• 한국환경과학회지
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• 제21권5호
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• pp.585-596
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• 2012

This study is mainly focused on micellar effect of cetyltrimethyl ammonium bromide(CTABr) solution including alkylbenzimidazole(R-BI) on dephosphorylation of isopropyl-4-nitrophenylphosphinate(IPNPIN) in carbonate buffer(pH 10.7). The reactions of IPNPIN with R-$BI^{\ominus}$ are strongly catalyzed by the micelles of CTABr. Dephosphorylation of IPNPIN is accelerated by $BI^{\ominus}$ ion in $10^{-2}$ M carbonate buffer(pH 10.7) of $4{\times}10^{-3}$ M CTABr solution up to 89 times as compared with the reaction in carbonate buffer by no benzimidazole(BI) solution of $4{\times}10^{-3}$ M CTABr. The value of pseudo first order rate constant($k_{\Psi}$) of the reaction in CTABr solution reached a maximum rate constant increasing micelle concentration. Such rate maxima are typical of micellar catalyzed bimolecular reactions. The reaction mediated by R-$BI^{\ominus}$ in micellar solutions are obviously slower than those by $BI^{\ominus}$, and the reaction rate were decreased with increase of lengths of alkyl groups. It seems due to steric effect of alkyl groups of R-$BI^{\ominus}$ in Stern layer of micellar solution. The surfactant reagent, CTABr, strongly catalyzes the reaction of IPNPIN with R-BI and its anion(R-$BI^{\ominus}$) in carbonate buffer(pH 10.7). For example, $4{\times}10^{-3}$ M CTABr in $1{\times}10^{-4}$ M BI solution increase the rate constant($k_{\Psi}=98.5{\times}10^{-3}\;sec^{-1}$) of the dephosphorylation by a factor ca.25, when compared with reaction($k_{\Psi}=3.9{\times}10^{-4}\;sec^{-1}$) in $1{\times}10^{-4}$ M BI solution(without CTABr). And no CTABr solution, in $1{\times}10^{-4}$ M BI solution increase the rate constant($k_{\Psi}=3.9{\times}10^{-4}\;sec^{-1}$) of the dephosphorylation by a factor ca.39, when compared with reaction ($k_{\Psi}=1.0{\times}10^{-5}\;sec^{-1}$) in water solution(without BI). This predicts that the reactivities of R-$BI^{\ominus}$ in the micellar pseudophase are much smaller than that of $BI^{\ominus}$. Due to the hydrophobicity and steric effect of alkyl group substituents, these groups would penetrate into the core of the micelle for stabilization by van der Waals interaction with long alkyl groups of CTABr.

• 대한간호학회지
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• 제30권3호
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• pp.750-763
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• 2000

This study is based on grounded theory methodology by Strauss & Corbin(1998). Ten hospitalized subjects were interviewed for data collection. In the process of data analysis, 'acceptance' is found to be the causal condition, while 'health professionals' skillfulness', 'ward environment', 'history of hospitalization', and 'general conditions' were identified as context, 'felling of relief' as the core phenomenon, 'self-efficacy', 'support of others', and 'life style' as the intermediate situation, 'passive reaction', 'alternative reaction' and 'active reaction' as the strategy and 'stabilization', 'satisfaction', 'hope' and 'carrying out' as consequences. 'Feeling of relief' is found to go through the three stages of recognition-generation-maintenance after the five different patterns. 1) In case the health professionals are skillful, the ward environment is favorable, the general conditions of the patients improved and as a result the feeling of relief is strong, during the first hospitalization, the self-efficacy of the subjects tends to be strong. They proceed toward the goal set for themselves with a renewed hope and active or alternative reaction toward the feeling of relief. 2) The subjects tend to proceed toward the goal set for themselves with a renewed hope and active and alternative reaction toward the feeling of relief in case health professionals are skillful, the ward environment is favorable the general conditions of the subjects improved, self-efficacy is strong, and lifestyle is autonomous, during the second hospitalization even though support of others is merely superficial. 3) The subjects tend to stabilize, and satisfy themselves with the given situation with passive and alternative reaction to the feeling of relief in case health professionals are skillful and the ward environment is favorable but the general conditions worsened and accordingly the feeling of relief, is weak and life style is dependent during the second hospitalization although the subjects' self-efficacy is strong and support of others is specific. 4) The subjects tend to stabilize and satisfy themselves with the given situation with passive and alternative reaction to the feeling of relief in case health professionals are unskillful the ward environment is unfavorable, the general conditions improved, support of others is specific but life style is dependent and self-efficacy is weak during the first hospitalization. 5) The subjects tend to stabilize and satisfy themselves with the given situation in case health professionals are unskillful the ward environment is unfavorable but the general conditions improved support of others is specific and as a result self-efficacy is strong but life style is dependent.

