• 제목/요약/키워드: copoly((4-methacryloyloxy) chalcone-cholesteryl methacrylate))

검색결과 7건 처리시간 0.02초

Chalconyl과 Cholesteryl group을 가진 methacryl계 공중합체를 이용한 프리틸트 발생에 관한 연구 (Study on generation of pretilt angle using a methacrylic copolymers having cholconyl and cholesteryl groups.)

  • 황정연;서대식
    • 한국전기전자재료학회논문지
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    • 제13권7호
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    • pp.625-629
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    • 2000
  • We synthesized a new copoly (PM4Ch-ChMA) copoly(poly(4-methacryloyloxy) chalcone-cholesteryl methacrylate) having chalconyl and cholesteryl moiety for homeotropic liquid crystal(LC) alignment. Pretilt angles of nematic(N) LC generated by linearly polarized UV exposure on the copolymer surfaces were investigated. Good thermal stabilities of the synthesized copolymer were obtained by TGA (Thermogravimetric Analysis) measurement. Pretilt angles of the NLC decreased with increasing UV exposure time on the copolymer surfaces. We consider that the pretilt angle of the NLC is attributed to increased chalcone by increased UV exposure time. High pretilt angle of the NLC is attributed to increased chalcone by increased UV exposure time. High pretilt angle of 81$^{\circ}$was observed after the UV exposure for 3 min.

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Chalconyl 과 Cholesteryl 기를 함유한 광폴리머의 합성 및 LCD 응용 (Synthesis of photopolymer containing chalconyl and cholesteryl moieties and their LCD applications)

  • 황정연;서대식;김재형;손정호;서동학
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.137-140
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    • 2000
  • Synthesis of a new copoly (M4Ch-ChMA), copoly ((4-methacryloyloxy) chalcone-cholestery methacrylate), with chalconyl and cholesteryl moiety characteristics for photoalignment materials was investigated. Good thermal stabilities of the synthesized copolymers are confirmed by thermogravimetric analysis (TGA) measurement. The pretilt angles of the nematic liquid crystal (NLC) are reduced as UV exposure time is increased on the copolymer surfaces. A pretilt angle of 81$^{\circ}$ in NLC was observed with UV exposure of 3 min on the copolymer-3 surface. The NLCs pretilt angle is attributable to increased chalcone with increasing the UV exposure time.

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Cholesteryl 기를 함유한 수직배향용 광폴리머 재료의 합성 및 배향 효과 (Liquid crystal alignment effect and synthesis of photo-polymer material containing cholesteryl moiety for homeotropic alignment)

  • 황정연;서대식;한은주
    • 한국전기전자재료학회논문지
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    • 제13권9호
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    • pp.770-775
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    • 2000
  • A new photo-polymer material of the copoly (PM4Ch-ChMA), copoly (poly (4-methacryloyloxy)chalcone-cholesteryl methacrylate) for homeotropic alignment was synthesized and the electro-optical (EO) performance for the photo-aligned vertical-aligned (VA)-LC display (LCD) was studied. Good thermal stabilities of synthesized copolymer were obtained by TGA(Thermogravimetric Analysis) measurement. Good voltage-transmittance (V-T) and response time characteristics for the photo-aligned VA-LCD with polarized UV exposure in oblique direction($\theta$$_{i}$=30$^{\circ}$) on a copolymer-1 (2%) surfaces for 1 min were observed. but, light leakage in the off-state was observed. Therefore, we achieved excellent V-T and response time characteristics for the photo-aligned VA-LCD with UV exposure on a copolymer-3 (30%) surfaces for 3 min.n.

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Chalconyl 과 Cholesteryl 기를 함유한 광폴리머의 합성 및 LCD 응용 (Synthesis of photopolymer containing chalconyl and cholesteryl moieties and their LCD applications)

  • 황정연;서대식;김재형;손정호;서동학
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2000년도 추계학술대회논문집
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    • pp.137-140
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    • 2000
  • Synthesis of a new copoly (M4Ch-ChMA), copoly ((4-methacryloyloxy) chalcone-cholestery methacrylate), with chalconyl and cholesterol moiety characteristics for photoalignment materials was investigated. Good thermal stabilities of the synthesized copolymers are confirmed by thermogravimetric analysis (TGA) measurement. The pretilt angles of the nematic liquid crystal (NLC) are reduced as UV exposure time is increased on the copolymer surfaces. A pretilt angle of 81$^{\circ}$in NLC was observed with UV exposure of 3 min on the copolymer-3 surface. The NLCs pretilt angle is attributable to increased chalcone with increasing the UV exposure time.

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새로운 광 폴리머를 이용한 광배향 VA-LCD의 전기 광학 특성 (Electro-optical characteristics of photo-aligned VA-LCD using a new photo-polymer)

  • 황정연;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.181-184
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    • 2000
  • A new photo-alignment material, copoly (PM4Ch-ChMA), copoly (poly (4-methacryloyloxy) chalcone-chalconemethacryl) was synthesized and the electro-optical (EO) characteristics for the photo-aligned vertically aligned (VA)-LC display (LCD) were investigated. The monodomain alignment of the NLC for the photo-aligned VA-LCD by linearly polarized UV exposure on the photo-dimerized copoly (PM4Ch-ChMA) surfaces was observed. Excellent voltage-transmittance characteristics for the photo-aligned VA-LCD by UV exposure for 1 min. on the copoly (PM4Ch-ChMA) surfaces were achieved. The response time of the photo-aligned VA-LCD by UV exposure on for 1 min. the copoly (PM4Ch-ChMA) surfaces was about 39.3 ms. The response time for the photo-aligned VA-LCD decreased with increasing UV exposure time.

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Effect of Liquid Crystal Alignment for Photo-Aligned VA-LCD on the Photo-Dimerized Polymer Surface

  • Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Journal of the Optical Society of Korea
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    • 제5권1호
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    • pp.16-19
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    • 2001
  • A photopolymer, copoly (M4Ch-ChMA), copoly ((4-methacryloyloxy) chalcone-cholesteryl methacrylate), was synthesized in this study. The electro-optical (EO) characteristics for the photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) were investigated. Excellent voltage-transmittance curves for the VA-LCD photo-aligned by polarized UV exposure on the copoly (M4Ch-ChMA) surface were observed. The response time for the photo-aligned VA-LCD decrease with increasing UV exposure time. consequently, the photo-dimerized chalcone moiety increased with increasing UV exposure time, which then contributed to a low response time for the VA-LCD photo-aligned.

Chalconyl과 Cholesteryl기를 함유한 광폴리머의 테마틱 액정의 배향 (Alignment capabilities of nematic liquid crustal using a photo-polymer containing chalconyl and cholesteryl moiety)

  • 황정연;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.835-838
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    • 2000
  • A new photo-alignment material, copoly (PM4Ch-ChMA), copoly (poly (4-methacryloyloxy) chalcone-cholesterol methacrylate) was synthesized and the electro-optical (EO) characteristics for the photo-aligned vertical-aligned (VA)-LC display (LCD) were studied. Good voltage-transmittance (V-T) and response time characteristics for the photo-aligned VA-LCD with polarized UV exposure on the copolymer-1 (2%) surfaces for 1 min. were observed. EO performance for the photo-aligned VA-LCD decreased with increasing UV exposure time on a copolymer surface. Also, excellent V-T and response time characteristics for the photo-aligned VA-LCD with UV exposure on copolymer-2 and copolymer-3 surfaces for 3min. can be achieved.

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