• Title/Summary/Keyword: corrosion control

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Mesoscale model for cracking of concrete cover induced by reinforcement corrosion

  • Chen, Junyu;Zhang, Weiping;Gu, Xianglin
    • Computers and Concrete
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    • v.22 no.1
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    • pp.53-62
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    • 2018
  • Cracking of concrete cover induced by reinforcement corrosion is a critical issue for life-cycle design and maintenance of reinforced concrete structures. However, the critical degree of corrosion, based on when the concrete surface cracks, is usually hard to predict accurately due to the heterogeneity inherent in concrete. To investigate the influence of concrete heterogeneity, a modified rigid-body-spring model, which could generate concrete sections with randomly distributed coarse aggregates, has been developed to study the corrosion-induced cracking process of the concrete cover and the corresponding critical degree of corrosion. In this model, concrete is assumed to be a three-phase composite composed of coarse aggregate, mortar and an interfacial transition zone (ITZ), and the uniform corrosion of a steel bar is simulated by applying uniform radial displacement. Once the relationship between radial displacement and degree of corrosion is derived, the critical degree of corrosion can be obtained. The mesoscale model demonstrated its validity as it predicted the critical degree of corrosion and cracking patterns in good agreement with analytical solutions and experimental results. The model demonstrates how the random distribution of coarse aggregate results in a variation of critical degrees of corrosion, which follows a normal distribution. A parametric study was conducted, which indicates that both the mean and variation of critical degree of corrosion increased with the increase of concrete cover thickness, coarse aggregates volume fraction and decrease of coarse aggregate size. In addition, as tensile strength of concrete increased, the average critical degree of corrosion increased while its variation almost remained unchanged.

Corrosion control of drinking water pipes by corrosion inhibitor (부식억제제에 의한 상수도관의 부식제어)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.6
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    • pp.2306-2310
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    • 2010
  • Corrosion is a complex series of oxidation/reduction reactions between at the water-metal surfaces and materials in which the water is stored or transported. With respect to the corrosion potential of drinking water, the primary concerns include the potential presence of toxic metals, such as lead and copper; deterioration and damage to the household plumbing, and aesthetic problems such as stained laundry, and bitter taste. This study was performed to evaluate the effects of corrosion inhibitors on corrosion rates, Fe and Cu release concentration in water distribution pipes. Decrease of corrosion rates were strongly related to phosphate corrosion inhibitors. Considering that typical corrosion processes consists of a series of electrochemical reaction at the metal surface in contact with water, corrosion rates were positively correlated with Fe release.

Approaches to Internal Corrosion Control Technologies by Controlling Water Quality in Water Treatment Systems (수질제어를 통한 관 내부 부식방지 기술의 정수처리공정 적용방안)

  • Seo, Dae-Keun;Wang, Chang-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.509-518
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    • 2006
  • Although final water of domestic water treatment plants almost contains highly corrosive characteristics, the countermeasures for eliminating internal corrosion of pipeline system have not been conducted yet by controlling water quality in plants. The technologies of internal corrosion control are to control water quality parameters(pH, Alkalinity, and Calcium Hardness etc.) and to use corrosion inhibitor. Under the conditions of domestic water treatment, first of all, the technologies of adjusting water quality parameters has to be considered. Otherwise, The technology of using corrosion inhibitor is favorably thought to be applied with the technology of adjusting water quality parameters in accordance with the result of availability for water treatment process. Since the technology of adjusting water quality parameter influences on other water treatment processes, the guideline of water quality management to be apt for water quality characteristic is required to be estabilished. While the selection of proper chemicals and technologies is dependent upon the raw water characteristics and water treatment process, typically, the technology of $Ca(OH)_2$ & $CO_2$ additions is considered more effective than other technologies in order to adjust pH and Alkalinity, increase $Ca^{2+}$ and form $CaCO_3$ film

Correlation between Corrosion Rate and Red Water on Application of Corrosion Inhibitor in Drinking Water Distribution System (배급수 계통에서 부식억제제 적용에 따른 부식과 적수와의 상관관계)