• 패션비즈니스
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• 제5권4호
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• pp.158-175
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• 2001

The purpose of this study was to understand and improve the clothing habits and the apparel industry of North Korea in preparation for the reunification of South and North Korea. For this study, literary data, reports, periodicals, interviews and internet data of the two Koreas were reviewed. North Korean clothing habits used to be monotonous and uniform but nowadays people's clothes have become somewhat brighter in color and more diverse in design than before. In particular, liberal and individual dressing habits appeared among the privileged classes. When taking part in national events, women have to wear the traditional Korean costume, Hanbok, while men wear business suits for formal wear. In general, men don't wear Hanbok. Students have to be in uniforms but blue jeans, T-shirts with English logos were popular among them reflecting their sensitivity and openness towards western cultures. The brides usually wear pink Hanboks and the bridegrooms wear black business suits for their wedding. North Koreans also wear Hanbok on national holidays like South Koreans. Clothing is the most important item in the trade of process commission between North and South Korea. Trading items are mid to low end men's clothing for the most part due to less emphasis on fashion in the North. The processing is indirect trade and composed of sample making and contracting, sending out materials and production, carrying in goods and setting accounts. To activate South-North trade, establishment of infrastructure, stabilization of shipping, reducing high costs of distribution, building direct communication system by setting up office in a neutral zone and simplifying procedures in applying for the South and North Korea Economic Cooperation Fund. On the other hand, clothing and textiles education is carried on at art colleges, light industries colleges and commercial colleges in Pyongyang. Clothing institutes which study Hanbok and Western clothes, are installed in each city and province. Graduates who majored in clothing and textiles are posted in institutes or apparel factories. Their job is designing, patternmaking and sewing for their customers. Most of them are women and in good state of economic conditions. The North Korean clothing industry has been the core national industry that has developed based on overseas demand form the mid 1980s. The standard is that of South Korea in the early 1980s. In 1999, trade of North Korean textile products with trade counterparts such as Japan and China was $1.3 million in exports and $1.27 in imports. Of this amount the export takes up 25.4% of the total exports in North Korea. However, fundamentally even in sectors that are irrelevant to politics such as the fashion clothing industry, trust between the South and North should be a prerequisite. Only through this can exchange between North and South and economic cooperation contribute towards the reunification.

• International Journal of Oral Biology
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• 제32권4호
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• pp.119-125
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• 2007

Dlx3 is a homeodomain protein and is known to play a role in development and differentiation of many tissues. Deletion of four base pairs in DLX3 (NT3198) is causally related to tricho-dento-osseous (TDO) syndrome (OMIM #190320), a genetic disorder manifested by taurodontism, hair abnormalities, and increased bone density in the cranium. The molecular mechanisms that explain the phenotypic characteristics of TDO syndrome have not been clearly determined. In this study, we examined phenotypic characteristics of wild type DLX3(wtDlx3) and 4-BP DEL DLX3 (TDO mtDlx3) in C2C12 cells. To investigate how wtDlx3 and TDO mtDlx3 differentially regulate osteoblastic differentiation, reporter assays were performed by using luciferase reporters containing the promoters of alkaline phosphatase, bone sialoprotein or osteocalcin. Both wtDlx3 and TDO mtDlx3 enhanced significantly all the reporter activities but the effect of mtDlx3 was much weaker than that of wtDlx3. In spite of these differences in reporter activity, electrophoretic mobility shift assay showed that both wtDlx3 and TDO mtDlx3 formed similar amounts of DNA binding complexes with Dlx3 binding consensus sequence or with ALP promoter oligonucleotide bearing the Dlx3 binding core sequence. TDO mtDlx3 exhibits a longer half-life than wtDlx3 and it corresponds to PESTfind analysis result showing that potential PEST sequence was missed in carboxy terminal of TDO mtDlx3. In addition, co-immunoprecipitation demonstrated that TDO mtDlx3 binds to Msx2 more strongly than wtDlx3. Taken together, though TDO mtDlx3 acted as a weaker transcriptional activator than wtDlx3 in osteoblastic cells, there is possibility that during in vivo osteoblast differentiation TDO mtDlx3 may antagonize transcriptional repressor activity of Msx2 more effectively and for longer period than wtDlx3, resulting in enhancement of osteoblast differentiation.

