• Journal of Dairy Science and Biotechnology
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• v.23 no.2
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• pp.115-123
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• 2005

Microcapsules consisting of natural, biodegradable polymers for controlled and/or sustained core release applications are needed. Physicochemical properties of whey proteins suggest that they may be suitable wall materials in developing such microcapsules. The objectives of the research were to develop water-insoluble, whey protein-based microcapsules containing a model water-soluble drug using a chemical cross-linking agent, glutaraldehyde, and to investigate core release from these capsules at simulated physiological conditions. A model water soluble drug, theophylline, was suspended in whey protein isolate (WPI) solution. The suspension was dispersed in a mixture of dichloromethane and hexane containing 1% biomedical polyurethane. Protein matrices were cross-linked with 7.5-30 ml of glutaraldehyde-saturated toluene (GAST) for 1-3 hr. Microcapsules were harvested, washed, dried and analyzed for core retention, microstructure, and core release in enzyme-free simulated gastric fluid (SGF) and simulated intestinal fluid(SIF) at $37^{\circ}C$. A method consisting of double emulsification and heat gelation was also developed to prepare water-insoluble, whey protein-based microcapsules containing anhydrous milkfat (AMF) as a model apolar core. AMF was emulsified into WPI solution (15${\sim}$30%, pH 4.5-7.2) at a proportion of 25${\sim}$50%(w/w, on dry basis). The oil-in-water emulsion was then added and dispersed into corn oil ($50^{\circ}C$) to form an O/W/O double emulsion and then heated at $85^{\circ}C$ for 20 min for gelation of whey protein wall matrix. Effects of emulsion composition and pH on core retention, microstructure, and water-solubility of microcapsules were determined. Overall results suggest that whey proteins can be used in developing microcapsules for controlled and sustained core release applications.

• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1534-1538
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• 2011

Uniform, hollow nanosilica spheres were prepared by the chemical coating of cationic polystyrene (cPS) with tetraethylorthosilicate (TEOS), followed by calcination at 600 $^{\circ}C$ under air. cPS was synthesized by surfactant-free emulsion polymerization using 2,2'-azobis (2-methyl propionamidine) dihydrochloride as the cationic initiator, and poly(vinyl pyrrolidone) as a stabilizer. The resulting cPS spheres were 280 nm in diameter, and showed monodispersion. After coating, the hollow silica product was spherically shaped, and 330 nm in diameter, with a narrow distribution of sizes. Dispersion was uniform. Wall thickness was 25 nm, and surface area was 96.4 $m^2/g$, as determined by BET. The uniformity of the wall thickness was strongly dependent upon the cPS surface charge. The effects of TEOS and ammonia concentrations on shape, size, wall thickness, and surface roughness of hollow $SiO_2$ spheres were investigated. We observed that the wall thicknesses of hollow $SiO_2$ spheres increased and that silica size was simultaneously enhanced with increases in TEOS concentrations. When ammonia concentrations were increased, the irregularity of rough surfaces and aggregation of spherical particles were more severe because higher concentrations of ammonia result in faster hydrolysis and condensation of TEOS. These changes caused the silica to grow faster, resulting in hollow $SiO_2$ spheres with irregular, rough surfaces.

• Steel and Composite Structures
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• v.34 no.6
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• pp.783-794
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• 2020

Steel-concrete-steel sandwich composite wall is composed of two external steel plates and infilled concrete core. Internal mechanical connectors are used to enhance the composite action between the two materials. In this paper, the compressive behavior of a novel sandwich composite wall was studied. The steel trusses were applied to connect the steel plates to the concrete core. Three short specimens with different truss spacings were tested under compressive loading. The boundary columns were not included. It was found that the failure of walls started from the buckling of steel plates and followed by the crushing of concrete. Global instability was not observed. It was also observed that the truss spacing has great influence on ultimate strength, buckling stress, ductility, strength index, lateral deflection, and strain distribution. Three modern codes were introduced to calculate the capacity of walls. The comparisons between test results and code predictions show that AISC 360 provides significant underestimations while Eurocode 4 and CECS 159 offer overestimated predictions.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2001.10a
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• pp.3-10
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• 2001

The box system that is composed only of reinforced concrete walls and slabs are adopted on many high-rise apartment buildings recently constructed in Korea. And the framed structure with shear wall core that can effectively resist horizontal forces is frequently adopted for the structural system for high-rise building structures. In these structures, a shear wall may have one or more openings for functional reasons. It is necessary to use subdivided finite elements for accurate analysis of the shear wall with openings. But it would take tremendous amount of computational time and memory if the entire building structure is subdivided into a finer mesh . An efficient analysis method that can be used regardless of the number, size and location of openings is proposed in this study, The analysis method uses super element, substructure, matrix condensation technique and fictitious beam technique. Three-dimensional analyses of the box system and the framed structure with shear wall core having various types of openings were performed to verify the efficiency of the proposed method. It was confirmed that the proposed method have outstanding accuracy with drastically reduced time and computer memory from the analyses of example structures.

