• The Journal of the Petrological Society of Korea
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• v.18 no.1
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• pp.1-17
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• 2009

This article carried studies of the petrographical and petrochemical characteristics on the Cretaceous volcanic rocks in the area of Janggun peak and Gyemyeong peak which is located at the northeastern area of Mt. Geumjeong, Busan. The areas are composed of andesitic rock, sedimentary rock, rhyolitic rock, and intrusive hornblende, biotite granites, in ascending order. According to petrochemistry, the major elements show the calc-alkaline rock series ranged medium-K to high-K. With increasing $SiO_2$, $Al_{2}O_{3}$, $Fe_{2}O_{3}$, $TiO_2$ CaO, MgO MnO and $P_{2}O_{5}$ are decreased and $K_{2}O$ and $Na_{2}O$ are increased in the volcanic rocks. The trace element compositions show high LILE/HFSE ratios and negative anomaly of Nb, and REE patterns show enrichments in LREE and (-) anomaly values increase of Eu from the basaltic andesite to andesite facies, therefore the volcanic rocks have typical characteristics of continental margin arc calc-alkaline volcanic rocks, produced in the subduction environment. The volcanic rock show nearly the same patterns in spider and REE diagram. Fractional crystallization of the basaltic magma would have produced the calc-alkaline andesitic magma. And the rhyolitic magma seems to have been evolved from the basaltic andesitic magma with fractional crystallization of plagioclase, pyroxene, hornblende, biotite.

• Journal of the Korean earth science society
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• v.29 no.7
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• pp.539-550
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• 2008

In this paper, we investigate the geochemical and isotope properties of the Jeongeup foliated granite (hereafter, the JFG) in the Jeongeup area, aiming at establishing the movement age of the Honam shear zone by U-Pb sphene geochronology. In the AMF diagram, the JFG corresponds to the calc alkalic rock series, and belongs to the magnesia region in the diagram of silica versus $FeO^{total}/(FeO^{total}+MgO)$. Additionally, in the Rb-Ba-Sr diagram, it is classified as granodiorite and anomalous granite with distinctive negative Eu-anomaly in the REE patterns. According to the silica and trace element contents, the JFG falls on the type VAG+syn-COLG, which implies that this was formed under the circumstance of compressional continental margin or volcanic arc. $^{143}Nd/^{144}Nd$ isotope ratios range from 0.511495 to 0.511783 and $T_{DM}$ are calculated to be about $1.68{\sim}2.36Ga$. U-Pb sphene ages of the JFG are $172.9{\pm}1.7Ma$ and $170.7{\pm}2.8Ma$, based on $^{238}U-^{206}Pb$ and $^{235}U-^{207}Pb$ ages, respectively. Presumably, the dextral ductile shearing in the Jeongeup area has occurred after 173 Ma.

• Geosciences Journal
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• v.23 no.1
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• pp.1-20
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• 2019

We present data from the Mesozoic Keumkang, Palbong, and Baekhwa granites in Garorim Bay, in the southwestern part of the Gyeonggi massif, South Korea. Using major and trace element concentrations, Sr-Nd-Pb isotopic compositions, and sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb ages, we aim to constrain the petrogenesis of the granites and explain their origin within a broader regional geological context. SHRIMP U-Pb zircon ages of $232.8{\pm}3.2$, $175.9{\pm}1.2$, and $176.8{\pm}9.8$ Ma were obtained from the Keumkang, Palbong and Baekhwa granites, respectively. The Late Triassic Keumkang granites belong to the shoshonite series and show an overall enrichment in large ion lithophile elements (LILE), a depletion in high field strength elements (HFSE) relative to primitive mantle, compared with neighboring elements in the primitive mantle-normalized incompatible trace element diagram with notable high Ba and Sr contents, and negligible Eu anomalies. The Keumkang granites are typified by highly radiogenic Sr and unradiogenic Nd and Pb isotopic compositions: $(^{87}Sr/^{86}Sr)_i=0.70931-0.70959$, $(^{143}Nd/^{144}Nd)_i=0.511472-0.511484$ [$({\varepsilon}_{Nd})_i=-17.0$ to -16.7], and $(^{206}Pb/^{204}Pb)=17.26-17.27$. The Middle Jurassic Palbong and Baekhwa granites belong to the medium- to high-K calc-alkaline series, and show LILE enrichment and HFSE depletion similar to the Keumkang granites, but exhibit significant negative anomalies in Ba, Sr, and Eu. Furthermore, they have elevated Y and Yb contents at any given $SiO_2$ content compared with other Jurassic granitoids from the Gyeonggi massif. The Palbong and Baekhwa granites have slightly less radiogenic Sr and more radiogenic Nd and Pb isotopic compositions [$(^{87}Sr/^{86}Sr)_i=0.70396-0.70908$, $(^{143}Nd/^{144}Nd)_i=0.511622-0.511660$, $({\varepsilon}_{Nd})_i=-15.4$ to -14.7, $(^{206}Pb/^{204}Pb)=17.56-17.76$] relative to the Keumkang granites. The Keumkang granites are considered to have formed in a post-collisional environment following the Permo-Triassic Songrim orogeny that records continent-continent collision between the North and South China blocks, and may have formed by fractional crystallization of metasomatized lithospheric mantle-derived mafic melts. The Palbong and Baekhwa granites may have been produced from a gabbroic assemblage at pressures of less than ~15 kbar, associated with subduction of the paleo-Pacific (Izanagi) plate at the Eurasian continental margin. Elevated ${\varepsilon}_{Nd}(t)$ values in the granitoids from the southwestern part of the Gyeonggi massif relative to those of the central and northern parts, together with the comparatively shallow depth of origin, imply the presence of an exotic block in the Korean lithosphere.

