• Title/Summary/Keyword: contamination materials

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Microscopical and chemical surface characterization of CAD/CAM zircona abutments after different cleaning procedures. A qualitative analysis

  • Gehrke, Peter;Tabellion, Astrid;Fischer, Carsten
    • The Journal of Advanced Prosthodontics
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    • v.7 no.2
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    • pp.151-159
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    • 2015
  • PURPOSE. To describe and characterize the surface topography and cleanliness of CAD/CAM manufactured zirconia abutments after steaming and ultrasonic cleaning. MATERIALS AND METHODS. A total of 12 ceramic CAD/CAM implant abutments of various manufacturers were produced and randomly divided into two groups of six samples each (control and test group). Four two-piece hybrid abutments and two one-piece abutments made of zirconium-dioxide were assessed per each group. In the control group, cleaning by steam was performed. The test group underwent an ultrasonic cleaning procedure with acetone, ethyl alcohol and antibacterial solution. Groups were subjected to scanning electron microscope (SEM) analysis and Energy-dispersive X-ray spectroscopy (EDX) to verify and characterize contaminant chemical characterization non- quantitatively. RESULTS. All zirconia CAD/CAM abutments in the present study displayed production-induced wear particles, debris as well as organic and inorganic contaminants. The abutments of the test group showed reduction of surface contamination after undergoing an ultrasonic cleaning procedure. However, an absolute removal of pollutants could not be achieved. CONCLUSION. The presence of debris on the transmucosal surface of CAD/CAM zirconia abutments of various manufacturers was confirmed. Within the limits of the study design, the results suggest that a defined ultrasonic cleaning process can be advantageously employed to reduce such debris, thus, supposedly enhancing soft tissue healing. Although the adverse long-term influence of abutment contamination on the biological stability of peri-implant tissues has been evidenced, a standardized and validated polishing and cleaning protocol still has to be implemented.

A Study on the Planning Methods for Pollution Prevention of Building Exterior - Focused On the Public Borough Offices in Seoul - (건축물 외관의 오염방지를 위한 계획적 방안 연구 - 서울시 구청을 대상으로 -)

  • Choi, Myung-Hwan;Choi, Moon-Gyu
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.36 no.4
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    • pp.71-81
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    • 2020
  • The purpose of this study is to propose the planning methods for pollution prevention in the initial design stage by identifying the pollution phenomena on the exterior of the building. It is important to catch the problem early on because exterior troubles begin with an initial design defect and causes rapid aging. The scope of this study is seoul public borough offices that should be sustainable for long as landmark located at the center of the district. Field survey was conducted three times in six months. Twenty-six borough offices were diagnosed with three levels of contamination through visual inspection and the contaminated locations, types, materials, and characteristics were checked. Fourteen common contaminated locations were identified in the first and intensively rechecked in the second. Five locations vulnerable to contamination were designated and the contamination and cleanliness situations were checked by location in the third. As a result, main polluted types and locations are sloping wall, upper wall, protruded wall, canopy, and wall under window. The key to avoiding these pollution problems is to minimize the horizontal plane on which dust can be deposited. In other words, it can be considered variously by shape and location, such as the slope of the horizontal plane, the floating of the surface, the installation of the roof surface, and the vertical louvers. And throating plans and material plans suitable for each location are presented. Various methods of the shape and location, material are expected to use as useful basic data for preventing pollutions during the initial design stage.

Microbiological cleaning and disinfection efficacy of a three-stage ultrasonic processing protocol for CAD-CAM implant abutments

  • Gehrke, Peter;Riebe, Oliver;Fischer, Carsten;Weinhold, Octavio;Dhom, Gunter;Sader, Robert;Weigl, Paul
    • The Journal of Advanced Prosthodontics
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    • v.14 no.5
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    • pp.273-284
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    • 2022
  • PURPOSE. Computer-aided design and manufacturing (CAD-CAM) of implant abutments has been shown to result in surface contamination from site-specific milling and fabrication processes. If not removed, these contaminants can have a potentially adverse effect and may trigger inflammatory responses of the peri-implant tissues. The aim of the present study was to evaluate the bacterial disinfection and cleaning efficacy of ultrasonic reprocessing in approved disinfectants to reduce the microbial load of CAD-CAM abutments. MATERIALS AND METHODS. Four different types of custom implant abutments (total N = 32) with eight specimens in each test group (type I to IV) were CAD-CAM manufactured. In two separate contamination experiments, specimens were contaminated with heparinized sheep blood alone and with heparinized sheep blood and the test bacterium Enterococcus faecium. Abutments in the test group were processed according to a three-stage ultrasonic protocol and assessed qualitatively and quantitatively by determination of residual protein. Ultrasonicated specimens contaminated with sheep blood and E. faecium were additionally eluted and the dilutions were incubated on agar plates for seven days. The determined bacterial counts were expressed as colony-forming units (CFU). RESULTS. Ultrasonic reprocessing resulted in a substantial decrease in residual bacterial protein to less than 80 ㎍ and a reduction in microbiota of more than 7 log levels of CFU for all abutment types, exceeding the effect required for disinfection. CONCLUSION. A three-stage ultrasonic cleaning and disinfection protocol results in effective bacterial decontamination. The procedure is reproducible and complies with the standardized reprocessing and disinfection specifications for one- or two-piece CAD-CAM implant abutments.

