• 제목/요약/키워드: corrosion initiation

검색결과 191건 처리시간 0.025초

Al-Alloy 7075-T651의 부식피로균열 성장거동에 관한 연구(I) (A Study on Corrosion Fatigue Crack Growth Behavior in Al-Alloy 7075-T651 (I))

  • 김봉철;한지원;우흥식
    • 한국안전학회지
    • /
    • 제13권4호
    • /
    • pp.113-120
    • /
    • 1998
  • Fatigue crack growth rates(i.e. crack initiation and crack growth of short and long crack) are investigated using commercial plates of high strength Al alloy 7075-T651 for the transverse-longitudinal(T-L) direction in air, water and sea water. Also, the evaluation direct current potential drop(D.C.P.D) method and the fractographical analysis by SEM are carried out. Near threshold region, short crack growth rates were much faster than those of comparable long cracks, and these short crack growth rates actually decrease with increasing crack growth and eventually merge with long crack data. Fatigue crack propagation rates in aggressive media(i.e. sea water) increase noticeably over three times those in air. One of the most significant characters in this phenomenon as a corrosion-fatigue causes an acceleration in crack growth rates. Sea water environment, particularly Cl$^{[-10]}$ solution brings the most detrimental effects to aluminum alloy. The result of fractographical morphology in air, water and sea water by SEM shows obvious dimpled rupture and typical striation in air, but transgranular fracture surface in water and sea water.

  • PDF

콘크리트 중의 염소이온 확산 특성에 관한 실험적 연구 (A Experimental Study on the Chloride Diffusion Properties in Concrete)

  • 박승범;김도겸
    • 콘크리트학회논문집
    • /
    • 제12권1호
    • /
    • pp.33-44
    • /
    • 2000
  • Since the mechanism of chloride diffusion and its ratio in concrete depend on structural conditions and concrete as a micro-structure, if these are analyzed quantitatively, the long-term ageing of structures can be predicted. Although, a quantitative analysis of concrete micro-structure, in which the results are affected by various parameters, is very difficult, this can be done indirectly by the durability test of concrete. In this study, the compressive strength, void ratio and air permeability of concrete. In this study, the compressive strength, void ratio and air permeability of concrete are chosen as the parameters in concrete durability test, and these effects on test results are analysed according to changes of mixing properties. The relationships between parameters and chloride diffusion velocity is used for prediction models of chloride diffusion. The developed prediction models for the chloride diffusion according to mixing and physical properties, can be used to estimate the service life and corrosion initiation of reinforcing bars in marine structures.

해양 대기 환경 하에서 탄산화 콘크리트에 대한 염소이온 침투 해석 (Analysis on Penetration of Chloride Ion into Carbonated Concrete in Marine Atmospheric Conditions)

  • 최두만;장승엽
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
    • /
    • pp.233-236
    • /
    • 2006
  • Chloride attack and carbonation induced corrosion of reinforcement are those of the main factors which cause the deterioration of concrete structures. The objective of this study is to suggest an analytic model for the prediction of chloride penetration into carbonated concrete, in order to make up for the current codes. Carbonation depth model considering the moisture effect is validated by being compared with the test data and the analytic model on chloride penetration into carbonated concrete is developed. Finally, the corrosion-initiation time has been predicted by the present model, being compared with that by the current code equation. The comparison shows that the current code equation can underestimate the chloride penetration into carbonated concrete in marine atmospheric conditions.

  • PDF

PFM APPLICATION FOR THE PWSCC INTEGRITY OF Ni-BASE ALLOY WELDS-DEVELOPMENT AND APPLICATION OF PINEP-PWSCC

  • Hong, Jong-Dae;Jang, Changheui;Kim, Tae Soon
    • Nuclear Engineering and Technology
    • /
    • 제44권8호
    • /
    • pp.961-970
    • /
    • 2012
  • Often, probabilistic fracture mechanics (PFM) approaches have been adopted to quantify the failure probabilities of Ni-base alloy components, especially due to primary water stress corrosion cracking (PWSCC), in a primary piping system of pressurized water reactors. In this paper, the key features of an advanced PFM code, PINEP-PWSCC (Probabilistic INtegrity Evaluation for nuclear Piping-PWSCC) for such purpose, are described. In developing the code, we adopted most recent research results and advanced models in calculation modules such as PWSCC crack initiation and growth models, a performance-based probability of detection (POD) model for Ni-base alloy welds, and so on. To verify the code, the failure probabilities for various Alloy 182 welds locations were evaluated and compared with field experience and other PFM codes. Finally, the effects of pre-existing crack, weld repair, and POD models on failure probability were evaluated to demonstrate the applicability of PINEP-PWSCC.

