• Title/Summary/Keyword: copper number

검색결과 336건 처리시간 0.028초

구리 내성균(Pseudomonas stutzeri)의 균체내 구리 축적특성 (Copper Accumulation in Cells of Copper-Tolerant Bacteria, Pseudomonas stutzeri)

  • 조주식;한문규;이홍재;허종수
    • 한국환경농학회지
    • /
    • 제16권1호
    • /
    • pp.48-54
    • /
    • 1997
  • 구리 내성균인 P. stutzeri의 균체내 구리 축적 특성, 축적형태 및 균체내에 축적된 구리의 회수 방법을 조사한 결과는 다음과 같다. 구리 농도가 100mg/l인 용액중에서 치리 48시간 후 구리 내성균주의 구리 처리율은 약 78% 이상이었다. 구리가 축적된 균체를 전자현미경으로 관찰한 결과, 균체의 cell wall과 cell membrane에 많은 electron-dense granule들이 형성되어 있었으며, electron-dense granule들은 EDS로 분석한 결과, 이 granule들은 copper complex인 것으로 확인되었다. 구리 내성균주의 균체내 축적된 구리는 증류수에 의해서는 거의 탈착이 되지 않았으나 EDTA 처리에 의해서는 약 80% 이상 탈착되었다. 구리가 축적된 균체를 $550^{\circ}C$에서 회화시켰을 때 건조균체량의 약 23.2%에 해당하는 작열잔류화합물들이 생성되었으며, 이 작열잔류화합물들은 EDS로 분석한 결과, 구리가 약 78.4% 이상 함유되어 있는 비교적 순수한 구리 화합물인 것으로 확인되었다.

  • PDF

구리 재질의 평판 핀과 나선형 핀이 사용된 핀-관 열교환기의 공기측 성능 (Air-Side Performance of Fin-and-Tube Heat Exchanger with Copper Plate or Copper Spiral Fins)

  • 이진욱;박지훈;이정표;김내현
    • 대한기계학회논문집B
    • /
    • 제35권3호
    • /
    • pp.269-278
    • /
    • 2011
  • 본 연구에서는 구리 재질의 평판 핀과 나선형 핀-관 열교환기에 대하여 핀 피치와 열수의 변화에 따른 공기측 전열성능을 검토하였다. 두 형상 모두 핀 피치가 열전달계수에 미치는 영향은 미미하였다. 마찰인자는 핀 피치가 증가하면 증가하였다. 열수가 미치는 영향은 형상에 따라 다르게 나타났다. 평판 핀-관 열교환기의 경우 열전달계수는 열수가 증가할수록 감소하였다. 하지만 나선형 핀-관 열교환기의 열전달 계수는 열수가 증가하면서 그 값이 증가하는 경향을 보였다. 평판 핀-관 열교환기의 열전달계수는 나선형 핀-관 열교환기의 열전달계수보다 높게 나타났다. 하지만 열수가 증가하면 그 차이가 줄어들어 4열이 되면 거의 같았다. 한편 마찰인자는 평판 핀-관 열교환기에서 다소 높게 나타나고 열수의 영향은 크지 않았다. 본 실험 데이터를 기존 상관식의 예측치와 비교하였다.

자궁내피임장치 카파티 380A에 관한 임상적 고찰 (Clinical Expenience with Copper T 380A Intrauterine Contraceptive Device)