  • Woo, Dal-Sik;Ku, Sung-Eun;Lee, Byung-Doo;Kim, Ju-Hwan;Moon, Kwang-Soon
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.1
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    • pp.68-77
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    • 2005
  • This study was performed to evaluate the application of corrosion inhibitor and to examine the correlation between corrosion rate and red water in a series of batch tests and a test using auto corrosion monitoring system at A water treatment plant in Gyeonggido. The corrosion study in the auto corrosion monitoring system indicated that Fe concentration decreased by 30~50% and corrosion rate also reduced remarkably with corrosion inhibitor at $1.8mg\;PO_4/L$. After addition of corrosion inhibitor, it was indicated the effective adsorption of the inhibitor on the surface of the pipe line forming a protective film. The corrosion rate increases with the increase in Fe concentration. With $1.8mg\;PO_4/L$ of corrosion inhibitor, the corrosion rate decreased remarkably. Fe concentration had correlation to not only red water problems but also the corrosion rate that actually dissolved into the water, primarily due to the deposition of oxidized iron or other compounds as a scale, which serves as a large reservoir of corrosion by-product. Therefore, corrosion rate can be estimated by Fe concentration. For these reasons, an effective corrosion inhibitor is also an effective red water control reagent. The effect of the corrosion inhibition can last for some time even the application the corrosion inhibitor is discontinued. For the cost effective and efficient corrosion control, the concentration and timing of corrosion inhibitor addition must be determined properly.

Corrosion Resistance Properties of Rice Husk Ash Blended Concrete

  • Ganesan, K.;Rajagopal, K.;Thangavel, K.
    • Corrosion Science and Technology
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    • v.6 no.1
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    • pp.12-17
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    • 2007
  • Portland cement incorporating supplementary cementing material develops excellent mechanical properties and long term durability characteristics. India is a leading rice producing country and rice husk is considered as waste in the rice milling industries. In this present work, the rice husk ash (RHA) was added to concrete as cement replacement from 0 to 30%. Corrosion performance of reinforcing steel embedded in RHA blended concretes was studied using linear polarization, AC impedance and gravimetric methods. The corrosion rate of steel bars embedded in RHA concretes were compared with control concrete. The results clearly indicate that the corrosion rate of reinforcing steel embedded in concrete is significantly reduced with the incorporation of RHA. A good correlation among gravimetric method and electrochemical methods was observed. Electrochemical impedance study showed 98 percentage reduction in corrosion rate to the RHA blended concrete with 15% replacement than control concrete.

The anti-corrosion study on the corrosion-sensitive areas of unpainted weathering steel bridges with closed box girder(I) (밀폐 박스거더형 무도장 내후성강 교량의 부식취약부에 대한 방식대책 연구(I))

  • Song, Chang-young;Lee, Eui-Ho;Lee, Jea-Hyun;Park, Hyun-Chul;Choi, Jae-Suk;Noh, Young-Tae
    • Corrosion Science and Technology
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    • v.12 no.3
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    • pp.149-157
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    • 2013
  • In corrosion-sensitive areas of exsisting unpainted weathering steel bridges with closed box girder structures. there are some serious local corrosion problems because of rain water or dew water which can not be solved by exsisting maintenance methods. These problems must be controled technically because of bad. influence on the safety of bridge. This study is the first stage of developing the economic corrosion control manual for these local corrosion problems. Through the injection of tar sealant into the crevice of mock-up equipment, it was prooved that the corrosive sealant can be useful to corrosion control at crevice of corrosion sensitive area.

Effect of corrosive water quality control and corrosion index monitoring in pilot scale pipeline simulator (파일럿 규모 모의관로에서 부식성 수질제어 효과와 부식지수 모니터링)

  • Kim, Do-Hwan;Kim, Yung-Jin;Son, Hee-Jong;Ryou, Dong-Choon;Ahn, Jun-Young;Kim, Cheolyong;Hwang, In-Seong
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.183-192
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    • 2018
  • Applicability of corrosion inhibitor was evaluated using pilot scale water distribution pipe simulator. Calcium hydroxide was used as corrosion inhibitor and the corrosion indices of the water were investigated. Corrosion indices, Langelier saturation index (LI) increased by 0.8 and calcium carbonate precipitation potential (CCPP) increased by 9.8 mg/L. This indicated that corrosivity of water decreased by corrosion inhibitor and the effects lasted for 18 days. Optimum calcium hydroxide dose was found to be 3~5 mg/L for corrosion inhibition. We suggest that monitoring of CCPP as well as LI need to be conducted to control corrosivity of water.