감육된 탄소강배관의 변형과 파괴거동 (Deformation and Fracture Behavior of Wall Thinned Carbon Steel Pipes)

  • 안석환;남기우
    • 한국해양공학회지
    • /
    • 제20권4호
    • /
    • pp.17-23
    • /
    • 2006
  • Monotonic four-point bending tests were conducted on straight pipe specimens, 102 mm in diameter with local wall thinning, in order to investigate the effects of the depth, shape, and location of wall thinning on the deformation and failure behavior of pipes. The local wall thinning simulated natural erosion/corrosion metal loss. The deformation and fracture behavior of the straight pipes with local wall thinning was compared with that of non wall-thinning pipes. The failure modes were classifiedas local buckling, ovalization, or crack initiation, depending on the depth, shape, and location of the local wall thinning. Three-dimensional elasto-plastic analyses were carried out using the finite element method. The deformation and failure behavior, simulated by finite element analyses, coincided with the experimental results.

수소유기 균열된 APi-X80 강재의 파면 분석 (Analysis of Fracture Surface of API-X-80 Steel Failed by Hydrogen Induced Cracking)

  • 김마로;구다영;최용
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2015년도 춘계학술대회 논문집
    • /
    • pp.124-124
    • /
    • 2015
  • Acoustic microscopy and scanning electron microscopy were applied to non-destructively evaluate the hydrogen-induced cracking of API X-80 steels and to find the initiation time of the crack. The API X-80 steel had the average grain size of about $4-10{\mu}m$. The hardness was reduced from 240 to 202 [Hv] after exposing in HIC environment for 2-days. Friction coefficient and wear loss were 0.745 and 0.392 mm, respectively. Empirical equation of corrosion potential and corrosion rate of the steel with HIC time in $5%NaCl-0.5%CH_3COOH$ at $25^{\circ}C$ were $Eh\;(up)=0.06^*t[day]+0.2951$, $Eh(down)=0.376^*t[day]+0.5938$, respectively. HIC grew with micro-size after 1-day exposure. The HIC tended to propagate on the surface with Al, Si, Ti, and Mn.

  • PDF

건습반복 부식촉진시험 및 장기폭로시험의 상관성에 대한 연구 (A Study on Correlation Between Cyclic Drying-Wetting Accelerated Corrosion Test and Long-term Exposure Test)

  • 박상순
    • 한국구조물진단유지관리공학회 논문집
    • /
    • 제20권4호
    • /
    • pp.136-143
    • /
    • 2016
  • 염해에 의한 철근콘크리트 구조물의 내구수명을 평가하는 방법에는 여러 가지가 있지만, 가장 확실한 방법은 염해환경에 노출된 시편에 대한 철근 부식시험을 시행하는 것이다. 그러나 이러한 방법은 장기간이 소요된다는 단점이 있으며 이를 보완한 촉진부식시험 결과는 장기시험과의 상관성이 규명되지 않아 적용에 한계가 따른다. 따라서 본 연구에서는 부식촉진시험과 장기폭로시험간의 상관성을 분석하는 것을 연구의 목표로 한다. 부식속도가 가장 빠른 간만대 환경을 모사한 최적 건습반복시험방법을 찾고 해양환경폭로시험장의 간만대에 장기간 노출된 시편의 철근부식모니터링 시험결과와의 비교를 통해 촉진부식시험과 장기폭로시험간의 상관계수를 도출하였다. 또한 재료의 배합별 특성을 파악하기 위해 물,결합재비 60%를 기준으로 플라이애시를 20% 치환한 배합과 고로슬래그 미분말을 30% 치환한 배합을 비교하였으며, 물-결합재비가 35%인 고강도 배합에 대해서도 시험을 실시하였다. 반전지전위법에 의한 부식 모니터링 결과 일정기간의 건조와 습윤의 반복 조건보다는 염수를 시편 상부에 침지시켜 염수 및 산소의 공급이 계속되는 염수 ponding 시험법이 24~36% 정도 부식을 촉진시키는 것으로 나타났다. 각 배합별로는 모든 시험법에서 OPC60, FA, BS, OPC35 순으로 부식이 발생하였다. 간만대의 장기폭로시험과의 상관성 분석 결과 건습반복 부식촉진시험의 경우 4.23~5.52의 상관계수를 가지고 있었으며, 염수 ponding 시험법의 경우 6.54~7.82의 상관계수를 나타내었다.

