• 한국기계가공학회지
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• 제5권3호
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• pp.86-91
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• 2006

The compressive residual stress, which is inducing by shot peening process, has the effect of increasing the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, it was not known that the effect of shot peening in corrosion environment. In this study, the influence of shot peening and corrosion condition for corrosion property were investigated on immersed in 3.5% NaCl, 10% HNO3 + 3% HF, 6% $FeCl_3$. The immersion test was performed with two kind of specimen. The immersion periods was performed 150days. Corrosion potential, weight loss were investigated from experimental results. From test results, the effect of shot peening on the corrosion characteristics was evaluated.

• Corrosion Science and Technology
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• 제2권1호
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• pp.36-40
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• 2003

An attractive combination of corrosion resistance and mechanical properties in the temperature range -50 to $250^{\circ}C$ is offered by duplex stainless steel. However, undesirable secondary precipitation phase such as $\sigma$, $\gamma_2$ and $Cr_2N$ may taken place at the cooling stage from the welding processes. Therefore, this paper describes the influence of different welding procedures such as manual metal arc welding (MMA), tungsten inert gas welding (TIG) and vacuum brazing on corrosion resistance of the welded joint for UNS S31803 duplex stainless steel. Microstructure and chemical compositions of the welded joint were examined. The weight loss of specimens immersed in 6% $FeCl_3$ solution at $47.5^{\circ}C$ for 24-hours was determined and used to evaluate the pitting resistance of duplex stainless steel and their welds. The region of heat-affected zone of specimen obtained by the MMA is much wider than that resulted from TIG, therefore, the weight loss of welds by MMA was larger than that of weld by TIG. The weight loss of brazed specimens cooled from slow cooling rate was larger than those of specimens cooled from high cooling rate, because the precipitation of $\sigma$ phase. Beside that, the weight loss of brazed specimen is greater than those of the welded specimens. The galvanic corrosion was observed in brazed duplex stainless steel joints in the chloride solution.

• Structural Engineering and Mechanics
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• 제30권6호
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• pp.713-732
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• 2008

Serviceability and durability of the concrete members can be seriously affected by the corrosion of steel rebar. Carbonation front and or chloride ingress can destroy the passive film on rebar and may set the corrosion (oxidation process). Depending on the level of oxidation (expansive corrosion products/rust) damage to the cover concrete takes place in the form of expansion, cracking and spalling or delamination. This makes the concrete unable to develop forces through bond and also become unprotected against further degradation from corrosion; and thus marks the end of service life for corrosion-affected structures. This paper presents an analytical model that predicts the weight loss of steel rebar and the corresponding time from onset of corrosion for the known corrosion rate and thus can be used for the determination of time to cover cracking in corrosion affected RC member. This model uses fully the thick-walled cylinder approach. The gradual crack propagation in radial directions (from inside) is considered when the circumferential tensile stresses at the inner surface of intact concrete have reached the tensile strength of concrete. The analysis is done separately with and without considering the stiffness of reinforcing steel and rust combine along with the assumption of zero residual strength of cracked concrete. The model accounts for the time required for corrosion products to fill a porous zone before they start inducing expansive pressure on the concrete surrounding the steel rebar. The capability of the model to produce the experimental trends is demonstrated by comparing the model's predictions with the results of experimental data published in the literature. The effect of considering the corroded reinforcing steel bar stiffness is demonstrated. A sensitivity analysis has also been carried out to show the influence of the various parameters. It has been found that material properties and their inter-relations significantly influence weight loss of rebar. Time to cover cracking from onset of corrosion for the same weight loss is influenced by corrosion rate and state of oxidation of corrosion product formed. Time to cover cracking from onset of corrosion is useful in making certain decisions pertaining to inspection, repair, rehabilitation, replacement and demolition of RC member/structure in corrosive environment.

• 수산해양기술연구
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• 제35권2호
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• pp.196-200
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• 1999

In the case that erosion and corrosion occurs in machinery and structure at the same time, the synergy effect by erosion-corrosion affects fatal effect to durability of machinery and structure. Therefore, in machinery and structure which use corrosion liquid, the study of the synergy effect of erosion-corrosion which affects metal material is requested. In this paper. the flow corrosion experiment about the effect of temperature change and liquid velocity change in sea water was carried out to study the characteristics of erosion-corrosion for tube material Cu heat exchanger The main results obtained are as follows. (1) Damage appearance of tube outside by erosion-corrosion becomes dull because electrode potentials of Cu tube is higher than electrode potential of STPG38 shell. (2) In the cooling system by sea water, the weight loss rate of Cu at tube outside liquid temperature of $70^{\circ}C$ is higher than that of temperature of $20^{\circ}C$. (3) In cooling system by sea water, the weight loss rate of Cu at liquid velocity of 5.1m/s is higher than that of velocity of 1.47m/s. But as the testing time passed, the weight loss rate of Cu at velocity of 5.1m/s is almost steady and becomes dull at velocity of 1.47m/s.