• Economic and Environmental Geology
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• v.52 no.5
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• pp.367-379
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• 2019

Pyeongan Supergroup (PS) in the Taebaeksan basin preserves key geological evidences to understand the tectonometamorphic evolution of the Songrim orogeny that affected the formation of the Korean Peninsula during the late Paleozoic to early Mesozoic. The aims of this paper therefore are to investigate the characteristics of the Songrim orogeny based on the previous results of metamorphism and deformations of the PS, and then to review geological significance and research necessity of the PS. Age distributions and Th/U ratio of detrital zircon in the PS indicate that sedimentary environment of the Taebaeksan basin during the late Paleozoic was arc-related foreland basin and retro-arc foreland basin at the active continental margin. In addition, the main magmatic activities occurred in the early Pennsylvanian and Middle Permian, thus sedimentation and magmatic activities occurred simultaneously. The PS was affected by lower temperature-medium pressure (M1) and medium temperature and pressure (M2) regional metamorphism during the Songrim orogeny. During M1, slate and phyllite containing chloritoid, andalusite, kyanite porphyroblasts intensively deformed by E-W bulk crustal shortening combined with folding and shearing. And garnet and staurolite porphyroblasts were formed during the N-S bulk crustal shortening accompained by M2. Such regional metamorphism of the PS is interpreted to occur in an area where high strain zone is localized during ca. 220-270 Ma. In order to elucidate the evolution of the Taebaeksan basin and tectonic features of the Songrim orogeny, it is expected that the study will be carried out such as the regional distribution of metamorphic zones developed in the PS, characteristics and timing of deformations, and late Paleozoic paleo-geography of the Taebaeksan basin.

• Economic and Environmental Geology
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• v.52 no.3
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• pp.213-221
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• 2019

The Wugang banded iron formation (BIF) is located within the Taihua complex at the southern margin of the North China Craton (NCC). In this study, we analyzed major elements and rare-earth elements in iron ores from the Wugang BIF, to study the type of BIFs and their formation mechanism in combination with previously-published data from the literature. We found that the iron ores from the Wugang BIF display two types of banding textures, which can be described as weak banding or no banding. The samples are composed of coarse-grained magnetite, quartz, pyroxene, and amphibole. Based on our geochemical results, mixing of a hydrothermal fluid with sea water led to the precipitation of the Wugang BIF, and there is evidence of crustal contamination. These results, combined with previous literature data, almost all of the iron ores lack Ce anomalies, though some samples show negative Ce anomalies. Our results indicate that the Wugang BIF was formed in a dominantly reducing environment, although the surfaces were relatively oxidized. Geochemical evidence suggests that the Wugang BIF iron ores were formed in a near-shore continental-shelf environment or in a back-arc basin. The BIF is known as interbedded with migmatite, amphibole gneiss, minor quartz and marble, which indicating lack of volcanic materials input. This study, combined with previous results on geochemical interpretation of related wall rock of Wugang BIF, demonstrated that Wugang BIF belongs to Superior-type BIF.

