• Title/Summary/Keyword: coordination center

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Preparation and Pore-Characteristics Control of Nano-Porous Materials using Organometallic Building Blocks

  • Oh, Gyu-Hwan;Park, Chong-Rae
    • Carbon letters
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    • v.4 no.1
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    • pp.1-9
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    • 2003
  • Recently, the control of pore-characteristics of nano-porous materials has been studied extensively because of their unique applications, which includes size-selective separation, gas adsorption/storage, heterogeneous catalysis, etc. The most widely adopted techniques for controlling pore characteristics include the utilization of pillar effect by metal oxide and of templates such as zeolites. More recently, coordination polymers constructed by transition metal ions and bridging organic ligands have afforded new types of nano-porous materials, porous metal-organic framework(porous MOF), with high degree and uniformity of porosity. The pore characteristics of these porous MOFs can be designed by controlling the coordination number and geometry of selected metal, e.g transition metal and rare-earth metal, and the size, rigidity, and coordination site of ligand. The synthesis of porous MOF by the assembly of metal ions with di-, tri-, and poly-topic N-bound organic linkers such as 4,4'-bipyridine(BPY) or multidentate linkers such as carboxylates, which allow for the formation of more rigid frameworks due to their ability to aggregate metal ions into M-O-C cluster, have been reported. Other porous MOF from co-ligand system or the ligand with both C-O and C-N type linkage can afford to control the shape and size of pores. Furthermore, for the rigidity and thermal stability of porous MOF, ring-type ligand such as porphyrin derivatives and ligands with ability of secondary bonding such as hydrogen and ionic bonding have been studied.

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Facilitated Transport of Oxygen in Copolymer Membranes of Styrene and 4-Vinylpyridine Containing Cobalt Schist Base Carrier : Effect of Membrane Thickness and Carrier Concentration

  • Hong, Jae-Min;Kang, Yong-Soo
    • Macromolecular Research
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    • v.8 no.1
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    • pp.1-5
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    • 2000
  • The valiclity of the simple mathematical model for facilitated transport in a solid state membrane developed previously has been examined againsts the carrier concentration and membrane thick-ness. Membranes are prepared with copolymer of styrene and 4-vinylpyridine as a matrix and Co(salen) as a carrier. 4-Vinylpyridine is incorporated to provide the coordination site for Co(salen) carrier. Oxygen permeability through the facilitated transport membrane is linearly increased with the square of its thick-ness, as predicted by the mathematical model. However, the oxygen permeability does not increase linearly with the carrier concentration. This seems to be due to the deactivation of the carrier by dimerization at high carrier concentrations as well as the reduced chain mobility by coordination of bulky Co(salen) carrier.

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A Study on the Standardization of the System Kitchen by Utilizing Reference Plane (조립기준면을 활용한 시스템키친의 표준화 연구)

  • Lee, Ga-Kyung;Lim, Seok-Ho
    • Journal of the Korean housing association
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    • v.21 no.6
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    • pp.43-52
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    • 2010
  • It has applied the design method of face to face dimension, an MC (Modular Coordination) design method, at design steps of an apartment house for standardization of architecture. But It has been still using center line size. A construction limit isn't specific on these center line size, and dead space occurs with excessive gaps as size matching isn't performed well between structural sieve and parts. And above all, measurement before construction isn't to expect standardization, and to increase custom-made furniture. We investigate manufacture of a preferential domestic system kitchen and construction state, and we derive from a problem in viewpoints of standardization for this. And we utilized a reference plane, and we present construction document and design plan in order to solve these problems. And we analyze an effect got by application of the assembly basis aspect that we presented, and we can raise efficiency of standardization of housing and construction industry, and we light ultimately up.

AN EXPERT SYSTEM FOR SETTING AND COORDINATION OF PROTECTIVE RELAYS (보호계전기의 정정 협조 전문가 시스템)

  • Lee, Seung-Jae;Kim, Ki-Hwa;Cho, Young-Ik;Yoon, Sang-Hyun;Yoon, Man-Chul;Lee, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.358-362
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    • 1991
  • This paper describes enhancements made on PROSET, an, expert system which can perform setting and coordination of protective relays used in the ultra-high voltage transmission systems. Enhancements include the friendly and convenient environment for rulebase management and system manipulation, expanded setting capability, and faster processing speed which have been achieved through adoption of the new rule representation, rule order independent IE, rulebase editor, local database generator, Interface to PSS/E fault program, RB expansion etc.

