• Proceedings of the Acoustical Society of Korea Conference
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• 1994.06a
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• pp.644-649
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• 1994

Recent studies reveal that grip forces due to repeated mechanical vasocompressions are most significant for the genesis of vibration-induced which finger syndrome (VWF). Therefore, exerted grip force was regarded as a dependent variable in 2 experiments and the effects of noise and vibrations of different weighted acceleration levels were studied. Neither grip forces nor peripheral blood flow as indicated by finger skin temperature were influenced by noise or vibrations. the cause of VWF is therefore presumed to be a concomitant variable which correlates with weighted accelerations and with grip forces as well. A possible factor is the weight of hand-held vibrating tools.

• Bulletin of the Korean Chemical Society
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• v.18 no.1
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• pp.86-91
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• 1997

Complexation of primary alkylammonium ions by 1, 3-distal calix[4]arene diesters was studied by NMR spectroscopy. The guest alkylammonium ions are found to bind mainly to the two ester moieties and are oriented outward with respect to the cone cavity of the host, forming exo-type complexes unlike the case of alkylammonium-calix[6]arene systems. Measurement of T1 also revealed that the primary binding site is the two ester moities and phenolic OH groups. The temperature dependence of the chemical shifts of phenolic OH protons in these diesters correlates with the basicity of the solvent moderately well and the temperature coefficients of their chemical shifts are found to significantly decrease upon complexation with propylammonium ion.

• Bulletin of the Korean Chemical Society
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• v.4 no.1
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• pp.36-41
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• 1983

An equation is derived which correlates the unperturbed dimensions $_0$ of polypeptides with the helical contents in the helix-coil transition region by using a simple model of a polypeptide chain. The model is a chain of connected balls which represent the repeating units, -CO-NH-CHR-, based on the fact that the repeating unit has a plane structure. The changing trend of the expansion factor ${\alpha}_{\eta}$ in the transition region is connected with the helical content $f_H$. The intrinsic viscosities [${\eta}$] of polypeptides are calculated from the unperturbed dimensions and the ${\alpha}_{\eta}$ factors. The above calculated results concerning $_0$ and [${\eta}$] are compared with other authors' theoretical and experimental results. From the comparison, we concluded that our theory explains better the chain dimensional behavior of polypeptides in the helix-coil transition region than others.

• Bulletin of the Korean Chemical Society
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• v.18 no.2
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• pp.143-149
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• 1997

We have investigated a relationship between conformational preferences of various substituents in monosubstituted cyclohexanes and pertinent torsional parameter values in molecular mechanics calculations. We have manipulated torsional parameters to supply a certain energy difference between gauche and anti conformers, and applied those parameters to monosubstituted cyclohexanes. After investigating 6 different substituents, namely Me, SiH3, F, Cl, Br, and I, MM3 calculations show that (1) the MM3 calculated A values with the current torsional parameters reproduce the available experimental values well, (2) the conformational energy difference between axial and equatorial conformations (the A value) correlates perfectly with the gauche/anti energy differences of the corresponding butane-like fragment (correlation coefficient=l.000), and (3) the A values are essentially twice as the gauche/anti energy differences (slopes=1.86-2.00). On the basis of our analysis, the A values as well as the gauche/anti energy differences are easily calibrated by an adjustment of the relevant torsional parameter. Thus, our technique for tuning the torsional parameters may be of great use in updating molecular mechanics results about conformational preferences whenever a further refinement is necessary.

• Bulletin of the Korean Chemical Society
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• v.18 no.9
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• pp.965-972
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• 1997

An approximate molecular theory of classical fluids based on the nonrandom lattice statistical-mechanical theory is presented. To obtain configurational Helmholtz free energy and equation of state (EOS), the lattice-hole theory of the Guggenheim combinatorics is approximated by introducing the nonrandom two-fluid theory. The approximate nature in the derivation makes the model possible to unify the classical lattice-hole theory and to describe correctly the configurational properties of real fluids including macromolecules. The theory requires only two molecular parameters for a pure fluid. Results obtained to date have demonstrated that the model correlates quantitatively the first- and second-order thermodynamic properties of real fluids. The basic simplicity of the model can readily be generalized to multicomponent systems. The model is especially relevant to (multi) phase equilibria of systems containing molecularly complex species.