  • 배병주;황영환
    • Clinical and Experimental Reproductive Medicine
    • /
    • 제21권2호
    • /
    • pp.221-226
    • /
    • 1994
  • Copper T 380A intrauterine devices were inserted to nine thousand and nine hundred twenty women by 51 KAVS-member physicians since January 1, 1993 through December 31, 1993. This study was undertaken for the clinical analysis on a total of 9,920 women wearing Copper T 380A to grasp the effectivness as well as the expulsion rate due to a various side effects. The following features were the results of the study: 1. During the twelve months period, from January 1993 to December 1993, the largest number of IUD insertion per one physician is 740 cases and the smallest number 60 cases, the mean 195 cases. 2. After insertion of Copper T 380A, a total of 117 cases were removed the IUD;81 cases(0.8%) were due to extensive bleeding and 36 cases(O.36%) were due to pain. The pregnancy failure rate represented comparatively lower rate, 0.08% (8 cases) and the expulsion rate was 0.06%(6 cases). 3. The removal rate of Copper T 380A was different by physicians. The highest removal rate for bleeding was 3.13% and 13 physicians(25.5%) did not experience any bleeding cases. 4. For the removal rate for pain, 30 physicians(58.8%) did not experience any removal of IUD due to pain while 21 physicians(41.2%) removed IUD due to pain: 17 physiciansC33.4 %) had 0.1-1.5% of removal rate and 4 physiciansC7.0%) had 1.6-2.1% of removal rate. 5. A total of 43 physicians(84.3 %) did not experience any pregnancy failure case while 8 (15.7%) physicians was experienced pregnancy failure rate. Four physicians(7.8%) had 0.1-0.5% of pregnancy failure rate and 4 physicians had 0.6-1.0% of pregnancy failure rate. 6. Expulsion rate showed comparatively lower, 0.06% in this study. A total of 45 physicians (88.2%) did not experience any expulsion cases while 6 physicians(11.7%) had expulsion rate with the highest expulsion rate of 2.0%.

  • PDF

Nutirtional Status of Iron, Zinc and Copper of Preschool Children Residing in Low-Income Area of Seoul

  • Son, Sook-Mee;Park, Sung-Hee
    • Journal of Community Nutrition
    • /
    • 제1권1호
    • /
    • pp.3-9
    • /
    • 1999
  • This study was performed to investigate the biochemical status of iron, zinc and copper for 125 preschool children (Males : 69, Females : 56) residing in a low-income area of Seoul. The number of subjects aged, 3, 4, 5 and 6 were 19, 41, 41 and 24, respectively. The hemoglobin level of the children aged 3 was 11.8 g/dl and was lower thant hat of the other groups(p<0.05). Similar results were found for hematocrit and serum zinc. The percentage of children with an iron deficiency assessed by Hb(3-5) years : <11.0g/dl, 6 years: <11.5g/dl), Hct(3-6 years : 33%, 6 years : <35%), serum transferrin(<16%) and serum ferritin(<10ng/ml) were 4.3%, 9.5%, 8.2% and 17.7%, respectively. The mean serum zinc was 67.9$\mu\textrm{g}$/dl and urinary zinc was 0.1300mg/day. Low serum zinc (61.0$\mu\textrm{g}$/dl) occurred in 28.0% of the children. The mean serum copper was 110.5$\mu\textrm{g}$/dl and urinary copper was 0.0126mg/day. The prevalence of children with elevated serum copper($\geq$ 130$\mu\textrm{g}$/dl) was 54.8%, which was higher than 7.4%, the prevalence of low serum copper(<70$\mu\textrm{g}$/dl). Children with higher status, more weight, larger girth of chest, or larger midarm circumference showed higher values of Hb. The height and weight of children also showed a positive crrelation with serum zinc(P<0.001-P<0.05).

  • PDF

Histopathology and residues in fresh water fish exposed to acute and chronic copper and mercury toxicity