• Economic and Environmental Geology
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• v.56 no.6
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• pp.799-816
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• 2023

Mineralogical and geochemical studies of shales within the Lower Anambra Basin was conducted to unravel the depositional environment, provenance, maturity, paleo-weathering conditions, and tectonic settings. Mineralogical studies conducted using X-ray diffraction analysis revealed that the samples were composed of kaolinite, montmorillonite, chlorite, and illite. KaolinIite is the dominant mineral, constituting approximately 41.5% of the bulk composition, whereas the non-clay minerals are quartz, ilmenite, and sillimanite. Geochemical analysis showed a predominance of SiO₂, Al₂O₃, and Fe₂O₃ contents of the shale samples with mean values of 52.29%, 14.09%, and 6.15% for Imo Shale (IS); 52.31%, 16.70%, and 7.39% for Mamu Shale (MS); 43.21%, 21.33%, and 10.36% for Enugu Shale (ES); 53.35%, 15.64%, and 7.17% for Nkporo Shale (NS); and 51.24%, 17.25%, and 7.78% for Agwu Shale (AS). However, the shales were depleted in Na₂O, MgO, K₂O, MnO, TiO₂, CaO, and P₂O₅. The trace element ratios of Ni/Co and Cu/Zn of the shale suggest an oxic depositional environment. The average SiO₂ vs. Al₂O₃ ratio of the shales indicated textural maturity. Compared to the PAAS standard, the shales plot below the PAAS value of 0.85, suggesting a high degree of maturity and intensive chemical weathering, further confirmed on a CIA vs. PIA plot. On log (K₂O/Na₂O) against SiO₂ and tectonic setting discriminant function diagrams, the shales plot mostly in the field of passive continental margin tectonic setting. The discriminant function diagrams as well as Al₂O₃/TiO₂ ratio of the shales showed that they were derived from a mixed source (mafic and intermediate igneous rocks).

• Economic and Environmental Geology
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• v.48 no.4
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• pp.301-312
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• 2015

A commercial gas field was found in the southwestern continental shelf of the Ulleung Basin, East Sea in the late 1990s. To develop additional gas field, an exploration well was drilled through the coarse infill of submarine canyon near the gas field, but it was uneconomic to develop hydrocarbons. Using newly acquired deep seismic reflection and previous well data, we have identified additional geological structure which has hydrocarbon potentials below submarine canyons in the southwestern margin of the basin. Based on the interpretation of the deep seismic reflection and well data, the sequences of the study area can be classified into the syn-rift megasequence(MS1), post-rift megasequence(MS2), syn-compressional megasequence(MS3), and post-compressional megasequence(MS4) in relation to the tectonic events. MS1, deposited simultaneously with the basin formation before the middle Miocene, is characterized by chaotic seismic facies with low- to moderate-amplitude and low frequency reflections. MS2 comprises laterally continuous, low- to moderate-amplitude reflections, showing progradational stacking patterns due to high rates of sediment supply during basin expansion in the middle Miocene. MS3 is mainly composed of continuous reflections with high amplitude and moderate- to high-frequency which are interpreted as coarse-grained sediments. The coarse-grained sediments of MS3 sequence is widely truncated by several submarine canyons which filled with fine-grained sediment of MS4 to form a stratigraphic trap of hydrocarbon. Therefore, the reservoir and seal of the hydrocarbon trap in the study area are coarse-grained sediment of MS3 and submarine canyon filled with fine-grained sediment of MS4, respectively. A flat-spot seismic anomaly, which may indicate the presence of hydrocarbon, is observed within the stratigraphic trap.

• Economic and Environmental Geology
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• v.41 no.3
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• pp.299-314
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• 2008

The NE-trending Honam shear zone is a broad, dextral strike-slip fault zone between the southern margin of the Okcheon Belt and the Precambrian Yeongnam Massif in South Korea and is parallel to the trend of Sinian deformation that is conspicuous in Far East Asia. In this paper, we report geochemical and isotopic(Sr and Nd) data of mylonitic quartz-muscovite Precambrian gneisses and surrounding foliated hornblende-biotite granitoids near the Myeongho area in the Yecheon Shear Zone, a representative segment of the Honam Shear Zone. Foliated hornblende-biotite granitoids commonly plot in the granodiorite field($SiO_2=61.9-67.1\;wt%$ and $Na_2O+K_2O=5.21-6.99\;wt%$) on $SiO_2$ vs. $Na_2O+K_2O$ discrimination diagram, whereas quartz-muscovite Precambrian orthogneisses plot in the granite field. The foliated hornblende-biotite granitoids are mostly calcic and calc-alkalic and are dominantly magnesian in a modified alkali-lime index(MALI) and Fe# [$=FeO_{total}(FeO_{total}+MgO)$] versus $SiO_2$ diagrams, which correspond with geochemical characteristics of Cordilleran Mesozoic batholiths. The foliated hornblende-biotite granitoids have molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 0.89 to 1.10 and are metaluminous to weakly peraluminous, indicating I type. In contrast, Paleoproterozoic orthogneisses have peraluminous compositions, with molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 1.11 to 1.22. On trace element spider diagrams normalized to the primitive mantle, the large ion lithophile element(LILE) enrichments(Rb, Ba, Th and U) and negative Ta-Nb-P-Ti anomalies of foliated hornblende-biotite granitoids and mylonitized quartz-muscovite gneisses in the Yecheon Shear Zone are features common to subduction-related granitoids and are also found in granitoids from a crustal source derived from the arc crust of active continental margin. ${\varepsilon}_{Nd}(T)$ and initial Sr-ratio ratios of foliated hornblende-biotite granitoids with suggest the involvement of upper crust-derived melts in granitoid petrogenesis. Foliated hornblende-biotite granitoids in the study area, together with the Yeongju Batholith, show not changing contents of specific elements(Ti, P, Zr, V and Y) from shear zone to the area near the shear zone. These results suggest that no volume changes and geochemical alterations in fluid-rich foliated hornblende-biotite granitoids may occur during deformation, which mass transfer by fluid flow into the shear zone is equal to the mass transfer out of the shear zone.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.5 no.2
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• pp.95-104
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• 2000