• 한국환경과학회지
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• 제19권5호
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• pp.565-575
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• 2010

This study is mainly focused on micellar effect of cetylpyridinium chloride(CPyCl) solution including alkylbenzimidazole(R-BI) on dephosphorylation of diphenyl-4-nitrophenylphosphinate(DPNPIN) in carbonate buffer(pH 10.7). The reactions of DPNPIN with R-BI$^{\ominus}$ are strongly catalyzed by the micelles of CPyCl. Dephosphorylation of DPNPIN is accelerated by BI$^{\ominus}$ ion in $10^{-2}M$ carbonate buffer(pH 10.7) of $4{\times}10^{-3}M$ CPyCl solution up to 100 times as compared with the reaction in carbonate buffer by no BI solution of $4{\times}10^{-3}M$ CPyCl. The value of pseudo first order rate constant($k^m_{BI}$) of the reaction in CPyCl solution reached a maximum rate constant increasing micelle concentration. Such rate maxima are typical of micellar catalyzed bimolecular reactions. The reaction mediated by R-BI$^{\ominus}$ in micellar solutions are obviously slower than those by BI$^{\ominus}$, and the reaction rate were decreased with increase of lengths of alkyl groups. It seems due to steric effect of alkyl groups of R-BI$^{\ominus}$ in Stern layer of micellar solution. The surfactant reagent, cetylpyridinium chloride(CPyCl), strongly catalyzes the reaction of diphenyl-4-nitrophenylphosphinate(DPNPIN) with alkylbenzimidazole (R-BI) and its anion(R-BI$^{\ominus}$) in carbonate buffer(pH 10.7). For example, $4{\times}10^{-3}M$ CPyCl in $1{\times}10^{-4}M$ BI solution increase the rate constant ($k_{\Psi}=1.0{\times}10^{-2}sec^{-1}$) of the dephosphorylation by a factor ca.14, when compared with reaction ($k_{\Psi}=7.3{\times}10^{-4}sec^{-1}$) in $1{\times}10^{-4}M$ BI solution(without CPyCl). And no CPyCl solution, in $1{\times}10^{-4}M$ BI solution increase the rate constant ($k_{\Psi}=7.3{\times}10^{-4}sec^{-1}$) of the dephosphorylation by a factor ca.36, when compared with reaction ($k_{\Psi}=2.0{\times}10^{-5}sec^{-1}$) in water solution(without BI). This predicts that the reactivities of R-BI$^{\ominus}$ in the micellar pseudophase are much smaller than that of BI$^{\ominus}$. Due to the hydrophobicity and steric effect of alkyl group substituents, these groups would penetrate into the core of the micelle for stabilization by van der Waals interaction with long alkyl groups of CPyCl.

