• Title/Summary/Keyword: controlled blast

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A Study on the Physical Properties of Slag-based Glass-Ceramics (Slag를 위주로 한 Glass-Ceramics 의 물리적 성질에 관한 연구)

  • 장승현;정형진
    • Journal of the Korean Ceramic Society
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    • v.17 no.1
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    • pp.27-34
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    • 1980
  • The synthesis of glass-ceramic materials from glasses based on industrial wastes or natural rocks their physical properties were studied. Glasses of composition, CaO14.7∼16.1, MgO7.4∼9.0, Al2O38.3∼19.3, SiO2 48.9∼51.0wt% were prepared from domestic blast furnace slag, serpentine, sea sand and etc. with additions of chromic oxide, and fluoride as nucleating agent. The glasses were subjected to controlled heat treatments and yielded fine microstructure of glass-ceramics which were composed of monocrystalline phase of aluminous diopside. X-ray diffraction techniques were adopted to identify the crystalline phases and to determine the degree of crystallization quantitatively. Density, coefficient of thermal expansion, young's modulus, microhardness and modulus of rupture were measured and the resulting properties were discussed in terms of the heat-treatment conditions, the degree of crystallization, species of crystaline phase, the microstructures formed in glass-cramics and the chemical compositions of mother glasses.

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A Study on Erosion Properties of Sialon Ceramics by Hot-Pressing (열간가압소결법으로 제조된 Sialon세라믹스의 고온 Erosion 특성에 관한 연구)

  • 여인웅;임대순;박동수
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1996.04b
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    • pp.20-24
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    • 1996
  • Three kinds of the sialon ceramics with and without TiN additions were hot pressed. Hardness and fracture toughness were measured with prepared specimens to study the effect of additives on the mechanical properties. A gas blast type erosion tester was employed to examine erosion behavior of the specimens up to 600 $^{\circ}$C. Erosion tests showed an increase of erosion rate up to 400 $^{\circ}$C and a gradual decrease of erosion rate 500 $^{\circ}$C for all kinds of sialon. The results also showed that erosion rates of the sialons were controlled better by microstructure factors than by mechanical properties such as fracture toughness.

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A Study on Erosion Properties of Hot Pressed Sialon Ceramics (열간가압소결법으로 제조된 Sialon세라믹스의 Erosion특성에 관한 연구)

  • 여인웅;임대순;박동수
    • Tribology and Lubricants
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    • v.13 no.3
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    • pp.42-47
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    • 1997
  • Three kinds of the sialon ceramics with and without TiN additions were prepared by hot pressing to investigate the effect of microstructure on erosion behaviors. Hardness and fracture toughness were measured with prepared specimens to study the effect of additives on the mechanical properties. A gas blast type erosion tester was employed to examine erosion behavior of the specimens up to $600^{\circ}C$. Erosion tests showed an increase of erosion rate up to 40$0^{\circ}C$ and a gradual decrease of erosion rate up to 50$0^{\circ}C$ for all kinds of sialon. The results also showed that erosion rates of the sialons were controlled better by microstructural factors than by mechanical properties including fracture toughness and hardness.

In vivo Antifungal Activity Against Various Plant Pathogenic Fungi of Curcuminoids Isolated from the Rhizomes of Curcuma longa

  • Cho, Jun-Young;Choi, Gyung-Ja;Lee, Seon-Woo;Lim, He-Kyoung;Jang, Kyung-Soo;Lim, Chi-Hwan;Cho, Kwang-Yun;Kim, Jin-Cheol
    • The Plant Pathology Journal
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    • v.22 no.1
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    • pp.94-96
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    • 2006
  • In a search for plant extracts with potent in vivo antifungal activity against various plant pathogenic fungi, the methanol extract of the Curcuma longa rhizomes effectively controlled the development of rice blast catised by Magnaporthe grisea and tomato late blight caused by Phytophthora infestans. Three curcuminoids such as curcumin, demethoxycurcumin, and bisdemethoxycurcumin were purified from the methanol extract of C. longa rhizomes as antifungal principles. Among the three curcuminoids, demethoxycurcumin was the most active to both rice blast and tomato late blight, followed in order by curcumin and bisdemethoxycurcumin. However, they all exhibited no or little in vivo antifungal activity against other fungal pathogens causing rice sheath blight (Corticium sasaki), tomato gray mold (Botrytis cinerea), wheat leaf rust (Puccinia recondita), or barley powdery mildew (Blumeria graminis f. sp. hordel).

