• Title/Summary/Keyword: corrosion initiation

Search Result 188, Processing Time 0.023 seconds

Prediction of RC structure service life from field long term chloride diffusion

  • Safehian, Majid;Ramezanianpour, Ali Akbar
    • Computers and Concrete
    • /
    • v.15 no.4
    • /
    • pp.589-606
    • /
    • 2015
  • It is well-documented that the major deterioration of coastal RC structures is chloride-induced corrosion. Therefore, regional investigations are necessary for durability based design and evaluation of the proposed service life prdiction models. In this paper, four reinforced concrete jetties exposed to severe marine environment were monitored to assess the long term chloride penetration at 6 months to 96 months. Also, some accelerated durability tests were performed on standard samples in laboratory. As a result, two time-dependent equations are proposed for basic parameters of chloride diffusion into concrete and then the corrosion initiation time is estimated by a developed probabilistic service life model Also, two famous service life prediction models are compared using chloride profiles obtained from structures after about 40 years in the tidal exposure conditions. The results confirm that the influence of concrete quality on diffusion coefficients is related to the concrete pore structure and the time dependence is due to chemical reactions of sea water ions with hydration products which lead a reduction in pore structure. Also, proper attention to the durability properties of concrete may extend the service life of marine structures greater than fifty years, even in harsh environments.

An Experimental Study on Corrosion Fatigue Strength of TMCP Steel in Consideration of NaCl Salinity (염분농도변화에 따른 TMCP강의 부식피로강도에 관한 실험적 연구)

  • 강성원;김철현;이해우
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.40 no.3
    • /
    • pp.54-60
    • /
    • 2003
  • Fatigue strength of offshore structures or ship structures is significantly decreased due to corrosive environment condition such as sea water and/or coal, crude oil of cargoes, compared to that of on shore structures. In corrosive environment, fatigue strength of structures also depends on characteristics of weld material heat affected zone(HAZ). In this research work, rotary bending fatigue tests of parent material and HAZ of TMCP steel were performed in order to investigate the initiation and propagation of cracks both in air and in NaCl solution. Comparison of fatigue strength In relation with the salinity of NaCl were carried out as well. According to the test results weld material or HAZ of TMCP steel showed higher fatigue strength than that of the parent material. The fatigue strength of TMCP steel decreases drastically in NaCl solution compared to that of in air environment. In particular, more reduced fatigue strength is observed in 1% NaCl solution than in 3% NaCl solution.

Long-Term Experiments for Demonstrating Durability of a Concrete Barrier and Gas Generation in a Low-and Intermediate-Level Waste Disposal Facility

  • Kang, Myunggoo;Seo, Myunghwan;Kim, Soo-Gin;Kwon, Ki-Jung;Jung, Haeryong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.19 no.2
    • /
    • pp.267-270
    • /
    • 2021
  • Long-term experiments have been conducted on two important safety issues: long-term durability of a concrete barrier with the steel reinforcements and gas generation from low-and intermediate-level wastes in an underground research tunnel of a radioactive waste disposal facility. The gas generation and microbial communities were monitored from waste packages (200 L and 320 L) containing simulated dry active wastes. In the concrete experiment, corrosion sensors were installed on the steel reinforcements which were embedded 10 cm below the surface of concrete in a concrete mock-up, and groundwater was fed into the mock-up at a pressure of 2.1 bars to accelerate groundwater infiltration. No clear evidence was observed with respect to corrosion initiation of the steel reinforcement for 4 years of operation. This is attributed to the high integrity and low hydraulic conductivity of the concrete. In the gas generation experiment, significant levels of gas generation were not measured for 4 years. These experiments are expected to be conducted for a period of more than 10 years.

Life-Cycle Cost-Effective Optimum Design of Steel Bridges Considering Environmental Stressors (환경영향인자를 고려한 강교의 생애주기비용 최적설계)

