Package (플라스틱 BGA 패키지의 신뢰성에 관한 연구)

  • 김경섭;신영의
    • Journal of Welding and Joining
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    • v.18 no.2
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    • pp.95-99
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    • 2000
  • PBGA(Plastic Ball Grid Array) is composed of some materials such as PCB(Printed Circuit Board), epoxy molding compound, die attach and so on. Reliability of PBGA package is weak compared with plastic packages. The weak points of reliability are the lower resistance to popcorn cracking, which is induced by moisture absorption in PCB, and the pressure cooker test corrosion, which is the basic problem due to the material characteristics of PCB. Introducing the PCB banking and the plasma treatment cleared the popcorn cracking phenomenon. The PCB banking and plasma treatment reduced the epoxy void by eliminating the source of moisture vaporization during the epoxy curing and enhanced the adhesion between PCB and epoxy. Also, plasma treatment enhanced the wettability of epoxy on PCB. The problem of corrosion is cleared using multi-functional epoxy. This type of EMC(Epoxy Molding Compound) is recommended in package using PCB as a substrate.

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Corrosion Fatigue Cracking Propagation Characteristics and its Protection for the AL-Alloys of Shipbuilding (선박용 알루미늄 합금재의 부식피로균열 진전특성과 그 억제에 관한 연구)

  • Lim, Uh-Joh;Kim, Soo-Byung;Lee, Jin-Yel
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.25 no.2
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    • pp.87-104
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    • 1989
  • Recently, with the tendency of more lightening, high-strength and high-speed in the marine industries such as marine structures, ships and chemical plants, the use of the aluminium Alloy is rapidly enlarge and there occurs much interest in the study of corrosion fatigue crack characteristics. In this paper, the initiation of surface crack and the propagation characteristics on the base metal and weld zone of 5086-H116 Aluminium Alloy Plate which is one of the Al-Mg serious alloy(A5000serious) used most when building the special vessels, were investigated by the plane bending corrosion fatigue under the environments of marine, air and applying cathodic protection. The effects of various specific resistances on the initiation, propagation behavior of corrosion fatigue crack and corrosion fatigue life in the base metal and heat affected zone were examined and its corrosion sensitivity was quantitatively obtained. The effects of corrosion on the crack depth in relation to the uniform surface crack length were also investigated. Also, the structural, mechanical and electro-chemical characteristics of the metal at the weld zone were inspected to verify the reasons of crack propagation behavior in the corrosion fatigue fracture. In addition, the effect of cathodic protection in the fracture surface of weld zone was examined fractographically by Scanning Electron Microscope(S.E.M.). The main results obtained are as follows; (1) The initial corrosion fatigue crack sensitibity under specific resistance of 25Ω.cm% show 2.22 in the base metal and 19.6 in the HEZ, and the sensitivity decreases as specific resistance increases (2) By removing reinforcement of weldment, the initiation and propagation of corrosion crack in the HAZ are delayed, and corrosion fatigue life increases. (3) As specific resistance decreases, the sensitivity difference of corrosion fatigue life in the base metal and HAZ is more susceptible than that of intial corrosion fatigue crack. (4) Experimental constant, m(Paris' rule) in the marine environment is in the range of about 3.69 to 4.26, and as specific resistance increases, thje magnitude of experimental constant, also increases and the effect by corrosion decreases. (5) Comparing surface crack length with crack depth, the crack depth toward the thickness of specimen in air is more deeply propagated than that in corrosion environment. (6) The propagation particulars of corrosion fatigue crack for HAZ under initial stress intensity factor range of $\Delta$k sub(li) =27.2kgf.mm super(-3/2) and stress ratio of R=0 shows the retardative phenomenon of crack propagation by the plastic deformation at crack tip. (7) Number of stress cycles to corrosion fatigue crack initiation of the base metal and the welding heat affected zone are delayed by the cathodic protection under the natural sea water. The cathodic protection effect for corrosion fatigue crack initiation is eminent when the protection potential is -1100 mV(SCE). (8) When the protection potential E=-1100 mV(SCE), the corrosion fatigue crack propagation of welding heat affected zone is more rapid than that of the case without protection, because of the microfissure caused by welding heat cycle.

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A Study on the Behavior in the Corner Crack Propagation of Al-Alloy used for the Shipbuilding by the Corrosion Fatigue (부식피로에 의한 선박용 알루미늄 합금제 용접부의 균열 전파기동에 관한 연구)

  • Im, U-Jo;Lee, Jin-Yeol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.24 no.4
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    • pp.164-171
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    • 1988
  • Recently with the rapid development in marine and shipbuilding industries such as marine structures, ships and chemical plants, it takes much interest in the study of corrosion fatigue characteristics that was close up an important role in mechanical design. In this study, characteristics of corner crack propagation on the base metal and heat affected zone of 5086 Al-Alloy was tested by using of a rotary bending fatigue tester and was investigated under the environments of specific resistance, $\rho$=25$\Omega$ cm and air. The corrosion fatigue crack initiation and corrosion fatigue life sensitivity were quantitatively inspected for 5086 Al-Alloy in the specific resistance, $\rho$=25$\Omega$ cm. Main results obtained are as follows: (1) The corrosion sensitivity of heat affected zone under specific resistance, $\rho$=25$\Omega$cm shows approximately 1.69~2.22 and corrosion sensitivity of base metal is more susceptible than that of heat affected zone. (2) The corrosion fatigue life sensitivity on heat affected zone decreases eminently than that of initial corrosion fatigue crack. (3) The characteristics of quarter elliptical corner crack propagation shows that depth crack is more grown than surface crack at crack initiation, but the surface crack is more propagated than depth crack as the crack propagation is increased. (4) The surface crack and depth crack growth on heat affected zone by softness show delayed phenomenon than that of base metal.

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Effect of Bacteria in Soil on Microbiologically Influenced Corrosion Behavior of Underground X65 Pipeline (토양 속 박테리아가 지하매설 X65 배관의 미생물 부식 거동에 미치는 영향)

  • Choe, Byung Hak;Han, Sung Hee;Kim, Dae Hyun;Kim, Woosik;Kim, Cheolman;Choi, Kwang Su
    • Korean Journal of Materials Research
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    • v.32 no.3
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    • pp.168-179
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    • 2022
  • Microbiologically Influenced Corrosion (MIC) occurring in underground buried pipes of API 5L X65 steel was investigated. MIC is a corrosion phenomenon caused by microorganisms in soil; it affects steel materials in wet atmosphere. The microstructure and mechanical properties resulting from MIC were analyzed by OM, SEM/EDS, and mapping. Corrosion of pipe cross section was composed of ① surface film, ② iron oxide, and ③ surface/internal microbial corrosive by-product similar to surface corrosion pattern. The surface film is an area where concentrations of C/O components are on average 65 %/16 %; the main components of Fe Oxide were measured and found to be 48Fe-42O. The MIC area is divided into surface and inner areas, where high concentrations of N of 6 %/5 % are detected, respectively, in addition to the C/O component. The high concentration of C/O components observed on pipe surfaces and cross sections is considered to be MIC due to the various bacteria present. It is assumed that this is related to the heat-shrinkable sheet, which is a corrosion-resistant coating layer that becomes the MIC by-product component. The MIC generated on the pipe surface and cross section is inferred to have a high concentration of N components. High concentrations of N components occur frequently on surface and inner regions; these regions were investigated and Na/Mg/Ca basic substances were found to have accumulated as well. Therefore, it is presumed that the corrosion of buried pipes is due to the MIC of the NRB (nitrate reducing bacteria) reaction in the soil.