VOCs Emission Characteristics of Coating Materials for Wood Finishing (목재용 마감도료의 휘발성유기화합물 방출특성)

  • Park, Sang-Bum;Lee, Min;Lee, Sang-Min;Kang, Yeong-Seok
    • Journal of the Korea Furniture Society
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    • v.26 no.1
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    • pp.22-30
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    • 2015
  • In order to prevent decay, distortion, bending, twist on wood products such as wooden furnitures, variety of coating materials were developed and used so far. The coating materials for wood finishing can be synthesized by natural resource or petroleum. However, these coating materials can cause contamination of indoor air quality due to emission of volatile organic compounds (VOCs). In this study, commercialized coating materials for wood finishing such as varnish, coat, and stain were evaluated on emission characteristics of VOCs. Among the varnish, eco-friendly products had about 15~46% lower TVOC emission ($1,042{\mu}g/m^2h{\sim}3,257{\mu}g/m^2h$, respectively, than typical product ($7,100{\mu}g/m^2h$). Natural resource based coating material showed lowest TVOC emission level. However, one of natural resource based waterborne stain showed higher TVOC emission level because waterborne stain already contained higher amount of natural VOC. Oil-based stain might not be suitable for indoor use on interior wall and furniture due to exceed amount of TVOC. Based on results, natural resource based coat or waterborne stain are recommenced to use on wood products.

Review of Metal Oxide-based Formaldehyde Gas Sensor to Measure Indoor Air Quality (실내 대기질 진단을 위한 금속산화물 기반 폼알데하이드 가스센서 연구 동향)

  • Kim, Yoon Hwa;Koo, Won-Tae;Jang, Ji-Soo;Kim, Il-Doo
    • Journal of Sensor Science and Technology
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    • v.28 no.6
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    • pp.377-384
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    • 2019
  • People currently spend more than 80% of their time indoors; therefore, the management of indoor air quality has become an important issue. The contamination of indoor air can cause sick house syndrome and various environmental diseases such as atopy and nephropathy. Formaldehyde gas, which is the main contaminant of indoor air, is lethal even with microscopic exposure; however, it is commonly used as an adhesive and waterproofing agent for indoor building materials. Therefore, there is a need for a gas sensor capable of detecting trace amounts of formaldehyde gas. In this review, we summarize recent studies on metal oxide-based semiconductor gas sensors for formaldehyde gas detection, methods to improve the gas-sensing properties of metal oxides of various dimensions, and the effects of catalysts for the detection of parts-per-billion level gases. Through this, we discuss the necessary characteristics of the metal oxidebased semiconductors for gas sensors for the development of next-generation sensors.

Environmentally friendly Remodeling of Interior Space : Implementation of Construction Process (실내공간의 환경친화적 리모델링 시공프로세스의 실행내용에 관한 연구)

  • Kim Yoon-Ho;Pak Hee-Jin
    • Korean Institute of Interior Design Journal
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    • v.14 no.6 s.53
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    • pp.270-279
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    • 2005
  • As remodeling market is growing and peoples' concern on health and well-being is getting high, there is a need to apply environmentally friendly approach to remodeling an interior space. Therefore, the purpose of this study is to provide basic information on environmentally friendly remodeling process focused on the implementation of interior construction process. The method of this study was two-folds. First, previous researches were reviewed to drive general remodeling process, and then content of implementation of environmentally friendly remodeling process were added. Second, semi-structured interview was conducted to eight experts in interior design who were members of KOSID. The results of this study are as follows; (1) Applying environmentally friendly method to remodeling will be essential. Therefore, it is necessary to develop various types of environmentally friendly finish materials and methods and continuing attention should be paid. (2) For broad implementing an environmentally friendly application on remodeling, builders, interior designers, manufacturers, and clients should change their consciousness through education and publicity, (3) The results showed that using environmentally friendly materials was the most primary concern for the designers. However, there is a lack of information about contamination derived from materials when manufacturing and constructing and even wastes. Thus designers should be aware of using environmentally friendly verified materials regarding materials itself and its manufacturing process.