Evaluation of Curing Conditions for Improving the Various Properties of Aerated Concrete Incorporating Slag Powder (슬래그 혼입 기포콘크리트의 성능향상을 위한 양생조건의 평가)

  • Park, Jong-Beom;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.527-532
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    • 2018
  • The objective of the present study is to evaluate a practical approach for enhancing the compressive strength and minimizing deforming of aerated concrete. Test results measured in the aerated concrete mixes that were produced using 40% ground granulated blast-furnace slag (GGBS) as a replacement of cement and cured under different conditions (i.e., high temperatures of $40^{\circ}C$ and $60^{\circ}C$ for 10 hrs or 15 hrs) were compared with those obtained from the specimens cured under room temperature. No deforming was observed in the mixes with 40% GGBS. The compressive strength of the prepared aerated concrete cured under high temperature was higher than that of the concrete cured at room temperature, even at the lower ranges of the apparent dry density. However, the curing time is needed to be controlled as not exceeding 10 hrs at the temperature of $60^{\circ}C$ to prevent the decrease in the compressive strength due to foam mergences.

A Study on Movement of the Free Face During Bench Blasting (전방 자유면의 암반 이동에 관한 연구)

  • Lee, Ki-Keun;Kim, Gab-Soo;Yang, Kuk-Jung;Kang, Dae-Woo;Hur, Won-Ho
    • Explosives and Blasting
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    • v.30 no.2
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    • pp.29-42
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    • 2012
  • Variables influencing the free face movement due to rock blasting include the physical and mechanical properties, in particular the discontinuity characteristics, explosive type, charge weight, burden, blast-hole spacing, delay time between blast-holes or rows, stemming conditions. These variables also affects the blast vibration, air blast and size of fragmentation. For the design of surface blasting, the priority is given to the safety of nearby buildings. Therefore, blast vibration has to be controlled by analyzing the free face movement at the surface blasting sites and also blasting operation needs to be optimized to improve the fragmentation size. High-speed digital image analysis enables the analyses of the initial movement of free face of rock, stemming optimality, fragment trajectory, face movement direction and velocity as well as the optimal detonator initiation system. Even though The high-speed image analysis technique has been widely used in foreign countries, its applications can hardly be found in Korea. This thesis aims at carrying out a fundamental study for optimizing the blast design and evaluation using the high-speed digital image analysis. A series of experimentation were performed at two large surface blasting sites with the rock type of shale and granite, respectively. Emulsion and ANFO were the explosives used for the study. Based on the digital images analysis, displacement and velocity of the free face were scrutinized along with the analysis fragment size distribution. In addition, AUTODYN, 2-D FEM model, was applied to simulate detonation pressure, detonation velocity, response time for the initiation of the free face movement and face movement shape. The result show that regardless of the rock type, due to the displacement and the movement velocity have the maximum near the center of charged section the free face becomes curved like a bow. Compared with ANFO, the cases with Emulsion result in larger detonation pressure and velocity and faster reaction for the displacement initiation.