ASSESSMENT OF POSSIBILITY OF PRIMARY WATER STRESS CORROSION CRACKING OCCURRENCE BASED ON RESIDUAL STRESS ANALYSIS IN PRESSURIZER SAFETY NOZZLE OF NUCLEAR POWER PLANT

  • Lee, Kyoung-Soo;Kim, W.;Lee, Jeong-Geun
    • Nuclear Engineering and Technology
    • /
    • 제44권3호
    • /
    • pp.343-354
    • /
    • 2012
  • Primary water stress corrosion cracking (PWSCC) is a major safety concern in the nuclear power industry worldwide. PWSCC is known to initiate only in the condition in which sufficiently high tensile stress is applied to alloy 600 tube material or alloy 82/182 weld material in pressurized water reactor operating environments. However, it is still uncertain how much tensile stress is re-quired to generate PWSCC or what causes such high tensile stress. This study was performed to pre-dict the magnitude of weld residual stress and operating stress and compare it with previous experi-mental results for PWSCC initiation. For the study, a pressurizer safety nozzle was selected because it is reported to be vulnerable to PWSCC in overseas plants. The assessment was conducted by nu-merical analysis. Before performing stress analysis for plant conditions, a preliminary mock-up ana-lysis was done. The result of the preliminary analysis was validated by residual stress measurement in the mock-up. After verification of the analysis methodology, an analysis under plant conditions was conducted. The analysis results show that the stress level is not high enough to initiate PWSCC. If a plant is properly welded and operated, PWSCC is not likely to occur in the pressurizer safety nozzle.

ACOUSTIC EMISSION BEHAVIOR DURING STRESS CORROSION CRACKING OF INCONEL 600

  • Sung, Key-Yong;Cho, Sang-Jin;Kim, Bong-Hyun;Kim, In-Sup
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1996년도 춘계학술발표회논문집(3)
    • /
    • pp.145-150
    • /
    • 1996
  • Acoustic Emission (AE) technique was applied to stress corrosion cracking of Inconel 600 to investigate the AE capability of detecting crack growth and to obtain the relation between AE characteristics and crack mechanism. The specimens were heat-treated in two conditions (600$^{\circ}C$ for 30 hrs or 700 $^{\circ}C$ for 1 hr) and undergone CERT at two extension rates ( 2.5${\times}$10$^{-5}$ or 1.25${\times}$10$^{-4}$(mm/s)). It was found that the AE peak amplitude from plastic deformation was generally smaller than about 48dB (0.25mV), while Intergranular stress corrosion cracking (IGSCC) and ductile fracture produced higher values of 49 to 70dB (0.3mV to 3mV). The slopes of cumulative amplitude distribution (b-values) were linearly dependent on IGSCC susceptibility and the higher the susceptibility, the smaller the b-value. The monitoring of combined AE parameters such as event rate, amplitude, count and energy can provide effective means to clearly identify the transition from crack initiation and small crack growth to rapid growth of dominant cracks.

  • PDF

현수교케이블의 응력부식에 관한 신뢰성해석 (Reliability Analysis for Stress Corrosion Cracking of Suspension Bridge Wires)

  • Taejun;Andrzej S. Nowak
    • 한국전산구조공학회:학술대회논문집
    • /
    • 한국전산구조공학회 2003년도 봄 학술발표회 논문집
    • /
    • pp.537-544
    • /
    • 2003
  • This paper deals with stress corrosion cracking behavior of high strength steel exposed to marine environments. The objective is to determine the time to failure as a function of hydrogen concentration and tensile stress in the wires. A crack growth curve is modeled using finite element method (FEM) program. The coupled hydrogen diffusion-stress analyses of SCC were programmed separately. The first part is calculating stress and stress intensity /sup 1)/factor of a cylindrical shell, prestressing tendon or suspension bridge wires, from the initiation of cracks to rupture. Virtual crack extension method, contour integral method, and crack tip elements are used for the calculation of stresses in front of the crack tip. Comparisons of the result show a good agreement with the analytical equations and wire tests. The second part of the study deals with the programming of hydrogen diffusion, affected by hydrostatic stress, calculated at the location of boundary of plastic area around the crack tip. The results of paper can be used in the design and management of prestressed structures, cable stayed and suspension bridges. Time dependent correlated parallel reliabilities of a cable, composed of 36 wires, were evaluated by the consideration of the deterioration of stress corrosion cracking.

  • PDF