A Study on the Post-Weld Heat Treatment Effect to Mechanical Properties and Hydrogen Embrittlement for Heating Affected Zone of a RE 36 Steel

  • Moon, Kyung-Man;Lee, Myung-Hoon;Kim, Ki-Joon;Kim, Jin-Gyeong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.2 no.6
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    • pp.283-288
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    • 2003
  • The cathodic protection method is being widely used in marine structural steel, however a high tensile steel like RE 36 steel for marine structural steel is easy to get hydrogen embrittlement due to over protection during cathodic protection as well as preferential corrosion of HAZ(Heating Affected Zone) part. In this paper, corrosion resistance and mechanical properties such as elongation and hydrogen embrittlement were investigated with not only in terms of electrochemical view but also SSRT(Slow Strain Rate Test) method with applied constant cathodic potential, analysis of SEM fractography in case of both As-welded and PWHT(Post-Weld Heat Treatment) of $550^{\circ}C$. The best effect for corrosion resistance was apparently indicated at PWHT of $550^{\circ}C$ and elongation was increased with PWHT of $550^{\circ}C$ than that of As-welded condition. On the other hand. Elongation was decreased with applied potential shifting to low potential direction which may be caused by hydrogen embrittlement, however the susceptibility of hydrogen embrittlement was decreased with PWHT of $550^{\circ}C$ than that of As-welded condition and Q.C(quasi cleavage) fracture mode was also observed significantly according to increasing of susceptibility of hydrogen embrittlement. Eventually it is suggested that an optimum cathodic protection potential range not causing hydrogen embrittlernent is from -770 mV(SCE) to -850 mV(SCE) in As-welded condition while is from -770 mV(SCE) to -875 mV(SCE) in PWHT of $550^{\circ}C$.

Study on the Web-based Prediction System for Corrosion Monitoring and Anti-corrosion (부식감시 및 방식을 위한 웹기반 예측시스템에 관한 연구)

  • Park, Hyoung-Keun;Kim, Sun-Yeob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.784-789
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    • 2012
  • In this paper, a number of anode and reference electrodes that are installed around the target anti-corrosion objects to monitor, appropriate to your situation of a fixed potential and polarization methods can be applied automatically in the system was developed. In particular, this system was configured with a remote electric anti-corrosion automatic control device that have automatically adjust function to uniformal anti-corrosion in all parts of target objects, a corrosion monitoring device to perform the function of corrosion potential detection and a web-based operating program to perform the function of real-time monitoring, control and prediction. Using this system, by preventing oxidative corrosion phenomena can maximize the life of the target anti-corrosion objects.

A Study on the Erosion-Corrosion of Sprayed Cu-Ni Alloy Coating in the Marine Environment (해양환경 중에서 Cu-Ni 용사피복재의 침식-부식에 관한 연구)

  • Lee, Sang-Yoel;Lim, Uh-Joh;Yun, Byoung-Du
    • Journal of Fisheries and Marine Sciences Education
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    • v.10 no.1
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    • pp.69-78
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    • 1998
  • Thermal sprayed Cu-Ni alloy coating on the carbon steel was carried out impingement erosion-corrosion test and electrochemical corrosion test in the marine environment. The impingement erosion-corrosion behavior and electrochemical corrosion characteristics of substrate(SS400) and thermal sprayed Cu-Ni coating was investigated, and the corrosion control efficiency of Cu-Ni coating to substrate was estimated quantitatively. Main results obtained are as follows : 1) The weight loss rate of Cu-Ni coating layer by the impingement erosion-corrosion compared with substrate was smaller in high specific resistance solution than in low specific resistance solution. 2) The corrosion potential of Cu-Ni coating layer spray coating in the marine environment became more noble than that of substrate. 3) With the lapse of time, corrosion current density of Cu-Ni coating layer became stable, but that of substrate was increased. 4) As the corrosion control efficiency of Cu-Ni coating layer in the marine environment was over 90%, its anti-corrosion characteristics was excellent.

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