Antifungal activities of coumarins isolated from Angelica gigas and Angelica dahurica against Plant pathogenic fungi (당귀와 백지로부터 분리한 Coumarin계 물질들의 식물병원균에 대한 항균활성)

  • Ryu, Shi-Yong;Kim, Young-Sup;Kim, Heung-Tae;Kim, Seong-Ki;Choi, Gyung-Ja;Kim, Jeoung-Seob;Lee, Seon-Woo;Heor, Jung-Hee;Cho, Kwang-Yun;Kim, Jin-Cheol
    • The Korean Journal of Pesticide Science
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    • v.5 no.3
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    • pp.26-35
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    • 2001
  • In order to search potent antifungal substances from domestic plants, 40 plants cultivated in Korea were collected. After extracting with methanol (MeOH) and concentrating to dryness, the MeOH extracts were screened for in vivo antifungal activity against six plant diseases at a concentration of $2000{\mu}g/mL$. Fourteen extracts showed disease-controlling activity more than 90% against at least one of the 6 plant diseases tested; eight, seven, and three extracts controlled more than 90% the development of rice blast, tomato late blight, and wheat leaf rust, respectively. However, none of the extracts exhibited in vivo antifungal activity more than 90% against rice sheath blight, tomato gray mold, and barley powdery mildew. From the MeOH extracts of Angelica gigas and A. dahurica showing potent controlling activity against rice blast, 1 and 2 antifungal substances, respectively, were isolated by solvent partitioning and column chromatography. The three compounds were identified to be coumarins, namely, decursin, imperatorin, and isoimperatorin, by mass spectrometry and NMR spectroscopy. They were examined for in vitro and in vivo antifungal activities together with umbelliferone (7-bydroxycournarin) and scopoletin (6-methoxy-7-hydroxycoumarin) containing a free hydroxyl group at position 7 to investigate the structure-activity relationship. In vitro, most of 50% growth inhibitory concentrations ($IC_{50}$) were over $200{\mu}g/mL$, indicating that they have relatively weak antifungal activity. The antifungal activity of decursin and scopoletin, containing cyclic alkoxy groups instead of free hydroxyl group at position 7, was stronger than umbelliferone and scopoletin. Especially, decursin and imperatorin showed potent antifungal activities against Pythium ultimum and Magnaporthe grisea, respectively, with $IC_{50}$ values less than $25{\mu}g/mL$. In vivo, decursin and imperatorin showed potent antifungal activity against rice blast, whereas other coumarins hardly controlled the development of 6 plant diseases tested. These results suggest that the antifungal activity of 7-hydroxycoumarin derivative is substantially increased when the hydroxyl group at position 7 is protected by a stable cyclic alkoxy grouping.

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Antifungal activities of Several Plant Extracts against Wheat Leaf Rust (몇 가지 식물 추출물의 밀 녹병 방제 특성)

  • Choi, Gyung-Ja;Kim, Jin-Cheol;Jang, Kyung-Soo;Lee, Seon-Woo;Kim, Jin-Suk;Cho, Kwang-Yun
    • The Korean Journal of Pesticide Science
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    • v.6 no.2
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    • pp.87-95
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    • 2002
  • Disease control activities of the methanol extracts from 27 plant species were investigated against six plant diseases such as rice blast, rice sheath blight, tomato gray mold, tomato late blight, wheat leaf rust and barley powdery mildew. The extracts of Humulus japonicus, Hosta longipes, Liriope platyphylla, and Astragalus membranaceus exhibited a great in vivo control activity against rice blast. Similarly, the extracts of Commelina communis and A. membranaceus were highly active on tomato gray mold and barley powdery mildew, respectively. The extracts of H. longipes, L. platyphylla, Solanum nigrum and A. membranaceus showed especially high disease control activity against wheat leaf rust, and then were selected for further tests such as protective, curative, systemic, and lasting activity against wheat leaf rust. The extracts of L. platyphylla and S. nigrum were strong protectant, and that of A. membranaceus possessed both a preventive activity and a curative activity. Systemic disease control by the selected four plant extracts was investigated by examing translaminar activity from leaf-under-surface to leaf-upper-surface and systemic activity by leaf-to-Ieaf movement. All extracts strongly controlled wheat leaf rust by translaminar movement, but hardly controlled the disease by leaf-to-leaf movement. Good lasting activity was also observed against wheat leaf rust from all of the tested extracts. Especially, disease control experiments on wheat seedlings sprayed with the extracts of S. nigrum or H. longipes 7 days prior to inoculation represented control value over 95%. These results suggest that methanol extracts of H. longipes, L. platyphylla, S. nigrum, and A. membranaceus, especially S. nigrum, would potently control wheat leaf rust caused by Puccinia recondita in the fields.