  • Sawsan, H.A.;Amira, H.M.;Mostafa, M.B.;Nashaat, AM.M.
    • 한국어병학회지
    • /
    • 제30권2호
    • /
    • pp.115-134
    • /
    • 2017
  • A total number of 668 apparently healthy fish were obtained from farm to study the effect of two heavy metals (Copper and Mercury) on histopathology of liver, kidney, spleen, gills and muscles also residues in muscles. The $LC_{50}$/96 hr. of Cu and Hg were estimated and fish exposed to 1/2 $LC_{50}$ for 7 days and for 1/10 $LC_{50}$ for 8 weeks from each product separately. Histopathological findings in acute and chronic mercuric chloride toxicity revealed degeneration and necrosis in the glomeruli, interstitium tissue and epithelium lining renal tubules. The tubular epithelium became necrotic at several places. Eosinophilic hyaline droplets is exist in the cytoplasm of the necrosed cells. Degenerative changes and hyperactivity in melanomachrophage center was seen in the spleen together with some necrotic areas. Necrosis and aggregation of melanomachrophage were seen in the hepatic cells, Hepatic cells showed vacuolar degeneration in the hepatic cells. Gills showed loss in the lamellae of the filaments associated with edema, inflammatory cells infiltration and haemorrhages in the arch. The sarcoplasm of the bundles of the skeletal muscle showed granular degeneration and focal inflammatory cells infiltration between the hyalinized bundles. Mercury residues obtained from these studies in the acute toxicity were 0.22 ppm/gm in the 2nd day, 0.411 ppm/gm in the $5^{th}$ day ended with 0.96 ppm/gm in the $7^{th}$ day. In chronic toxicity it was 1.1320, 1.7140, 2.3620 and 3.5640 ppm/gm respectively from the $2^{nd}$ to the $8^{th}$ week of exposure. In acute and chronic copper toxicity, there was degenerative changes in renal tubules. Melanophores aggregation in the wall of the blood vessels of the spleen and depletion of some of the melanophores in the melanomachrophage were seen together with necrosis in some areas. Congested Mvs (Micro vessels) and vacuolation of hepatocytes were observed. Some areas of hemorrhage and melanophores vacuolar degeneration in the liver were seen. There was mitosis in some areas with displesia of hepatopancreatic cells and eosinophilic granular cells aggregation. Zymogen granules disappeared and there were dyplastic hepatocytes. Congestion in the blood vessels of the gill filaments, associated with massive number of granular eosinophilic cells infiltration were seen in the base of the filaments. There were sever vacuolization and hyalinization in the skeletal muscle bundles. Detection of residues of copper sulfate revealed increase of the amount of copper measured in ppm/gm comparing to the normal control starting from 0.60 ppm/g in the $2^{nd}$ day, 0.67 ppm/g in the $5^{th}$ day and 0.67 ppm/g in the $7^{th}$ day. Result obtained in chronic copper sulfate toxicity revealed gradual increase of the amount of copper which ranged from 0.18 ppm/g at the $2^{nd}$ week to 0.21 ppm/g in the $8^{th}$ week of exposure.

Copper(II) Selective PVC Membrane Electrodes Based on Schiff base 1,2-Bis (E-2-hydroxy benzylidene amino)anthracene-9,10-dione Complex as an Ionophore

  • Jeong, Eun-Seon;Lee, Hyo-Kyoung;Ahmed, Mohammad Shamsuddin;Seo, Hyung-Ran;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권2호
    • /
    • pp.401-405
    • /
    • 2010
  • The Schiff base 1,2-bis(E-2-hydroxy benzylidene amino)anthracene-9,10-dione has been synthesized and explored as ionophore for preparing PVC-based membrane sensors selective to the copper ($Cu^{2+}$) ion. Potentiometric investigations indicate high affinity of these receptors for copper ion. The best performance was shown by the membrane of composition (w/w) of ionophore: 1 mg, PVC: 33 mg, DOP: 66 mg and KTpClPB as additive were added 50 mol % relative to the ionophore in 1 ml THF. The proposed sensor's detection limit is $2.8{\times}10^{-7}$ M over pH 5 at room temperature (Nernstian slope 31.76 mV/dec.) with a response time of 15 seconds and showed good selectivity to copper ion over a number of interfering cations.

레이저에 의한 폴리머상의 무전해 도금 시드 형성 메커니즘 연구 (Study on the Formation Mechanism of Electroless Plating Seeds on Polymer by Laser)

  • 백병만;이제훈;신동식;이건상
    • 한국정밀공학회지
    • /
    • 제29권1호
    • /
    • pp.41-47
    • /
    • 2012
  • The LDS(Laser Direct Structuring) is one of the new direct writing methods to fabricate conductive patterns by energy beam. It uses thermoplastic polymers with an additive compound that serves as plating seed after the activation by laser. The advantages of LDS include the miniaturization of electrical components, design flexibility, and a reduced number of production steps. The purpose of this study is to investigate the fundamental mechanism for LDS and the characteristics of conductive patterns by laser parameters. These results were studied by SEM, EDX, and XPS analysis. We have used a 20W pulse-modulated fiber laser and copper electroless plating to fabricate conductive patterns on polymer. The result showed that electroless copper plating seed caused the laser cracking of additive compound. In particular, the additive compound contained in copper metal oxides atoms will be changed to copper metal elements. Also, the characteristics of conductive patterns were dependent on laser parameter, especially laser fluence.