Depths to four seismic sequence boundaries and the thickness of each sequence were estimated and mapped based on multi-channel seismic data in the Ulleung Basin. These depth-structure and isopach maps were incorporated into the interpretation of gravity and magnetic anomaly maps. The sediment thickness ranges from 3,000 m to 4,000 m in the central basin, while it reaches 6,000 m locally along the southwestern, western, and southeastern margins. The acoustic basement forms a northeast-southwest elongated depression deeper than 5000 m, and locally deepens up to 7,500 m in the southwestern and western margins. Low gravity anomalies along the western and southern margins are associated with basement depressions with thick sediment as well as the transitional crust between the continental and oceanic crusts. Higher gravity anomalies, dominant in the central Ulleung basin, broaden from southwest toward northeast, are likely due to the shallow mantle and a dense crust. A pair of magnetic elongations in the southeastern and northwestern margins appear to separate the central Ulleung basin from its margin. These magnetic elongations are largely dominated by intrusive or extrusive volcanics which occurred along the rifted margin of the Ulleung basin formed during the basin opening. The crust in the central Ulleung Basin, surrounded by the magnetic elongations, is possibly oceanic as inferred from the seismic velocity. The oceanic crust can be mapped in the central zone where it widens to 120 km from the southwest toward northeast. Bending of the crustal boundary in the southern part of the Ulleung Basin suggests that the Ulleung Basin has been deformed by a collision of the Phillipine plate into the Japan arc.

• The Journal of the Petrological Society of Korea
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• v.6 no.1
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• pp.19-33
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• 1997

This study reports the results about the petrography and geochemical characteristics of 10 representative volacanic rocks. The Cretaceous volcanic rocks distributed in the vicinity of the Kageo island composed of andesitic rocks, dacitic welded tuff, and rhyolitic rocks in ascending order. Sedimentary rock is the basement in the study area covered with volcanic rocks. Andesitic rocks composed of pyroclastic volcanic breccia, lithic lapilli tuff and cryptocrystallin lava-flow. Most dacitic rocks are lapilli ash-flow welded tuff. Rhyolitic rocks consists of rhyolite tuff and rhyolite lava flow. Rhyolite tuff are lithic crystal ash-flow tuff and crystal vitric ash-flow tuff with somewhat accidental fragments of andesitic rocks, but dacitic rocks. The variation of major and trace element of the volcanic rocks show that contents of $Al_2O_3$, FeO, CaO, MgO, $TiO_2$ decrease with increasing of $SiO_2$. On the basis of Variation diagrams such as $Al_2O_3$ vs. CaO, Th/Yb vs. Ta/Yb, and $Ce_N/YB_N$ vs. $Ce_N$, these rocks represent mainly differentiation trend of calc-alkaline rock series. On the discriminant diagrams such as Ba/La and La/Th ratio, Rb vs. Y + Nb, the volcanic rocks in study area belongs to high-K Orogenic suites, with abundances of trace element and ternary diagram of K, Na, Ca. According to the tectonic discriminant diagram by Wood, these rocks falls into the diestructructive continental margin. K-Ar ages of whole rocks are from andesite to rhyolite $97.0{\pm}6.8~94.5{\pm}6.6,\68.9{\pm}4.8,\61.5{\pm}4.9~60.7{\pm}4.2$ Ma, repectively. Volcanic rocks in study area show well correlation to the Yucheon Group in terms of rock age dating and geochemcial data, and derived from andesitic calc-alkaline magma that undergone low pressure fractional crystallization dominated plagioclase at <30km.