  • Lee, Kwang Min;Cho, Hyo Nam;Cha, Cheol Jun
    • Journal of Korean Society of Steel Construction
    • /
    • v.17 no.2 s.75
    • /
    • pp.227-241
    • /
    • 2005
  • This paper presents a practical and realistic Life-Cycle Cost (LCC) optimum design methodology for steel bridges considering the long-term effect of environmental stressors such as corrosion and heavy truck traffics on bridge reliability. The LCC functions considered in the LCC optimization consist of initial cost, expected life-cycle maintenance cost, and expected life-cycle rehabilitation costs including repair/replacement costs, loss of contents or fatality and injury losses, road user costs, and indirect socio-economic losses. For the assessment of the life-cycle rehabilitation costs, the annual probability of failure, which depends upon the prior and updated load and resistance histories, should be accounted for. For the purpose, Nowak live load model and a modified corrosion propagation model, which takes into consideration corrosion initiation, corrosion rate, and repainting effect, are adopted in this study. The proposed methodology is applied to the LCC optimum design problem of an actual steel box girder bridge with 3 continuous spans (40m+50m+40m=130m). Various sensitivity analyses are performed to investigate the effects of various design parameters and conditions on the LCC-effectiveness. From the numerical investigation, it has been observed that local corrosion environments and the volume of truck traffic significantly influence the LCC-effective optimum design of steel bridges. Thus, these conditions should be considered as crucial parameters for the optimum LCC-effective design.

An Electrochemical Evaluation on the Crevice Corrosion of 430 Stainless Steel with Variation of Crevice Wide by Micro Capillary Tubing Method (Micro Capillary Tube 방법을 이용한 430 스테인레스강 틈의 폭변화에 따른 틈부식의 전기화학적 평가)

  • Na, Eun-Young
    • Journal of the Korean Electrochemical Society
    • /
    • v.6 no.4
    • /
    • pp.250-254
    • /
    • 2003
  • In this study, the IR drop theory was adopted to explain the initiation of crevice corrosion in the framework of IR drop in crevice electrolyte. Furthermore, the electrochemical polarization was measured to study the mechanism of crevice corrosion for type STS430 stainless steel. lest method adopts under condition that the size of specimen is $10\times20\times5mm,\;in\;1N\;H_2SO_4+0.1N\;NaCl$ solution, and the artificial crevice gap sizes are three kinds, the Micro capillary tube size is inner diameter 0.04 mm, outer diameter 0.08 mm. Crevice corrosion is measured under the applied voltage of passivation potential -200mV/SCE, resulted from anodic potentio-dynamic polarization to the external surface along the crevice. The potential difference was measured by depth profile by Micro capillary tube which inserted in the crevice. The obtained results of this study showed that 1) As artificial crevice gap size became narrow, the current density was increased, whereas no crevice corrosion was found in the crevice gap size $3\times0.5\times16mm\;in\;1N\;H_2SO_4+0.1N\;NaCl\;solution\;at\;20^{\circ}C$ 2) potential of the crevice was about from -220 to -358mV which is lower than that of external surface potential of -200mV The results so far confirmes that the potential drop(so-called IR drop) in the crevice is one of the major mechanisms the process of crevice corrosion for 430 stainless steel.

Characteristics of OCP of Reinforced Concrete Using Socket-type Electrodes during Periodic Salt Damage Test (주기적 염해 시험에 따른 소켓 타입 전극을 활용한 철근 콘크리트의 OCP 특성)

  • Lee, Sang-Seok;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.25 no.4
    • /
    • pp.28-36
    • /
    • 2021
  • It is known that buried rebars inside concrete structures are protected from corrosion due to passive layer. It is very important to delay the timing of corrosion or evaluate a detection of corrosion initiation for the purpose of cost-beneficiary service life of a structure. In this study, corrosion monitoring was performed on concrete specimens considering 3 levels of cover depth(60 mm, 45 mm, and 30 mm), W/C(water to cement) ratio(40.0%, 50.0%, and 60.0%) and chloride concentration(0.0%, 3.5%, and 7.0%). OCP(Open Circuit Potential) was measured using agar-based socket type sensors. The OCP measurement showed the consistent behavior where the potential was reduced in wet conditions and it was partially recovered in dry conditions. In the case of 30 mm of cover depth for most W/C ratio cases, the lowest OCP value was measured and rapid OCP recovery was evaluated in increasing cover depth from 30 mm to 45 mm, since cover depth was an effective protection against chloride ion ingress. As the chloride concentration increased, the effect on the cover depth tended to be more dominant than the that of W/C ratio. After additional monitoring and physical evaluation of chloride concentration after specimen dismantling, the proposed system can be improved with increasing reliability of the corrosion monitoring.