30 W COB LED광원의 효율 개선을 위한 방열설계에 관한 연구 (A Study on Improving the Efficiency of a Heat Dissipation Design for 30 W COB LED Light Source)

  • 서범식;이기정;조영식;박대희
    • 한국전기전자재료학회논문지
    • /
    • 제26권2호
    • /
    • pp.158-163
    • /
    • 2013
  • In this paper, thermal analysis of heatsink for 30 W class Chip-on-Board (COB) LED light source is performed by using SolidWorks Flow Simulation package. In order to increase the convection heat transfer, number of fin and shape of the heatsink is optimized. Furthermore, a copper spread is applied between the COB LED light source and the heatsink to mitigate the heat concentration on the heatsink. With the copper spread, the junction temperature between the COB LED light source and the heatsink is $50.9^{\circ}C$, which is $5.4^{\circ}C$ lower than the heatsink without the copper spread. Due to the improvement of the junction temperature, the light output is improved by 5.8% when the LED light source is stabilized. The temperature difference between the simulation and measured result of the heatsink with the copper spread is within $2^{\circ}C$, which verifies the validity of the thermal design method using a simulation package.

Planar Laser-Induced Fluorescence (PLIF) Measurements of a Pulsed Electrothermal Plasma Jet

  • Kim, Jong-Uk;Kim, Youn J.;Byungyou Hong
    • Journal of Mechanical Science and Technology
    • /
    • 제15권12호
    • /
    • pp.1808-1815
    • /
    • 2001
  • The characteristics of a pulsed plasma jet originating from an electrothermal capillary discharge have been investigate using laser-induced fluorescence (LIF) measurement. Previous emission measurements of a 3.1 kJ plasma jet show trial upstream of the Mach disk the temperature and electron number density are about 14,000 K and and 10$\^$17/ cm$\^$-3/, while downstream of the Mach dick tole values are about 25,000 K and 10$\^$18/ cm$\^$-3/, respectively. However, these values are barred on line-of-sight integrated measurements that may be misleading. Hence, LIF is being used to provide both spatially and temporally resolved measurements. Our recent work has been directed at using planar laser-induced fluorescence (PLIF) imaging of atomic copper in the plasma jet flow field. Copper is a good candidate for PLIF studies because it is present throughout the plasma and has electronic transitions that provide an excellent pump-detect strategy. Our PLIF results to date show that emission measurements may give a misleading picture of the flow field, as there appeals to be a large amount of relatively low temperature copper outside the barrel shock. which may lead to errors in temperature inferred from emission spectroscopy. In this paper, the copper LIF image is presented and at the moment, relative density of atomic copper, which is distributed in the upstream of the pulsed plasma jet, is discussed qualitatively.

  • PDF

단상유도전동기의 동 다이캐스팅과 손실 저감을 위한 고정자 설계 (The Copper Rotor Die-casting of Single Phase Induction Motor and the Stator Design for Reducing Loss)

  • 이상훈;김기찬;김광수;김수용;김원호;이주
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2008년도 제39회 하계학술대회
    • /
    • pp.705-706
    • /
    • 2008
  • There has been, in recent years, effort to make cast copper rotors for industrial use of induction motors. Because the incorporation of copper for the conductor bars and end rings of the induction motor in place of aluminum would result in attractive improvements in motor energy efficiency. The purpose of this method is a reducing the copper loss as using higher conductivity of copper. In this paper as the single phase induction motor is studied, the stator slots and coil turn number is designed for adjusting the slot fill factor and improving its efficiency. At this time design is basis on calculation of reducing loss. And finally this paper shows that the before and after result is compared and analyzed.

  • PDF