• 한국전문물리치료학회지
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• 제30권1호
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• pp.50-58
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• 2023

Background: This study was carried out to determine whether non-face-to-face physical therapy would have similar exercise effects to face-to-face physical therapy. Hence, we developed an approach for patients, unable to visit hospitals due to circumstances such as the COVID-19 pandemic, to conduct physical therapy comfortably at home. Objects: This study aimed to compare the effects of a face-to-face and a non-face-to-face physical therapy treatment on improving a rounded shoulder posture. Methods: The participants with rounded shoulders were randomly divided into a face-toface group (n = 15) and a non-face-to-face group (n = 15), and each group performed exercises for four weeks. The exercise program consisted of the bare hands exercise, Thera-Band exercise, and foam roller exercise. The participants in the face-to-face group came to a designated place to perform their exercises, and those in the non-face-to-face group performed the exercises at their own home using Google Meet (Google). Acromial height, total scapular distance (TSD), shoulder pain and dysfunction index (SPADI), and pectoralis minor thickness were measured. Data analysis was performed using the R Statistical Software (R Core Team), and a normality test was performed using the Shapiro-Wilk test. Results: There were no significant differences between the face-to-face and the non-face-toface groups (p > 0.05). When comparing the differences before and after the exercises, both the face-to-face and the non-face-to-face groups showed significant differences in acromial height, SPADI, and pectoralis minor thickness (p < 0.05), and both groups showed no significant difference in TSD before and after the exercises (p > 0.05). Conclusion: The results of this study support the results of previous studies reporting that shoulder stabilization exercise and pectoralis minor stretching training improves round shoulders. In addition, this study revealed that both the face-to-face and the non-face-to-face physical therapy treatments had therapeutic effects.

• 한국체육학회지인문사회과학편
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• 제55권6호
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• pp.749-757
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• 2016

이 연구의 목적은 요가의 한발서기자세를 수련 후 신체안정화에 어떠한 영향을 미치는지를 규명하는 것이다. 요가수련 경험이 없는 20대 여성 13명을 대상으로 24개월간 수련 전·후의 3D동작분석과 근육 생체 신호를 측정하였고 분석 결과는 다음과 같다. 첫째, 댄서포즈에서 왼쪽 무릎의 y축과 오른쪽 발목의 x축, 그리고 트리포즈에서 오른쪽 발목의 x축, 왼쪽 발목 y축의 관절 움직임 범위가 작아지며 통계적으로 유의한 차이를 보였다(p<.05). 둘째, 몸통과 골반의 정렬각은 댄서포즈와 트리포즈 모두에서 유의한 차이가 없었다. 셋째, 질량중심 이동거리는 트리포즈의 Y, Z방향에서 작아지며 유의한 차이를 보였다(p<.05). 넷째, 트리포즈 동작에서 양쪽 척추기립근, 복직근 및 왼쪽 대퇴사두근의 근활성도가 커지면서 유의한 통계적 차이를 보였다(p<.05). 이러한 결과는 요가 훈련이 특히 발목과 질량중심 움직임을 작게하고, 코어근육을 강화시켜 안정적 자세를 만드는데 중요한 역할을 한다고 할 수 있다. 결론적으로 요가 훈련은 자세 안정화에 효과가 있으며, 자세교정에 영향을 미친다고 할 수 있다. 추후 요가훈련을 통해 자세안정화를 볼 수 있는 정렬각의 변인을 통해 얻을 수 있는 정보에 대한 연구가 더 필요할 것으로 사료된다.

• 대한화학회지
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• 제29권5호
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• pp.522-532
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• 1985