• Bulletin of the Korean Chemical Society
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• v.19 no.5
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• pp.544-548
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• 1998

A Monte Carlo simulation incorporated with the genetic algorithm is presented to describe the defect known as "transition from Y-to X-type deposition" of the cadmium arachidate Langmuir-Blodgett multilayer film. Simulation is performed based on the detachment models of XY-type deposition. The transition is simulated by introducing a probability of surface molecule detachment considering interaction between neighboring molecules. The genetic algorithm is incorporated into Monte Carlo simulation to get the optimum value of the probability factors. The distribution of layers having different thickness predicted by the simulation correlates well with the measured distribution of thickness using the small-angle X-ray reflectivity. The effect of chain length and subphase temperature on the detachment probability are investigated using the simulation. Simulation results show that an increase (or a decrease) of two hydrocarbon chain is roughly equivalent to the detachment probability to a temperature decrease (or increase) of 15 K.

• Journal of Smart Tourism
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• v.1 no.2
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• pp.13-18
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• 2021

Hotels have recently started to implement enterprise information systems to measure and report sustainability indicators in a smart manner. However, a complex ownership structure in a hotel chain prevents full smart systems adoption at the individual property level. This study explores how a smart sustainability performance measurement system (SPMS) for waste management adoption correlates with customer ratings, customer reviews, operational efficiency scores, and between franchised and corporate-managed properties. We derive insights from the secondary data constructed from multiple sources for a large multinational hotel chain hotel. The findings suggest that hotels that adopt SPMS have better operational efficiency scores and more customer reviews. Within the hotels that adopted SPMS, corporate-managed hotels have a lower level of ratings than franchised hotels, but they have higher operational efficiency scores and more reviews. We discuss research implications for the concept of smart tourism and hotel management literature and managerial implications.

• Cross-Cultural Studies
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• v.24
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• pp.112-119
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• 2011

This study presents experiments which examined the role of amplitude and fundamental frequency (f0) in the phonetic perception of short versus long stop length contrasts in Japanese (e.g., [t] vs. [tt]). Stop length contrasts are normally characterized by differences in the duration of stop closures. However, closure duration can be unreliable as a perceptual cue when one considers variability in the rate at which people speak. Acoustically, the amplitude and f0 of the vowel following stop consonants are known to covary with the length distinction of stops in Japanese. Given this fact, the current study examined amplitude and f0 as potential secondary cues to the distinction. The results indicate that even though both amplitude and f0 are robust correlates, Japanese listeners do not use these cues in categorizing short versus long stops.

• Journal of Engineering Education Research
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• v.21 no.3
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• pp.3-11
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• 2018

The Conceiving-Designing-Implementing-Operating (CDIO) initiative is a worldwide organization with members from over 120 institutions for higher education, and it provides an innovative educational framework for producing the next generation of engineers. This paper compares the CDIO standards and syllabus to the accreditation criteria of Accreditation Board for Engineering Education of Korea, ABEEK to identify similarities and differences and to find points of improvement for ABEEK criteria. It is found that the basic concepts of ABEEK criteria correlates well with those of CDIO standards, while the CDIO standards and syllabus provide more detailed and well-defined guidelines for engineering programs. Finally, some discussions are presented on the differences between the two educational models, a voluntary-based CDIO model and an accreditation-based ABEEK model.

• Bulletin of the Korean Chemical Society
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• v.16 no.3
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• pp.211-214
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• 1995

The catalytic activities of palladium(0,Ⅰ,Ⅱ)-diphosphine complexes were investigated in styrene oxidation using H2O2 as terminal oxidant. The rates showed a dependence on the chelate ring patterns of complexes (PdCl2L); 5-membered ring (L=dppe: 1,2-bis(diphenylphosphino)ethane) < 6-membered ring (L=dppp: 1,3-bis(diphenylphosphino)propane) < 4-membered ring (L= dppm: bis(diphenylphosphino)methane). This sequence correlates with the ligand field strength and interactions between metal and phosphine ligands. Pd(Ⅱ,Ⅰ)-diphosphine complexes which are capable of making 4-membered chelate ring showed an enhancement of catalytic activities for styrene oxidation. The catalytic activities of Pd(0,Ⅰ,Ⅱ)-diphosphine complexes are described in terms of electronic and steric factors.