• Journal of the Korea institute for structural maintenance and inspection
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• v.7 no.4
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• pp.201-208
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• 2003

The Hybrid Wall System(HWS) building composed of center core reinforced concrete walls and exterior steel frame has open space around the center core walls. It is necessary to develop design methodologies for the HWS building that the coupled shear walls withstand the most of lateral load and expect the most energy dissipation at the coupling beams and at wall foots. Major factors considered in this paper are connection type of coupling beams and scale of story. The studies of the system are investigated in terms of shear force, overturning moment, maximum lateral displacement, story drift ratio, and dynamical characteristics under the action of vertical and lateral forces such as wind and seismic loads.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.130-135
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• 2007

The mechanical characteristics of three types of core with two-dimensional isotropic patterns-triangular, hexagonal and starcell-were studied in applications to sandwich structures. The Young's modulus and shear modulus were calculated for the three core types in the direction normal to the faces. The compressive buckling strength and shear buckling strength were calculated by modeling each cell wall of the core as a plate under compressive or shear load. To verify this model, tests were conducted on scaled specimens to measures the compressive buckling strength of each core. The bending flexibilities of the three cores were also studied. Compliances for the three cores were measured using biaxial flexural tests. The three isotropic core patterns exhibited distinct characteristics. In the direction normal to the faces, all three cores had the same stiffness. However, the starcell core exhibited high flexibility compared to the other cores, indicating potential for application to curved sandwich structures.

• Proceedings of the Korean Society of Plant Biotechnology Conference
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• 2005.11a
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• pp.197-197
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• 2005

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.31 no.2
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• pp.70-76
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• 1999

This study was to measure the potential of nonwoody fibrous material, kenaf. Whole stalk of kenaf, Hibiscus cannabinus was separated by two parts of bast and core portion, and cooked separately by alkaline method. Morphological characteristic was evaluated using confocal laser scanning microscope (CLSM) and fiber quality analyzer(FQA). The strength properties of handsheets, made by different mixing ration between kenaf base and core fibers, were measured. Cross-sectional area of bast fibers was smaller than that of core fibers, but the bast fibers had a thick cell wall and narrow lumen area. Bast fibers were longer in length than core fibers. Core fibers had thin cell walls, broad lumen areas, and short lengths, and they had collapsed shape even in water. These characteristics of core fibers affected strength properties of handsheet positively. When the amount of core fibers increased, the strength properties of handsheet were increased. When the amount of bast fibers increased, the handsheet had rougher surface and higher air permeability.

• Progress in Superconductivity and Cryogenics
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• v.23 no.4
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• pp.14-18
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• 2021

The Mg-Powder-Compaction (MPC) process is proposed to fabricate the MgB₂ superconducting wires. Mg powder wall, similar to the Mg metal tube, inside the Nb outer sheath has been made and the stochiometric B powder was inserted into the wall. Even though the very high MgB₂ core density of 2.53 g/cm³ is obtained, the superconducting area fraction of MgB₂ is not high enough for the applications. In this work, an advanced MPC process was adopted by adding Mg powder into B powder. The Mg powder wall in the initial wire was fabricated by controlling the wall thickness while maintaining a constant density, and the mixture of B and Mg powder was filled into the Mg powder wall with the same filling density. It is found that the reduction in the area of the Mg powder wall proceeds similar to the wire, and the Mg powder wall is well maintained at the final wire diameter, which is advantage for the fabrication of long wires. With the advanced MPC process, as the added Mg is increased the densities of MgB₂ core is decreased and the porous structure is formed, it is found that the area fraction of superconducting MgB₂ increase up to the 37.7 % with the improved high critical current density (J_c) and the engineering critical current density (J_e).

• Journal of the Korean Society of Clothing and Textiles
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• v.26 no.5
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• pp.684-690
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• 2002

The microcapsules containing fragrant material as functional compound were produced by in-situ polymerization. The prepolymer was made from urea-formaldehyde(UF) and melamine-formaldehyde(MF) as wall materials of microcapsules. The effects of wall material, dispersing agent and ratio of wall material to core material on the mean diameter variation were investigated. Thermal efficiency and release behavior of microcapsules were measured. The resultant UF and MF microcapsules are capable of preserving fragrant oil for long self-life.