Characteristics of Autogenous Shrinkage for Concrete Containing Blast-Furnace Slag (고로슬래그를 함유한 콘크리트의 자기수축 특성)

  • Lee Kwang-Myong;Kwon Ki-Heon;Lee Hoi-Keun;Lee Seung-Hoon;Kim Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.16 no.5 s.83
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    • pp.621-626
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    • 2004
  • The use of blast-furnace slag (BFS) in making not only normal concrete but also high-performance concrete has several advantages with respect to workability, long-term strength and durability. However, slag concrete tends to show more shrinkage than normal concrete, especially autogenous shrinkage. High autogenous shrinkage would result in severe cracking if they are not controlled properly. Therefore, in order to minimize the shrinkage stress and to ensure the service life of concrete structures, the autogenous shrinkage behavior of concrete containing BFS should be understood. In this study, small prisms made of concrete with water-binder (cement+BFS) ratio (W/B) ranging from 0.27 to 0.42 and BFS replacement level of $0\%$, $30\%$, and $50\%$, were prepared to measure the autogenous shrinkage. Based on the test results, thereafter, material constants in autogenous shrinkage prediction model were determined. In particular, an effective autogenous shrinkage defined as the shrinkage that contributes to the stress development was introduced. Moreover, an estimation formula of the 28-day effective autogenous shrinkage was proposed by considering various W/B's. Test results showed that autogenous shrinkage increased with replacement level of BFS at the same W/B. Interestingly, the increase of autogenous shrinkage is dependent on the W/B at the same content of BFS; the lower W/B, the smaller increasing rate. In concluding, it is necessary to use the combination of other mineral admixtures such as shrinkage reducing admixture or to perform sufficient moisture curing on the construction site in order to reduce the autogenous shrinkage of BFS concrete.

Carbohydrate, Amino Acid and Phenolic Contents of Rice Leaves in Relation to Adult-Plant Resistance to Leaf Blast (벼 잎의 탄수화물, 아미노산, 페놀화합물 함량과 잎 도열병에 대한 성체식물 저항성과의 관계)

  • Hwang Byung Kook;Kim Ki Deok
    • Korean Journal Plant Pathology
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    • v.3 no.2
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    • pp.93-99
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    • 1987
  • Six rice cultivars showing various types of resistance or susceptibility to Pyricularia oryzae in the field were used to study the relationship between susceptibility and contents of carbohydrates, amino acids and phenolics at different plant maturities and leaf ages under controlled environmental conditions. No consistent differences between the susceptible cultivars and adult-plant-resistant cultivars were found in terms of the contents of individual carbohydrates, total amino acids and phenolics in rice leaves throughout the plant development. Only the adult-plant-resistant cultivar Dobong had lower contents of inositol throughout the plant development than the other cultivars. The amounts of sucrose, inositol, glucose, and fructose increased in all tested cultivars at eight leaf stage than those at five leaf stage, but slightly decreased at twelve leaf stage. In contrast, total amino acids and phenolics gradually decreased during plant development. With increasing age of rice leaves, the amounts of total soluble amino acids and phenolics gradually increased in healthy fifth leaf tissues, although there were no significant differences between the cultivars. In particular, a high level of phenolics existed in old fifth leaves of the cultivar Dobong. These results suggest that increased resistance to blast of matured rice plants and old leaves may be the two different phenomina derived from the physiological changes occurring during plant development and leaf senescence, probably functioning differently in P. oryzae development.

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