• 한국표면공학회지
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• 제51권4호
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• pp.218-223
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• 2018

In this study, we proposed a new ultrasonic-chemical decontamination process for decontaminating radioactive corrosion products during the maintenance of reactor coolant pump (RCP). The actual decontamination process was reproduced in the laboratory. And the corrosion characteristics of stainless steel (STS), constituting the RCP interior parts, were examined. The weight-loss measurment and polarization experiment were carried out in order to determine the corrosion characteristics of STS 304 and STS 415 by repeated decontamination processes. The STS 304 presented a little corrosion damage, which was almost indistinguishable from visual observation. The weight-loss rate of STS 304 was also significantly lower. On the other hand, STS 415 showed severe corrosion damage on its surface, greater weight-loss rate and higher corrosion current density than STS 304.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
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• pp.152-157
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• 2001

This paper was studied on the characteristics of crevice corrosion prevention of SS 400 in marine environment. In NaCl solution, polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 applied cathodic protection and non cathodic protection was measured according to the NaCl concentration. The main results obtained are as follows : The weight loss rate of Al-alloy galvanic anode was increased as the concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of Al-alloy galvanic anode become decreased. The protective potential of SS 400 used Al-alloy galvanic anode becomes more cathodic polarization with increasing concentration of NaCl solution. Effects of oxygen on the weight loss rate of Al-alloy sacrificial anode for cathodic protection as the concentration of 3.5% NaCl solution become sensitive than that of 0% NaCl solution.

• 한국표면공학회지
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• 제49권5호
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• pp.431-438
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• 2016

This research investigated the relationship between the corrosion damage characteristics of offshore wind steel substructure and the time of current density application by electrochemical accelerated short-term corrosion test. The galvanostatic corrosion was conducted on the steel specimens in natural seawater with a constant current density ranging from $1mA/cm^2$ to $200mA/cm^2$ for 1 ~ 180 min. Macro and micro observation was carried out on the surface of the corrosion damaged area using SEM and 3-dimensional analysis microscope. The weight loss of the specimens before and after was calculated as the difference between the initial weight prior to corrosion and weight after removal of the corrosion product. It was shown that during galvanostaic corrosion process, the corrosion behavior could be characterized by the onset of pitting corrosion in the early stage and the uniform corrosion in the late stage, showing damage development in the depth direction with the time of current application. The result of the 3D analysis revealed that both damage depth and surface roughness increased with increasing time of current application. The weight loss curves with time showed that a coefficient of determination ($R^2$) was relatively high for the relationship between the time of current application and weight loss. As a result, the degree of corrosion can be controlled by simply varying the time of current application.

• Journal of Advanced Marine Engineering and Technology
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• 제40권10호
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• pp.883-887
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• 2016

This study aims to evaluate the corrosion behavior of a newly developed high-strength steel in marine environments. Metals used in seawater are easily deteriorated because of the presence of corrosive species such as chloride ions in it. Seawater causes much higher corrosion than fresh water. Thus, the corrosion of steel in marine environment has been recognized as a crucial problem in designing structures which cannot be cathodically protected. In this study, the corrosion resistance of a newly developed high-strength steel was evaluated. Four different specimens were tested to confirm the corrosion resistance. The exposure corrosion test was carried out by exposing the specimens to different marine environments such as atmospheric, tidal, splash, and submerged zones for two years. The specimens taken out from each location were cleaned ultrasonically and chemically prior to the evaluation of their corrosion resistance by the weight loss method. Finally, the pitting depth of the specimens was also measured to evaluate their pitting corrosion. The conditions used for the corrosion test were similar to the environmental conditions. The corrosion test results revealed that the corrosion rate and pitting corrosion of the newly developed high-strength steel was lower than that of the other carbon steels.

• Corrosion Science and Technology
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• 제20권2호
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• pp.85-93
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• 2021

The corrosion damage of materials in marine environment mainly occurs by Cl^- ions due to the breakdown of passive films. Additionally, various characteristics in seawater such as salinity, temperature, immersion time, flow rate, and biological activity also affect corrosion characteristics. In this study, the corrosion characteristics of stainless steels (STS 304 and STS 316L) and anodized aluminum alloys (AA 3003 and AA 6063) were evaluated with seawater temperature parameters. A potentiodynamic polarization experiment was conducted in a potential range of -0.25 V to 2.0 V at open circuit potential (OCP). Corrosion current density and corrosion potential were obtained through the Tafel extrapolation method to analyze changes in corrosion rate due to temperature. Corrosion behavior was evaluated by measuring weight loss before/after the experiment and also observing surface morphology through a scanning electronic microscope (SEM) and 3D microscopy. Weight loss, maximum damage depth and pitting damage increased as seawater temperature increased, and furthermore, the tendency of higher corrosion current density with an increase of temperature attributed to an increase in corrosion rate. There was lower pitting damage and lower corrosion current density for anodized aluminum alloys than for stainless steels as the temperature increased.

• Corrosion Science and Technology
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• 제16권5호
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• pp.241-246
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• 2017

The comparative results of corrosion testing in humid tropical atmosphere in rural and coastal areas for hot dipped zinc coatings are presented below. The test was conducted in outdoor conditions over a period of five years. The mass loss and other performance characteristics of two types of zinc coatings were evaluated, analysed and discussed in relation to the climatic and environmental parameters. The corrosion rates of the coatings exposed to coastal conditions were about three times higher than the corrosion rates appreciated in rural conditions. The data demonstrates that the corrosion process obeys an equation of the form $M=At^n$, where M is the loss of metal and t is the time of exposure. A and n are constants which values depend on the environmental characteristics and the physicochemical behavior of the corrosion products respectively. Corrosion is strongly influenced by atmospheric time of wetness (TOW) and airborne salinity. The nature and composition of corrosion products are also considered. Simonkolleite, a major crystalline phase, was found in the zinc corrosion products exposed to coastal conditions, while zinc hydroxide and zinc hydrosulfate are easily found in rural settings.