• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.2
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• pp.374-379
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• 2002

Corrosion fatigue tests were carried out to clarify the influence of acid fog as environmental factor on the fatigue strength of SM55C using rotary bending fatigue tester. The fatigue strength of acid fog specimen extremely decreased about 80% compared to that of distilled water specimen. In acid fog environment, a number of cracks commenced at corrosion pit and coalesced with the adjacent cracks during they propagate, and they formed a single non-propagating circumferential crack under the endurance stress of N=5$\times$10$\^$7/ cycles. Also, the depth of the crack is smaller than that of normal fatigue crack, so the crack has a veil small aspect ratio. The reason of this peculiar crack growth characteristics is that the crack opening-closure behaviors are hindered by corrosion products on the surface crack faces, and hence it is thinkable that the strong corrosion action like anodic dissolution for crack growth in depth direction is weaker compared with surface, resulting from faint pumping action of crack during loading-shedding processes.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.110-115
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• 2009

At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.3
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• pp.447-452
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• 2003

Crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. Such stagnant micro environments tend to occur in crevices (shielded areas) such as those formed under gaskets washers insulation material. fastener heads. surface deposits. disbonded coatings. threads. lap joints and clamps. Crevice corrosion is initiated by changes in located electrochemical reaction within the crevice such as a) depletion of inhibitor in the crevice b) depletion of oxygen in the crevice c) a shift to acid conditions in the crevice and d) build-up of aggressive ion species (e.g chloride) in the crevice. In this study. the mechanism of crevice corrosion for Type 430 stainless steel is investigated undercondition that the size of specimen is $15{\times}20\{times}3mm$, in 1N $H_2SO_4$ + 0.05N NaCl solution. and the artificial crevice gap size of 3 x 0.2 x 15 mm. Crevice corrosion is measured under applied potential -300mV(SCE) to the external surface. The obtained result of this study showed that 1) the induced time for initiation of crevice is 750 seconds. 2) potential of the crevice was about from -320mV to -399mV. which is lower than that of external surface potential of -300mV It is considered that potential drop in the crevice is one of mechanisms for the crevice corrosion

• Proceedings of the KSR Conference
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• 2003.10c
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• pp.558-567
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• 2003

The catenary wires are damaged by periodic running of train as well as repeated stress. The wires are also degraded by atmosphere corrosion at fields. Corrosion of wires increased surface roughness and deteriorated mechanical properties by providing fatigue crack initiation sited resulting in a bad effect on service life of the wires. Fatigue test of catenary wires performed to estimate service lifetime. Also, simulation to analyze stress on catenary wires was conducted through modelling the finite elements for dynamic behaviors of wires. Fatigue life of catenary wires was estimated with fatigue and simulation tests.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.203-206
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• 1998

In reinforced concrete carbonation of concrete leads to depassivation of the reinforcement, and hence to initiation of corrosion. As a result of carbonation accelerating experiment with using effect of wet-dry cycle and 15% concentration of CO ₂, the carbonation rate shows very distinct difference according to W/C ratio. OPC-40 estimated no carbonation depth, whereas OPC-60 estimated rapidly the carbonation rate. The comparative analysis of the carbonation rate accelerating depends on different kinds of cement shows fastest FAC-20. Also, highly W/C ratio's concrete shows low half-cell potential value and fast corrosion rate. During period for 14 weeks. corrosion rate was not severe. So, it can be concluded that only carbonation attack on concrete doesn't severly deteriorated except very poor qualitified concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05a
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• pp.15-30
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• 2005

The increasing amount of structures presenting distress due to reinforcement corrosion is urging the establishment of more accurate calculation methods for the service life of concrete structures. In the present paper, a summary of the different approaches is presented that are able to calculate the expected life of new structures, in certain aggressive environments or the residual life of already corroding structures. The methods for the initiation period are based on the proper calculation of the carbonation front or chloride penetration and on the steel corrosion rate. The methods for the residual load-bearing capacity calculations are based in the use of ' indicators ' or in the evaluation of the reduced section and a structural recalculation.

• Proceedings of the KIEE Conference
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• 2004.11a
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• pp.223-226
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• 2004

Many extensive researches in the area of sensor's technology for corrosion monitoring in concrete structures have increasingly been carried out in recent years. This paper gives a brief discussion on the principles and usage of the role of sensors involved in both corrosion initiation and propagation steps of reinforcement corrosion monitoring in concrete structures. Special attention was given to the review of various sensing devices, selection of reliable sensing devices for detecting reinforcement corrosion at the particular environment and at the efficiency of the devices used. Various sensing operations in new and existing concrete structures are also described.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.65-66
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• 2021

In this study, the optimum amount of hybrid inhibitors i.e. L-Arginine (LA) and sodium phosphate tribasic dodecahydrate (SP), applied for carbon steel rebar in simulated pore concrete (SCP) solution contaminated with 3.5 wt.% NaCl, was discovered. The corrosion inhibition performance of hybrid inhibitors was investigated by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization. The highest corrosion inhibition efficiency was found as 99.52% corresponding to 2% LA and 0.25% SP after 210 h exposure. Anodic type inhibition action was confirmed by potentiodynamic polarization study. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate with electrochemical studies.

• Journal of Welding and Joining
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• v.11 no.2
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• pp.42-52
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• 1993

The corrosion fatigue fracture behaviour of dual phase steel was investigated in 3% NaCl solution at 302MPa and 137MPa. Fatigue test was conducted by cantilever type of self-made rotary bending fatigue testing machine. The fatigue strength increased with increasing the hardness of 2nd phase. Corrosion pit originated at the boundary of the 2nd phase. The size and number of corrosion pits were influenced by the 2nd phase hardness, and pits remained constant in size just after they were transited into cracks. The life of crack initiation was effected by stress level. The shape of relation of .DELTA. K and da/dN has smaller scattering in it in 3% NaCl solution than that in air. The higher the 2nd phase hardness is, the greater the corrosion fatigue life becomes. Corrosion fatigue fracture behaviour was primarily effected by mechanical factor in case of high stress(302MPa), but by electro-chemical reaction in a lower stress(137MPa). As stress level got lower and hardness of the 2nd phase got higher, the roughness of fracture surface increased.

• Computers and Concrete
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• v.15 no.4
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• pp.643-671
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• 2015

Chloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete members, whose economic and social consequences are growing up continuously. Prevention of these phenomena has a great importance in structural design, and modern Codes and Standards impose prescriptions concerning design details and concrete mix proportion for structures exposed to different external aggressive conditions, grouped in environmental classes. This paper focuses on reinforced concrete column section load carrying capacity degradation over time due to chloride induced steel pitting corrosion. The structural element is considered to be exposed to marine environment and the effects of corrosion are described by the time degradation of the axial-bending interaction diagram. Because chlorides ingress and consequent pitting corrosion propagation are both time-dependent mechanisms, the study adopts a time-variant predictive approach to evaluate residual strength of corroded reinforced concrete columns at different lifetimes. Corrosion initiation and propagation process is modelled by taking into account all the parameters, such as external environmental conditions, concrete mix proportion, concrete cover and so on, which influence the time evolution of the corrosion phenomenon and its effects on the residual strength of reinforced concrete columns sections.