• Title/Summary/Keyword: contact oxidation

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A Study on the Wear Characteristics and the Mechanism of KP-4M Steel for Plastic Molding (플라스틱성형용 KP-4M강의 마멸특성 및 이의 기구에 관한 연구)

  • 박흥식;전태옥;김동호
    • Tribology and Lubricants
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    • v.12 no.1
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    • pp.22-28
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    • 1996
  • This study was undertaken to investigate the dry wear characteristics and mechanism of KP-4M steel for plastic molding against SKD 61 hardened by heat treatment. The wear test was carried out under different conditions such as sliding speed, contact pressure, sliding distance, with frictional tester of pin on disc type. The wear loss on variation of sliding speed was little in lower speed range below 0.5 m/sec and in higher speed range above 1.5 m/sec,'but wear loss was high in intermediate speed range. The critical sliding speed, which showed the maximum value of specific wear rate, became lower with increased contact pressure. Increasing the contact pressure, the critical sliding distance Lcr which the wear mechanism changes from severe wear to mild wear was increased due to the decrease of oxidation reaction velocity. Through this study we suggested a model of generation and elimination process of wear debris of KP-4M steel for plastic molding.

The Effect of Oxide Layer Formed on TiN Coated Ball and Steel Disk on Friction Characteristics in Various Sliding Conditions (미끄럼조건에 따라 TiN 코팅볼과 스틸디스크에 형성되는 산화막이 마찰특성에 미치는 영향)

  • 조정우;이영제
    • Tribology and Lubricants
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    • v.17 no.6
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    • pp.459-466
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    • 2001
  • In this study, the effects of oxide layer formed on the contact parts of TiN coated ball and steel disk on friction characteristics in various sliding conditions were investigated. AISI52100 steel ball was used for the substrate of coated ball specimens, which were prepared by depositing TiN coating with 1(m in coating thickness. AISI1045 steel was used for the disk type counter-body. To investigate the effect of oxide layer on the contact parts of two materials, the tests were performed both in air for forming oxide layer on the contact parts and in nitrogen environment to avoid oxidation. From the test results, the frictional characteristic between the two materials was predominated by iron oxide layer that formed on wear tract of counter-body and this layer caused friction transition and high friction. And the adhesive wear occurred from steel disk to TiN coated ball caused the formation of oxide layer on counter parts between the two materials.

Analysis of the Surface Degradation in UV-irradiated High-Temperature Vulcanized Silicone Rubber (자외선 조사된 HTV 실리콘 고무의 표면열화 분석)

  • 연복희;이태호;허창수;이종한
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.411-419
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    • 2000
  • In this paper we have investigated the surface degradation by ultraviolet-irradiation in high-temperature vulcanized silicone rubber. Through the measurement of surface potential decay by corona-charging and of contact angle it is found that the change of surface electrostatic properties and the decrease of contact angle under UV-radiation. For the changes in micro-morphological and chemical structure of the UV-treated silicone rubber we utilized several analytical techniques such as SEM, ATR-FTIR,XPS. From this study it is shown that the chemical reactions(scissoring of side chain(S-$CH_3$) cross-linking and branching) occur on the surface of silicone rubber during the UV-irradiation. Also we obtained the results of the loss of low molecular weight chain by cross-linking and oxidation reaction.

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미끄럼시험시 TiN 코팅볼과 스틸디스크에 형성되는 산화막의 특성과 마찰특성에 미치는 영향

  • 조정우;박동신;임정순;이영제
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.401-405
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    • 2001
  • The effects of oxide layer formed on TiN coated ball and counter-body have been investigated from the frictional point of view during sliding tests. AISI52100 steel ball was used for the substrate of coated specimens. Two types of coated specimens were prepared by depositing TiN coating with 1 and 4$\mu\textrm{m}$ in coating thickness. AISI1045 steel was used for the disk type counter-body. To investigate the effect of oxide layer on the contact parts of two materials, the tests were performed both in ambient for forming oxide layer on the contact parts and in nitrogen environment to avoid oxidation.

