• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.327-334
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• 2018

Water-repellent coating solutions were prepared by sol-gel method using tetraethoxysilane (TEOS) and methyltrimethoxysilane (MTMS) as precursors. The solutions were spin-coated on a cold-rolled steel sheet and thermally cured to prepare a non-fluorine water-repellent coating films. The effects of molar ratios of MTMS/TEOS, water concentration and ammonia concentration on the hydrophobic properties of the coating films were studied. The contact angle of water on coating films prepared by varying the molar ratio of MTMS/TEOS to 1~20 showed a maximum value of $108^{\circ}$ when the MTMS/TEOS molar ratio was 10. With increasing water content, the coating films showed the larger contact angles and the better the water repellency. As the amount of ammonia added was increased, the contact angles of coating films were increased, showing the better the water repellency. It is considered that the larger the amount of ammonia added, the larger the size of the silica particles generated, which increases the surface roughness of the silica particles, thereby increasing the water repellency.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.1080-1083
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• 2002

In this paper, we have studied with regard to the use of lasers for modifying the surface properties of silicon in order to improve it's wettability and adhesion characteristics. Using an Nd:YAG pulse laser, the wettability and adhesion characteristics of silicon surface have been developed by an Nd:YAG pulse laser. It was found that the laser treatment of silicon surfaces modified the surface energy. In the result of wetting experiments, by the sessile drop technique using the distilled water, wetting characteristic of silicon after the laser irradiation shows a decreased value of the contact angle. In case of the laser treated silicon surface, laser direct writing of copper lines has been achieved by pyrolytic decomposition of copper formate films$(Cu(HCOO)_2{\cdot}4H_2Q)$, using a focused $Ar^+$ laser beam$(\lambda=514.5nm)$ on the silicon substrates. The deposited patterns were measured by energy dispersive X-ray(EDX), Scanning Electron Microscopy(SEM) and surface profiler($\alpha$-step) to examine the cross section of deposited copper lines and linewidth.

• Journal of the Korean institute of surface engineering
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• v.29 no.6
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• pp.781-787
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• 1996

Silicom oxide films with good water repellency were prepared by rf plasma-enhanced CVD (rf-PECVD) using four kinds of organosilicon compound, which had different number of methyl ($CH_3$) groups, and oxygen as gas sources. The differences in the deposition rates, film composition and film properties were studied in detail. Water repellency depended on the number of $CH_3$ groups in the organosilicon compounds and the partial pressure of oxygen in the plasma. The highest contact angle for water drops, about 95 degrees, was obtained when trimethy lmethoxy silane (TMMOS) was used. The contact angle decreased with the amount of oxygen gas introduced into the plasma. The dissociation of $CH_3$ groups by adding oxygen was comfirmed by Fourier transform infrared spectroscopy(FTIR) and X-ray photoelectron spectroscopy (XPS). The optical properties were estimated by double-beam spectroscopy and ellipsometry. The transmittance of the glass plate coated by the film prepared with tetramethoxy silane (TMOS) was about 90% and the refractive index of film was 1.44. This value was smaller than the refractive index of a glass plate(soda lime glass, refractive index is 1.515) and this film played a role of anti-refractive coating.

• Macromolecular Research
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• v.17 no.6
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• pp.388-396
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• 2009

The surface properties (water sorption and repellency, adhesion) are closely related to the surface tension of polymer solids. The critical surface tension (${\gamma}_c$) and surface tension (${\gamma}_s$) of a polymer solid were estimated by the contact angle method by our quantitative imaging system. BPDA (3,3',4,4'-biphenyl tetracarboxylic dianhydride)-BAPP (1,3-Bis(4-aminophenoxy) propane) polyimide was successfully synthesized. The ${\gamma}_c$ values were analyzed by a Zisman plot, a Young-$Dupr\acute{e}$-Good-Girifalco plot, and a log ($1+cos{\theta}$) vs log ${\gamma}_L$ plot. The ${\gamma}_s$ value of BPDA-BAPE polyimide was evaluated using the geometric mean equation and our multiple regression analysis. The calculated values of ${{\gamma}_s^d$ (a dispersion component), ${{\gamma}_s^p$ (a polar component), ${{\gamma}_s^h$ (a hydrogen bonding component), and ${\gamma}_s$ were 30.79, 9.32, 0.20, and 40.31 $mN{\cdot}m^{-1}$, respectively. The ${\gamma}_s$ of BPDA-BAPP polyimide containing both a methylene group and an ether group was larger than that of the polyimide containing only a methylene group.

• Korean Journal of Materials Research
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• v.18 no.3
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• pp.128-136
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• 2008

Evaluation of the solid surface properties by an analysis of the liquid penetration rate into powder beds is very important in applications of powder products. The penetration rate is related the surface property in powder beds. In order to analyze the surface property of powders, the contact angle values of several powders were obtained using the Washbun equation and the Wicking method. The surface free energy value ${\gamma}S$ was divided into a polar component ${\gamma}S^p$ and a dispersion component ${\gamma}S^d$. Inorganic powders such as calcite were used as test samples. The effects of the particle size and the type of experimental liquid on the penetration rate were measured. It was confirmed that the surface free energy of the grinding sample is smaller than that of the classification sample.