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Cellular coordination controlling organ separation and surface integrity in plants

  • Lee, Yuree;Kwak, June M.
    • BMB Reports
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    • v.51 no.7
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    • pp.317-318
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    • 2018
  • Plants are unable to relocate themselves to a more favorable location and thus have to deal with developmental programs and environmental cues wherever they happen to be. It is yet largely unknown how plant cells coordinate cellular activities and architectures to accomplish developmental processes and respond to environmental changes. By identifying and establishing a new cellular model system, we have discovered that two neighboring cell types in the abscission zone (AZ) of Arabidopsis flowers coordinate their activities to ensure a precise "cut" through a highly restricted area of plant tissue to bring about organ separation. From this perspective, we further discuss the essence of cellular coordination in AZ, the key molecules controlling the organ separation, and relevant implications.

Nephrotic syndrome: what's new, what's hot?

  • Kang, Hee Gyung;Cheong, Hae Il
    • Clinical and Experimental Pediatrics
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    • v.58 no.8
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    • pp.275-282
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    • 2015
  • While the incidence of nephrotic syndrome (NS) is decreasing in Korea, the morbidity of difficult-to-treat NS is significant. Efforts to minimize treatment toxicity showed that prolonged treatment after an initial treatment for 2-3 months with glucocorticosteroids was not effective in reducing frequent relapses. For steroid-dependent NS, rituximab, a monoclonal antibody against the CD20 antigen on B cells, was proven to be as effective, and short-term daily low-dose steroids during upper respiratory infections reduced relapses. Steroid resistance or congenital NS are indications for genetic study and renal biopsy, since the list of genes involved in NS is lengthening.

A Development of Software about Short-circuit Calculation and Protective-coordination (고장계산 및 보호협조 판정 소프트웨어 개발)

  • Park, S.C.;Choe, J.H.;Seo, J.M.
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.159-162
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    • 2002
  • A software, called touch-one, is developed about the determination of short-circuit values and protective co-ordination in power system. The used solution algorithm reviewed intensively, and the protective co-ordination determination technique presented by using the circuit-breaker's current-limitation characteristic. The protective coordination concerns the behaviour of two devices placed in series in an electrical network, with a short-circuit downstream circuit-breaker. It has two basic principles: First, discrimination which is an increasing requirement of low voltage electrical distribution systems. Second, which is less well known: cascading, which consists of installing a device, whose breaking capacity is less than the three-phase short-circuit current at its terminals and helped by main circuit-breaker. With this software, we can construct a electric-power system which is reliable and economic according to user's purpose.

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Blood-neural barrier: its diversity and coordinated cell-to-cell communication

  • Choi, Yoon-Kyung;Kim, Kyu-Won
    • BMB Reports
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    • v.41 no.5
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    • pp.345-352
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    • 2008
  • The cerebral microvessels possess barrier characteristics which are tightly sealed excluding many toxic substances and protecting neural tissues. The specialized blood-neural barriers as well as the cerebral microvascular barrier are recognized in the retina, inner ear, spinal cord, and cerebrospinal fluid. Microvascular endothelial cells in the brain closely interact with other components such as astrocytes, pericytes, perivascular microglia and neurons to form functional 'neurovascular unit'. Communication between endothelial cells and other surrounding cells enhances the barrier functions, consequently resulting in maintenance and elaboration of proper brain homeostasis. Furthermore, the disruption of the neurovascular unit is closely involved in cerebrovascular disorders. In this review, we focus on the location and function of these various blood-neural barriers, and the importance of the cell-to-cell communication for development and maintenance of the barrier integrity at the neurovascular unit. We also demonstrate the close relation between the alteration of the blood-neural barriers and cerebrovascular disorders.

Development of Expert System for Protection Coordination of Transmission Systems (송전계통 보호 협조 전문가 시스템의 개발)

  • Lee, Seung-Jae;Park, Young-Moon;Shim, Joung-Wook;Yoon, Sang-Hyun;Yoon, Man-Chul;Lee, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.129-132
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    • 1990
  • This paper reports an expert system for coordination of protective relays in the high voltage transmission system. The proposed system consists of five modules and has adopted the frame and production rule representations achieving the efficient data storage and knowledgebases. It has an interface to the fault program PSS/E and has reduced the data retrival time by implementing the local database containg only the minimum information for the process. Different relay parameters and output formats of the setting results can be easily incorporated owing to the rule-based structure. Graphics-based output helps understanding of the process and enhances the practical power.

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