• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.674-679
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• 1998

Small water leak experiment was carried out in liquid sodium atmosphere using a specimen of ferrite steel, which will be expected to be a material of the heat transfer tube of liquid metal fast breeder reactor. Self-plugging phenomena of leak path could be explained by the products of reaction and corrosion by sodium-water reaction. Also, re-opening mechanism of self-plugged path could be explained by the thermal transient and vibration of heat transfer tube. As a result, perfect re-opening time of self-plugged leak path was observed to be 129 minutes after water leak initiation. Re-opening shape of a specimen was appeared with double layer of circular type, and re-opening size of this specimen surface was about 2 mm diameter on sodium side.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.6
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• pp.90-96
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• 2014

The electrical resistivity of concrete can be related to two processes involved in corrosion of reinforcement: initiation (chloride penetration) and propagation (corrosion rate). The resisistivity of concrete structure exposed to chloride indicates the risk of early corrosion damage, because a low resistivity is related to rapid chloride penetration and to high corrosion rate. Concrete resistivity is a geometry-independent material property that describes the electrical resistance, which is the ratio between applied voltage and resulting current in a unit cell. In previous study, it was realized that the resistivity of concrete depended on the moisture content in the concrete, microstructural properties, and environmental attack such as carbonation. The current is carried by ions dissolved in the pore liquid. While some data exist on the relationship between moisture content on electrical resistivity of concrete, very little research has been conducted to evaluate the effect of chloride on the conduction of electricity through concrete. The purpose of this study is to examine and quantify the effect of chloride content on surface electrical resistivity measurement of concrete. It was obvious that chloride content had influenced the resistivity of concrete and the relationship showed a linear function. That is, concrete with chloride ions had a comparatively lower resistivity. Decreasing rate of resistivity of concrete was clear at early time, however, after 50 days resistivity was constant irrespective of chloride concentration. Conclusively, this paper suggested the quantitive solution to depict the electrical resistivity of concrete with chloride content.

• Computers and Concrete
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• v.20 no.5
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• pp.573-582
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• 2017

Chloride-induced cover cracking will aggravate the performance deterioration for RC structures under the chlorideladen environment, which may endanger the safety of structures and occupants. Traditional design method cannot ensure that a definite performance is satisfied. To overcome the defects, a study on the performance-based design method was carried out in this paper. Firstly, the limit state functions were established for the corrosion initiation and cover cracking. Thereafter, the uncertainty analysis was performed to study the effects of random factors on the time-dependent performances. Partial factor formulae were deduced through the first-order reliability method for performance verification. Finally, an illustrative example was presented and the sensitivity of cover depth to other parameters was carried out. It is found that the uncertainties of the random variables have great effects on the required cover depth. It is demonstrated that the performance-based design method can ensure that the target performance can be satisfied and support to formulate a rational maintenance and repair strategy for RC structures under the chloride environment.

• Korean Journal of Materials Research
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• v.3 no.4
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• pp.361-371
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• 1993

Among the various test methods for stress corrusiun cracking(SCC) susceptibility evaluatiun, the slow stram rate test(SSHT) method is a rapid and effective nwthod to evaluate the SCC susceptibility of metal in relatively short time. But it is very difficult to analyze the microfracture behaviors in SCC process by using the test(SSRT) method only. Up to now, it has been well known that the acoustic emission(AE) test is the effective technique to monitor the microcrack initiation and propagation in material fracture pmcess. Therefore. in this paper, we analyzed the correlation between the see process and the characteristics of AE signal by using the SSHT and the AE test. According to the test results. the AE signals produced from the material microfracture were clearly depended on the test environment. The AE signal characteristics generated during see process in synthetic sea water were comparatively greater than those. in air. In addition, the SCC behaviors could be definitely evaluated by the amplitude parameter of AE signals.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.4
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• pp.57-64
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• 2022

Chloride, which is one of the main deterioration factors in reinforced concrete structures, can degrade the performance of the structure due to chloride-induced corrosion of steel. Chloride content at steel depth or the rate of chloride penetration is necessary to determine deterioration of reinforced concrete or to calculate initiation time of steel corrosion caused by chloride attack. Chlorides in concrete are generally identified with typical two methods including chloride profiling using potentiometric titration method and discoloration method using AgNO₃ solution. The former is advantageous to estimate chloride penetration rate (diffusion coefficient in general) with measured chloride contents directly, but it is laborious. In the case of latter, while the result is obtained easily with the range of discoloration, the error may occur depending on workmanship when the depth of chloride ingress is measured. This study shows that chloride penetrated depth is evaluated with the results obtained from discoloration method through image analysis, thereby the error is minimized by workmanship. In addition, the effect of micro-crack in concrete is studied on chloride penetration. In conclusion, the depth of chloride penetration was quantified with image analysis and as it was confirmed that chlorides can rapidly penetrate through micro-cracks, caution is especially required for cracks in concrete structure.

• Journal of the Korea Concrete Institute
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• v.27 no.1
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• pp.85-92
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• 2015

The chloride ions, responsible for the initiation of the corrosion mechanism, intrude from the external medium into the concrete. A part of the intruding chloride ions will be retained by the hydration products of the binder in concrete, either through chemical adsorption or by physical adsorption. Since the hydration products of cement are responsible for the chloride binding in concrete, this study focused on the chloride binding in individual hydrate. The purpose of this study is to explore the time dependant behaviors of chloride ions adsorption with cement hydrates, focused on its mechanism. AFt phase and CH phase were not able to absorb chloride ion, however, C-S-H phase and AFm phase had a significant chloride adsorption capacity. In particular, AFm phase showed a chemical adsorption with slow rate in 40 days, while C-S-H phase showed binding behaviors with 3 stages including momentary physical adsorption, physico-chemical adsorption, and chemical adsorption. Based on the results, this study suggested theoretical approach to depict chloride adsorption behavior with elapsed time of C-S-H phase and AFm phase effectively. It is believed that the approach suggested in this study can provide us with a good solution to understand the mechanism on chloride adsorption with hydrates and to calculate a rate of chloride penetration with original source of chloride ions, for example, marine sand at initial time or sea water penetration later on.