• KSBB Journal
• /
• 제18권5호
• /
• pp.393-397
• /
• 2003

수용성 절삭유에서 발생빈도가 높고 생존ㆍ성장력이 우수한 Pseudomonas aeruginosa를 사용하여 방청제가 방부제 (Kathon 886 MW, Triadine 3, Triadine 10 and Grotan BK)의 항균효능에 미치는 영향을 조사하였다. 실험결과 방부제와 방청제를 함께 사용할 경우 방부제의 효능은 첨가되는 방청제에 의해 그 영향을 받았다. Kathon 886 MW 항균효능은 SS 510과 MEA를 각각 첨가하였을 때 증가하였다. Triadine 3, Triadine 10, Grotan BK는 사용된 방청제에 대해 유사한 경향의 향균효능을 보였는데, CP-105, CP-E-7, MEA에 대해서 상승효과를 보였다. 그리고 방청제 고유의 항균력을 비교해 본 결과, CP-E-7과 MEA는 bioresistant 하였으며, 다른 방청제 (CP-105, AMIDE, SS-510, TEA)는 biosupportive하였다. 방부제 고유의 항균력을 비교해본 결과, Triadine 10 ＜ Triadine 3 < Kathon 886 MW < Grotan BK 순으로 항균성이 좋게 나타났다.

• 동력기계공학회지
• /
• 제19권6호
• /
• pp.75-81
• /
• 2015

A deposited metal specimen of ER2594 which is a super duplex steel welding wire used to investigate the effect of sigma(${\sigma}$) phase on electrochemical corrosion characteristics was prepared by gas tungsten arc welding. Aging treatment was conducted for the specimen at the temperature range of $700^{\circ}C$ to $900^{\circ}C$ for 5 to 300 minutes after annealing at $1050^{\circ}C$. Corrosion current density has decreased a little with an increase of aging time over 60 minutes at $700^{\circ}C$ to $900^{\circ}C$ and the uniform corrosion of deposited metal had more influence on the precipitation of ferrite than the precipitation of sigma phase. Therefore, the precipitation of sigma phase did not have much effect on the uniform corrosion. Pitting potential representing pitting corrosion has shown decreasing tendency as the precipitation of sigma phase increased. The degree of sensitization representing intergranular corrosion has shown increasing tendency as the precipitation of sigma phase increased at $700^{\circ}C$ to $800^{\circ}C$, while it has decreased at $900^{\circ}C$ for 60 to 300 minutes.

• Journal of Welding and Joining
• /
• 제28권4호
• /
• pp.18-25
• /
• 2010

Super-duplex stainless steels (SDSS) have a good balance of mechanical property and corrosion resistance when they consist of approximately equal amount of austenite and ferrite. The SDSS needs to avoid the detrimental phases such as sigma(${\sigma}$), chi(${\chi}$), secondary austenite(${\gamma}2$), chromium carbide & nitride and to maintain the ratio of ferrite & austenite phase as well known. However, the effects of the subsequent weld thermal cycle were seldom experimentally studied on the micro-structural variation of weldment & pitting corrosion property. Therefore, the present study investigated the effect of the subsequent thermal cycle on the change of weld microstructure and pitting corrosion property at $40^{\circ}C$. The thermal history of root side was measured experimentally and the change of microstructure of weld root & the weight loss by pitting corrosion test were observed as a function of the thermal cycle of each weld layer. The ferrite contents of root weld were reduced with the subsequent weld thermal cycles. The pitting corrosion was occurred in the weld root region in case of the all pitted specimen & in the middle weld layer in some cases. And the weight loss by pitting corrosion was increased in proportional to the time exposed at high temperature of the root weld and also by the decrease of ferrite content. The subsequent weld thermal cycles destroy the phase balance of ferrite & austenite at the root weld. Conclusively, It is thought that as the more subsequent welds were added, the more the phase balance of ferrite & austenite was deviated from equality, therefore the pitting corrosion property was deteriorated by galvanic effect of the two phases and the increase of 2nd phases & grain boundary energy.

• Tribology and Lubricants
• /
• 제19권1호
• /
• pp.31-35
• /
• 2003

This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the various pH environments. In the variety of pH solutions, corrosion and wear-corrosion loss of GCD 600 were investigated. Also, the anodic polarization test of GCD 600 using potentiostat/galvanostat was carried out. And rubbed surface of GCD 60 using scanning electron micrographs after immersion and wear-corrosion test was examined in the environment of various pH values. The main results are as following In alkali zone, the wear-corrosion loss of GCD 600 increases, but corrosion loss decreases. The unevenness and crack of wear-corrosion surface in neutral zone becomes duller than that in alkali zone. As the corrosive environment is acidified, wear-corrosion behavior of GCD 600 with passing immersion time becomes sensitive.