A Study on Rotary Bending Fatigue Strength of the $CO_2$ Gas Welded Joint in Air and Sea Water ([$CO_2$] 용접이음재의 대기 및 해수중에서의 회전굽힘 피로강도에 관한 연구)

  • S.W. Kang;S.Y. Lee
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.37 no.2
    • /
    • pp.118-126
    • /
    • 2000
  • TMCP steel has been widely used to construct ships and offshore structures. When it comes to ship and offshore structures, corrosion fatigue damages caused by sea water and fatigue occurred by wave-induced forces usually go on occurring simultaneously. So the fatigue life in corrosion environment is decreased markedly in comparison with that in air. The fatigue crack in corrosion easily initiates on welded joints of structure like as the fatigue crack in air. Therefore it is very important to study the fatigue properties of those of their welded joints as well as steel plates. In this study, rotary bending fatigue tests have been performed to investigate fatigue crack initiation and behavior of fatigue crack growth on CO2 gas weld HAZ of TMCP steel. The fatigue test used the specimens with various stress concentration factors in air and 3% NaCl solution

  • PDF

Variation of Critical Chloride Content of Rebar Embedded in Concrete with Admixture (혼화재 혼입에 따른 콘크리트에 매립된 철근의 부식 임계 염화물량의 변화)

  • Park, Jang-Hyun;Lee, Yun-Su;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
    • /
    • v.19 no.6
    • /
    • pp.511-520
    • /
    • 2019
  • The critical chloride content of rebar embedded in concrete was experimentally evaluated according to the admixture replacement ratio and admixture type. Four types of reinforced concrete were mixed OPC 100%, OPC 70% + GGBFS 30%, OPC 40% + GGBFS 60%, and OPC 40% + GGBFS 40% + FA 20%. NaCl solution was supplied to the specimens, and the open circuit potential of the embedded rebar was monitored. The specimens determined to initiate corrosion were cut at intervals of 5mm from the NaCl solution supply surface and conducted to chlorine ion profile. Corrosion initiation time of rebar embedded in concrete was delayed as the admixture replacement ratio increased. Looking at the critical chloride content of the types of reinforced concrete, it was highest in OPC 1.46kg/㎥, followed in order by S30 0.98kg/㎥, TBC 0.74kg/㎥, and S60 0.71kg/㎥.

Effects of Expanding Methods on Residual Stress of Expansion Transition Area in Steam Generator Tube of Nuclear Power Plants (원전 증기발생기 전열관 확관법이 확관부위 잔류응력에 미치는 영향)

  • Kim, Young Kyu;Song, Myung Ho
    • Journal of Energy Engineering
    • /
    • v.21 no.4
    • /
    • pp.362-372
    • /
    • 2012
  • The steam generator tubes of nuclear power plants are pressure boundaries, and if tubes are leaked, the coolant with the radioactive materials was flowed out from the primary system to the secondary system and polluted the plant and the air. Recently most crack defects of tubes are stress corrosion cracks and these defects are located in expansion transition area, sludge pile-up region, and U-bend area. The most effective one of crack initiation factors in expansion transition area and U-bend area is the residual stress. According to the experiences of Korea standard nuclear plants(Optimized Power Reactor-1000), they had the stress corrosion cracks at the tube expansion transition area in early operating stage and especially lots of circumferential cracks were occurred. Therefore in this study, the distributions and conditions of residual stresses by tube expansion methods were compared and the dominant reason of a specific direction was examined.

Remaining Service Life Prediction of Concrete Structures under Chloride-induced Loads (염해환경하의 콘크리트 구조물의 잔존수명 예측)

  • Song, Ha-Won;Luc, Dao Ngoc The
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.1037-1040
    • /
    • 2008
  • In order to predict the remaining life of marine concrete structures under climatic loads, it is necessary to develop an analytical approach to predict the time and space dependent deterioration of concrete structures due to mainly chloride attack up to corrosion initiation and additional deterioration like cracking of cover concrete. This study aims to introduce FEM model for life-time simulation of concrete structures subjected to chloride attack. In order to consider uncertainties in materials as well as environmental parameters for the prediction, Monte Carlo Simulation is integrated in that FEM modeling for reliability-based remaining service life prediction. The paper is organized as follows: firstly general scheme for reliability-based remaining service life of concrete structures is introduced, then the FEM models for chloride penetration, corrosion product expansion and cover cracking are briefly explained, finally an example is demonstrated and the effects of localization of chloride concentration and corrosion product expansion on service life using above model are discussed.

  • PDF