A Study of Damage and Contamination on Silicon by Magnetized Inductively Coupled $\textrm{C}_{4}\textrm{F}_{8}$ Plasma Etching of $\textrm{SiO}_2$ (자화된 유도결합형 $\textrm{C}_{4}\textrm{F}_{8}$ 플라즈마를 이용한 $\textrm{SiO}_2$ 건식 식각시 실리콘 표면에 발생하는 손상 및 오염에 관한 연구)

  • Nam, Uk-Jun;Kim, Hyeon-Su;Yun, Jong-Gu;Yeom, Geun-Yeong
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.825-830
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    • 1998
  • 자화된 유도결합형 C4F8 플라즈마로 SiO2를 건식식각시 실리콘 표면에 발생하는 손상과 오염에 대하여 연구하였다. 오염의 분석을 위해서 XPS, SIMS, TEM을 사용하였으며, 손상정도를 측정하기 위해서 HRTEM과 Schottky-diode 구성을 통한 I-V특성 측정을 사용하였다. 유도 결합형 C4F8 플라스마에 0에서 18Gauss까지의 자장이 가해짐에 따라서 실리콘 표면에 생기는 잔류막의 두께가 SiO2식각속도와 선택비의 증가와 함께 증가하였으며, XPS를 통하여 그 조성이 fluorine-rich에서 carbon-rich 한 상태로 변화함을 알 수 있었다. 자장을 가하지 않는 상태에서는 표면에서 $40\AA$부근까지 고밀도의 손상층이 관찰되었으나, 자장을 가함에 따라서 노출된 손상층의 깊이는 깊어지나 그 밀도는 줄어들음을 HRTEM을 통하여 관찰 할 수 있었다. Schottky-diode를 통한 I-V특성곡선의 분석으로 자장이 증가함에 따라서 전기적인 손상이 감소함을 알 수 있었다.

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Fabrication of Lightweight Aggregates Using Fly Ash from Coal Burning Heat Power Plant (화력발전소 발생 플라이애쉬를 이용한 인공골재 제조)

  • Yoon Su-Jong
    • Journal of Powder Materials
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    • v.13 no.2 s.55
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    • pp.102-107
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    • 2006
  • Recycling industrial wastes such as fly ash from a coal burning heat power plant and shell from an oyster farming were investigated to prevent environment contamination as well as to enhance the value of recycling materials. In this study, the lightweight aggregates and the red bricks were fabricated from fly ashes with other inorganic materials and wastes. The starting materials of the lightweight aggregate were fly ash powder and water glass, and the compacts of these materials were heat treated at $1100^{\circ}C$. The fabricated lightweight aggregates had low bulk density, $0.9-1.2\;g/cm^3$, hence floated on the water and had the strength of 7.0-11.0 MPa and the modulus of 2900-3300 MPa which indicates it has enough strength as the aggregate. Another type of the light weight aggregate was prepared from fly ashes, shell powders and clays. The bulk density, porosity, and compressive strength of these aggregates were $1.19-1.34\;g/cm^3,\;18.3{\sim}56.1%$ and 5-12 MPa, respectively. The addition of a small amount of fly ash powder prevented hydration of the light weight aggregates. The red brick was also fabricated from the fly ash containing materials. It is suitable for the brick facing of a building as it has moderate strength and low water absorption rate.

Synthesis of Tungsten Heavy alloy Nanocomposite Powder by Ultrasonic-milling Process (초음파 밀링 공정을 이용한 텅스텐 중합금 나노복합분말의 제조)

  • Lee, Seung-Chul;Lee, Chang-Woo;Jung, Sung-Soo;Cha, Berm-Ha;Lee, Jai-Sung
    • Journal of Powder Materials
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    • v.14 no.2 s.61
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    • pp.101-107
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    • 2007
  • Ultrasonic-milling of metal oxide nanopowders for the preparation of tungsten heavy alloys was investigated. Milling time was selected as a major process variable. XRD results of metal oxide nanopowders ultrasonic-milled for 50 h and 100 h showed that agglomerate size reduced with increasing milling time and there was no evidence of contamination or change of composition by impurities. It was found that nanocomposite powders reduced at $800^{\circ}C$ in a hydrogen atmosphere showed a chemical composition of 93.1W-4.9Ni-2.0Fe from EDS analysis. Hardness of sintered part using 50 h and 100 h powder samples was 399 Hv and 463 Hv, respectively, which is higher than the that of commercial products (330-340 Hv).

Oil Absorption Effects of Organic Porous Materials (유기 다공성 소재의 흡유 효과)

  • Kang, Young-Goo;Han, Sang-Bum
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.86-91
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    • 2006
  • Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.