• Computers and Concrete
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• v.23 no.5
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• pp.351-359
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• 2019

In this study, the calcium hydroxide, an inherent product of cement hydration, was treated using biomimetic carbonation method of incorporating stearic acid to generate the hydrophobic calcium carbonate on concrete surface. Carbonation reaction was carried out at various $CO_2$ pressure and temperatures and utilizing the Scanning Electron Microscope (SEM), chloride-ion penetration test apparatus, and compression test machine to investigate the hydrophobicity, durability, and mechanical properties of the synthesized products. Experimental results indicate that the calcium stearate may change the surface property of concrete from hydrophilicity to hydrophobicity. Increasing reaction temperature can change the particles from irregular shapes to needle-rod structures with increased shear stress and thus favorable to hydrophobicity and microhardness. The contact angle against water for the concrete surface was found to increase with increasing $CO_2$ pressure and temperature, and reached to an optimum value at around $90^{\circ}C$. The maximum static water contact angle of 128.7 degree was obtained at the $CO_2$ pressure of 2 atm and temperature of $90^{\circ}C$. It was also found that biomimetic carbonation increased the permeability, acid resistance and chloride-ion permeability of the concrete material. These unique results demonstrate that the needle-rod structures of $CaCO_3$ synthetized on concrete surface could enhance hydrophobicity, durability, and mechanical properties of concrete.

• Journal of Korean society of Dental Hygiene
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• v.23 no.6
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• pp.459-466
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• 2023

Objectives: The purpose of this study was to evaluate the physical properties and antibacterial activity of denture base resin with added silver sulfadiazine. Methods: Specimens were made from self-curing denture base resin and silver sulfadiazine as an inorganic antibacterial agent. For physical evaluation of the specimens, surface roughness, surface hardness, and contact angle were measured. Bacterial growth was assessed by optical densityat 600 nm (OD600) and colony forming units (CFU) measurements to confirm antibacterial activity. Results: There was no significant difference in surface roughness, surface hardness, and contact angle in the experimental group containing silver sulfadiazine compared to the control group. In contrast, the experimental group showed a significant decrease in antibacterial activity compared to the control group in terms of OD value. Analysis of CFU confirmed a significant decrease in colonies in the experimental group compared to the control group. Conclusions: Denture base resin containing silver sulfadiazine, an inorganic antibacterial agent, exhibited enhanced antibacterial activity without physical changes. In conclusion, the use of denture base resin containing inorganic antibacterial agents may be expected in the future.

• Korean Journal of Environment and Ecology
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• v.7 no.2
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• pp.252-269
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• 1994

This study was conducted to the early diagnosis of injuries on needles of conifer by acid rain and air pollutants in metropolitan area, Korea. It was executed to calculate of injured index, contact angle measurement, nutrient content analysis in needles, analysis of soil chemical properties from June 1990 to June 1991. The sensitive species (Picea abies, Abies holophylla) for acid rain and air pollutants were used as the study materials. And the results from this study were as follows : Degree of Injured index was divided into three groups in June 1990. The first group (not injured sites) was Kwangnung and Yangpyung. The Second group (slight injured sites) was Inchon, Boramae Park, Kwachun, Seoul Women's Univ., Anyng, and Yangsuri. The third group (serious injured sites) was Namsan, Seoul City Univ., Children's Park, and Kumgok Royal Tomb. But, Inchon, Kwachon area were changed from slight injured areas to serious injured areas in December 1990. As time goes on, the degree of injured gets worse. In contact angle analysis, value of December 1990 was lower than that of June 1990, especially, that of two-year-needle were lower than of one-year-needle. The correlation between injured Index and contact angle was significantly negative. In the result of needle nutrients analysis of Picea abies, Abies hozophylla, Ca, Mg, K contents was higher in December 1990 than that in June 1991 and that of one-year-needle were prominantly higher than that of two-year-needle. In case of wax quantity analysis in injured area, the older the leaf age is, the smaller the contented wax quantity is. In injured area, the higher a leaf age is, the much that of index is. As a result, the method of analysis referred in the former, is applied by a complementary cooperation. That of method is done sustainably in the future, the correct results will be expected.

• Journal of the Korean Geosynthetics Society
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• v.22 no.4
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• pp.43-49
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• 2023

This study described the test results to evaluate the effect of fines content on the wettability of sandy soil composed of hydrophobic soil particles. Wettability was evaluated using the contact angle obtained from the water drop test results for Jumunjin standard sand and sandy soil containing fines content. The test results showed that the wettability of sandy soil composed of sand and fine-grained soil changed depending on the hydrophobic level and fines content. The influence of fines content on the wettability of sandy soil was analyzed. It was found that 1% and 3% hydrophobic sandy soil with 5% fines content decreased by 94.4% and 32.4%, respectively, compared to the contact angle of standard sand. In addition, the contact angle reduction ratio for sandy soil with a 5% hydrophobic level and a fines content of 5% and 10% were 24.4% and 37.3%, respectively. In other words, the wettability of the soils should be evaluated considering the fines content to predict the behavior of contaminants, because the fines content has a significant impact on the value and increase/decrease ratio of the contact angle of sandy soil

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.383-388
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• 2001

Effects of particle property variation of cone crack shape according to impact velocity in silicon carbide materials were investigated. The damage induced by spherical impact having different material and size was different according to materials. The size of ring cracks induced on the surface of specimen increased with increase of impact velocity within elastic contact conditions. The impact of steel particle produced larger ring cracks than that of SiC particle. In case of high impact velocity, the impact of SiC particle produced radial cracks by the elastic-plastic deformation at impact regions. Also percussion cone was formed from the back surface of specimen when particle size become large and its impact velocity exceeded a critical value. Increasing impact velocity, zenithal angle of cone cracks in SiC material was linearly decreasing not effect of impact particle size. An empirical equation, $\theta=\theta_{st}-\upsilon_p(180-\theta_{st})(\rho_p/\rho_s)^{1/2}/415$, was obtained from the test data as a function of quasi-static zenithal angle of cone crack($\theta_{st}$), the density of impact particle(${\rho}_p$) and specimen(${\rho}_s$). Applying this equation to the another materials, the variation of zenithal angle of cone crack could be predicted from the particle impact velocity.