• Corrosion Science and Technology
• /
• 제2권5호
• /
• pp.219-224
• /
• 2003

Crevice corrosion of stainless steels in natural seawater was investigated for several post weld treatments; as-annealed, as-welded, pickled, and ground. The results confirmed the effect of the biofilm on the cathodic reaction leading to an ennoblement of the rest potential. The degree of ennoblement of corrosion potential depends on the surface finish. As-annealed and pickled samples show stable corrosion potential approaching to 200 ~ 300 mV (SCE) while as-welded and ground samples show the fluctuating corrosion potential. This points to a situation where there are conflicting effects determining the trend in free corrosion potential. Crevice corrosion initiation will tend to pull the free corrosion potential in the active direction, whereas the presence of biofilm will tend to ennoble corrosion potential. There was no visible attack on UNS S31803, S32550, and 2205W. Therefore, those stainless steel grades appeared to be resistant to crevice corrosion in natural seawater on condition of weld metal.

• Corrosion Science and Technology
• /
• 제4권6호
• /
• pp.226-230
• /
• 2005

Si incorporated diamond-like carbon (Si-DLC) films ranging from 0 to 2 at.% contents were deposited on STS 316L substrates for orthopedic implants by means of r.f. plasma-assisted chemical vapor deposition (r.f. PACVD) technique, using mixtures of benzene ($C_6H_6$) and silane ($SiH_4$) as the precursor gases. This study provides the reliable and quantitative data for assessment of the effect of Si incorporation on corrosion property in the simulated body fluid environment through the electrochemical test. It was found that corrosion to resistance of Si-DLC coatings with increasing Si content are improved owing to high $sp^3$ bonding.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
• /
• pp.409-414
• /
• 2002

This study is intended to develop the self water proof admixture for durability concrete by anti-corrosion inhibitor. Chloride induced corrosion of reinforcement is one of the main factor which cause the deterioration of concrete structure. When the substitute anti-corrosion agents for a part of self waterproofing agent, the corrosion-proof increases for the increased water proofing capacity. And proper self waterproofing agent by cement weight in concrete was generally positive effect to concrete compressive strength, slump, freezing and thawing resistance. Also, permeability and absorption show a straight decrease when self waterproofing agent is added.

• 한국정밀공학회지
• /
• 제17권12호
• /
• pp.157-162
• /
• 2000

The object of this work is to develop an assessment system for pipeline integrity. the system consists of four module applications for internal algorithm; the effect of corrosion in pipeline, crack, stress corrosion crack (SCC) and fatigue modules. Presently, the module of the external corrosion has been developed and the internal algorithm for the effect of corrosion in pipeline and the database of the system are described in this paper. The database of the system is separated to mainly four parts; geometry of pipeline, material properties, boundary conditions and general properties. Each components of the system are designed by user-friendly concept. This system may give a guideline for maintenance and modifications for the pipeline at the industrial sight. Furthermore, a procedure to evaluate an inspection interval is also provided.

• Earthquakes and Structures
• /
• 제9권4호
• /
• pp.851-873
• /
• 2015

A methodology for estimation of statistical properties (viz. mean and standard deviation) of the expected seismic damage to reinforced concrete framed structures subject to corrosion of reinforcement, over a specified reference time (typically the service life of the structure) is proposed in this paper. The damage to the structure under the earthquake loading is characterised by the damage index, determined using the modified Park and Ang damage model. The reduction in area, yield strength and strain at ultimate of steel reinforcement, and the reduction in compressive strength of cover concrete due to corrosion are taken into account in the estimation of damage. The proposed methodology is illustrated through an example problem. From the results obtained, it is noted that there is an increase of about 70% in the mean value of expected seismic damage to the reinforced concrete frame considered over a reference time of 30 years when effect of corrosion is taken into consideration. This indicates that there is a need to consider the effect of corrosion of reinforcement on the estimation of expected seismic damage.

• Corrosion Science and Technology
• /
• 제5권1호
• /
• pp.15-22
• /
• 2006

The introduction of two-grid inside a conventional process system produces a reactive coating deposition and increases metal ion ratio in the plasma, resulting in denser and smoother films. The corrosion behaviors of TiN coatings were investigated by electrochemical methods, such as potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) in deaerated 3.5% NaCl solution. Electrochemical tests were used to evaluate the effect of microstructure on the corrosion behavior of TiN coatings exposed to a corrosive environment. The crystal structure of the coatings was examined by X-ray diffractometry (XRD) and the microstructure of the coatings was investigated by scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM). In the potentiodynamic polarization test and EIS measurement, the corrosion current density of TiN deposited by two grid-attached magnetron sputtering was lower than TiN deposited by conventional magnetron type and also presented higher Rct values during 240 h immersion time. It is attributed to the formation of a dense microstructure, which promotes the compactness of coatings and yields lower porosity.