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Wear Behaviors of ${Si_3}{N_4}$ under Various Sliding Conditions (미끄럼 환경의 변화에 따른 ${Si_3}{N_4}$의 마멸거동)

  • Lee, Yeong-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.6
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    • pp.1753-1761
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    • 1996
  • The wear behaviors of ${Si_3}{N_4}$ under the different sliding conditions were investigated. The cylinder-on-disc wear tester was used. Using the servo-metor, the sliding speed did ot alternate due to the frictional forces. Threekinds of loads and speeds were selected to watch the variation of the wear rates and the frictional forces. Also three kinds of sliding condition under a constant speed were used to see the effects of the oxidationand the abrasion. The contact pressure was more effective than the repeated cycle on the wear behavior of ${Si_3}{N_4}$. With the low loads, the effect of the asperity-failure was more dominant than that of oxidation and abrasion. As increasing the load, the effects of oxidation and abrasion were increased, but the asperity-failure effects were decreased. The wear particles destroyed the ozide layers formed on sliding surfaces. The wear rate could be decreased due to delaying the oxidation. The frictional power and the wear weight per time were usefuel to see the transition of wear.

Evaluation of Advanced Oxidation Process(AOP) as a Pretreatment Process of Biological Activated Carbon in Drinking Water Treatment (정수처리에서 생물활성탄의 전처리로서 고급산화처리법의 평가)

  • Kim Woo-Hang
    • Journal of Environmental Science International
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    • v.8 no.6
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    • pp.725-730
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    • 1999
  • The advanced oxidation process (AOP) using ozone combined with hydrogen peroxide and ultraviolet treatment were evaluated for biodegradable dissolved organic carbon (EDOC) formation and dissolved organic carbon (DOC) removal. Oxidation treatment were conducted alone or combination with ozone, hydrogen peroxide and ultraviolet processes. Ozone dosage of ozone process was varied from $0.5mg/l{\ell}\cdot}min$ to $5mg/{\ell}{\cdot}min$. Ozone/hydrogen peroxide process was done using $20mg/{\ell}{\cdot}min$ of hydrogen peroxide concentration. Ozone/ultraviolet process was irradiated with $12mW/cm^2$ of density and 254nm. Ozone dosage was varied from $0.5mg/{\ell}{\cdot}min$ to $5mg/{\ell}{\cdot}min$ at the ozone/hydrogen peroxide and ozone/ultraviolet processes too. Contact time of all the process was 20 minutes. Oxidation treatment were performed on microfiltration effluent samples. BDOC formation was reached to an optimum at ozone dosage of $1.5mg/{\ell}{\cdot}min$ in the ozone/hydrogen peroxide process and $1mg/{\ell}{\cdot}min$ in ozone/ultraviolet process, after which BDOC formation was decreased at higher ozone dosages. But BDOC formation was increased with ozone dosages increasing in ozone process. The efficiency of DOC removal was higher AOPs than ozone process. Ozone/ultraviolet proces was the highest for DOC removal efficiency in each process. THMFP. removal efficiency by ozone/ultraviolet process was higher than that by each of ozone process and ozone/hydrogen peroxide process.

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The Analysis of Voltage Waveform and Oxidation Growth of Conductor Due to Direct Arc (직렬아크에 따른 도체의 산화물 증식 및 전압파형 분석)

  • Choi, Chung-Seog;Kim, Hyang-Kon;Shong, Kil-Mok;Kim, Dong-Ook;Kim, Dong-Woo;Kim, Young-Seok
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1832-1834
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    • 2005
  • In the electrical equipments, there are lots of phenomena such as loosening of connectin parts, So, heat generation and oxidation growth is considered to have a possibility to cause fire. In this Paper, we were carried out to study the oxidation growth and voltage waveform of connecting parts. In case of copper and copper connection, the growing of Cu2O elongated more than the other copper alloys. According to oxidation growth, the voltage waveform is distorted. And the contact voltage and the power dissipation increased rapidly.