CTABr 미셀용액속에서 benzimidazole 및 naphth-2,3-imidazol 음이온($BI^-$ 및$NI^-$)에 의해 추진되는 p-nitrophenyldiphenylphosphate (p-NPDPP)의 탈인산화반응에 대한 속도론적 연구에서 이들 음이온은 친핵체로 작용하며 미셀은 반응을 급격히 촉진시킨다는 연구 결과를 밝힌바이다. 본 연구에서는 $BI^-$의 2위치에 알킬기가 치환된 음이온(R-$BI^-$)들에 의한 탈인산화반응을 다루었다. 미셀 용액속에서 R-$BI^-$에 의해 추진되는 반응은 $BI^-$에 의해 추진되는 반응보다 약 3배 느리게 일어난다. 이러한 속도의 감소효과를 밝히기 위하여 미셀의사층(micellar pseudophase) 내에 존재하는 $BI^-$와 R-$BI^-$의 농도비와 이들에 의해 추진되는 반응의 1차 및 2차 속도상수의 비를 비교하였다. 음이온 농도의 비([R-$B^-$]/[$BI^-$])에 비하여 반응의 1차 속도상수의 비$(k'_{R-BI^-}/k'_{BI^-})가 훨씬 적었다. 예를 들면$5 {\times}10^{-4}$M butyl-BI 용액속에서의 반응에서 농도의 비는 0.430인데 반하여 반응속도의 비는 0.089였다. 이 두 값의 차이(0.0341)는 butyl기의 영향이 70%에 이른다는 계산이 가능하다. 이것은 미셀의사층속에서 R-$BI^-$의 반응성이 그들의 알킬기의 영향으로 말미암아 $BI^-$의 반응성보다 작음을 의미한다. 또한 $10^{-4}$M R-BI 용액에서의 이 반응의 2차 반응속도 상수도 알킬기의 사슬이 길어질수록 미셀 의사층에서 R-$BI^-$에 의해 추진되는 반응이 $BI^-$에 의한 반응보다 현저하게 감소하였다. 예컨대 butyl-BI의 경우 이들의 반응속도의 비$(k_{m(R-BI^-)}/k_{m(BI^-)})$가 약 10배 감소하였다. R-$BI^-$들의 알킬기의 변화에 따른 1차 및 2차 반응속도의 변화를 정밀히 분석하여 다음과 같은 모델을 제시한다. 즉 미셀내에 존재하는 R-$BI^-$의 알킬기는 그들의 소수성과 입체장해 때문에 Stern층내에 자리하지 못하고 미셀의 핵(core)속으로 침투해 들어가게 될 것이며, 그 결과 분자 전체가 자유롭게 움직이지 못하고 한 곳에 고정될 것이다. 따라서 기질(p-NPDPP)과의 충돌빈도(collison frequency)가 감소하게 되고, 이로 말미암아 반응속도가 감소하게 될 것이다. 본인들은 이 효과를 "닻줄 효과"(anchor effect)라 명명하고자 한다. 이 효과는 R-$BI^-$의 알킬기가 길수록 그리고 이들의 농도가 증가할수록 현저하게 증가하였다.

• 한국환경생태학회지
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• 제26권4호
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• pp.498-511
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• 2012

산지습지는 멸종위기야생동식물 II 급인 끈끈이주걱과 지표종인 이삭귀개, 잠자리난초, 물매화, 진퍼리새 등이 분포하여 중요성은 높으나, 자연적 또는 인위적인 과정에 의해 건조화가 빠르게 진행되고 있어 시급한 관리가 필요한 실정이다. 본 연구는 정확한 자연생태계 현황 및 건조화 진행 실태를 파악하여 습지생태계 보존대책과 건조화 관리 방안을 제시하고자 한다. 화엄늪은 경사도 $10^{\circ}$ 미만(86.1%), 해발 750~810m(87.4%)로 산지습지의 적지라고 할 수 있으나 하부에 깊이 1.6m, 폭 0.8m인 수로가 형성되어 이탄층 유실, 수위저하 등으로 인한 건조화 진행이 우려되었다. 습지보호지역 내 식생은 진퍼리새 등 습윤지성 식생이 분포하는 면적이 6.7%로 협소한 반면, 참억새, 미역줄나무 등 산림성 목본 및 건조지성 초본이 우점하여 방치시 숲생태계로의 천이가 예상된다. 건조화를 예방하고 양호한 생태계의 지속적인 보존을 위해 식생의 생태적 특성을 고려한 보존 및 관리지역 설정, 습지보호를 위해 천이에 영향을 미치는 주연부 식생 관리, 핵심지역 보호를 위한 완충지역 설정을 제안하였다. 관리에 있어서는 습지훼손 요인관리를 위하여 수계로의 과도한 지하수 유출 억제를 통한 물고임 습지 안정화와 산지습지 지표종에 대한 보호 및 관리식물 지정, 습지의 산림화를 유발 촉진할 수 있는 건조지성 수목을 관리해야 할 것이다.