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Semi-Permanent Hydrophilization of Polyester Textile by Polymerization and Oxidation Using Atmospheric Pressure Dielectric Barrier Discharge (APDBD)

  • Se Hoon Shin;Yoon Kee Kim
    • Korean Journal of Materials Research
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    • v.33 no.4
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    • pp.115-123
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    • 2023
  • In this paper, we report and discuss the semi-permanently hydrophilic (SPH) treatment of polyester fabric using plasma polymerization and oxidation based on atmospheric pressure dielectric barrier discharge (APDBD) technology. SiOxCy(-H) was coated on polyester fabric using Hexamethylcyclotrisiloxane (HMCTSO) as a precursor, and then plasma oxidation was performed to change the upper layer of the thin film to SiO2-like. The degradation of hydrophilicity of the SPH polyester fabrics was evaluated by water contact angle (WCA) and wicking time after repeated washing. The surface morphology of the coated yarns was observed with scanning electron microscopy, and the presence of the coating layer was confirmed by measuring the Si peak using energy dispersive x-ray spectroscopy. The WCA of the SPH polyester fabric increased to 50 degrees after 30 washes, but it was still hydrophilic compared to the untreated fabric. The decrease in hydrophilicity of the SPH fabric was due to peeling of the SiOxCy(-H) thin film coated on polyester yarns.

Water Quality Improvement Using Inverted Siphon Curved Channel System of Serial Contact Materials (연속접촉재 역사이폰 만곡수로 시스템의 수질개선)

  • Lee, Jong-Seok;Lee, Seung-Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.6B
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    • pp.541-550
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    • 2011
  • This study sets the goal to improve effectively water quality of stream by complementing the weak points of the gravel contact oxidation process to use the inverted siphon curved channel system in free overfall of serial contact materials. The size of the current system can be diminished by expanding contact time, and the materials' replacement can be made easier when their gap are closed through the filtering boxes of contact materials. This system also has been developed into a construction method in which mixed and serial contact materials can be employed by using just the conventional single contact materials. It was verified the improvement ability of water quality of this system, during the simulation test at Tandong stream in Daejeon. The results of the verification of water quality improvement through several experiments in field were measured as follows : it showed to reduce about the averaged 55~83% higher than 60~75%, the internal planned goal of water quality improvement facilities.

Strain-induced enhancement of thermal stability of Ag metallization with Ni/Ag multi-layer structure

  • Son, Jun-Ho;Song, Yang-Hui;Kim, Beom-Jun;Lee, Jong-Ram
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.157-157
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    • 2010
  • Vertical-structure light-emitting diodes (V-LEDs) by laser lift-off (LLO) have been exploited for high-efficiency GaN-based LEDs of solid-state lightings. In V-LEDs, emitted light from active regions is reflected-up from reflective ohmic contacts on p-GaN. Therefore, silver (Ag) is very suitable for reflective contacts due to its high reflectance (>95%) and surface plasmon coupling to visible light emissions. In addition, low contact resistivity has been obtained from Ag-based ohmic contacts annealed in oxygen ambient. However, annealing in oxygen ambient causes Ag to be oxidized and/or agglomerated, leading to degradation in both electrical and optical properties. Therefore, preventing Ag from oxidation and/or agglomeration is a key aspect for high-performance V-LEDs. In this work, we demonstrate the enhanced thermal stability of Ag-based Ohmic contact to p-GaN by reducing the thermal compressive stress. The thermal compressive stress due to the large difference in CTE between GaN ($5.6{\times}10^{-6}/^{\circ}C$) and Ag ($18.9{\times}10^{-6}/^{\circ}C$) accelerate the diffusion of Ag atoms, leading to Ag agglomeration. Therefore, by increasing the additional residual tensile stress in Ag film, the thermal compressive stress could be reduced, resulting in the enhancement of Ag agglomeration resistance. We employ the thin Ni layer in Ag film to form Ni/Ag mutli-layer structure, because the lattice constant of NiO ($4.176\;{\AA}$ is larger than that of Ag ($4.086\;{\AA}$). High-resolution symmetric and asymmetric X-ray diffraction was used to measure the in-plane strain of Ag films. Due to the expansion of lattice constant by oxidation of Ni into NiO layer, Ag layer in Ni/Ag multi-layer structure was tensilely strained after annealing. Based on experimental results, it could be concluded that the reduction of thermal compressive stress by additional tensile stress in Ag film plays a critical role to enhance the thermal stability of Ag-based Ohmic contact to p-GaN.

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