• Title/Summary/Keyword: contact angle test

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A Study of Corona Discharge in Polymer Insulators by Artificial UV Radiation (인위적인 자외선 조사량에 따른 폴리머애자에서의 코로나 방전 특성)

  • Kim, Y.S.;Choi, M.I.;Kim, C.M.;Bang, S.B.;Shong, K.M.;Kwag, D.S.
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.5
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    • pp.643-648
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    • 2013
  • In this study, degradation was observed by irradiating UV rays to the polymer insulators which have been widely used in outdoor electric power facilities. For an indoor accelerated UV test, 0.55 w/m2 of UV rays were applied using a xenon-arc method. A UV detection system with 65 ${\phi}mm$ in diameter, 100 mm in length and 1.0 of brightness (F/#) has been designed. Even though efflorescence on the surface of polymer insulators wasn't observed according to the accelerated UV test. UV rays were detected at around 50% and 40% of insulation breakdown in EPDM and silicone-type insulators respectively. As degradation continued because of an indoor accelerated UV test, breakdown voltage with which UV rays can be detected in an early stage decreased as well. A silicone polymer insulator would be severer than EPDM polymer insulator in terms of surface degradation because of UV strength against $V_m/V_{BD}$ was high in silicone polymer insulators. UV strength in silicone-type insulators increased at 1,000 $kJ/m^2$ because contact angle at the intial stage sharply decreased to from $113^{\circ}$ to $92.1^{\circ}$.

Analysis of PVDF Coating Properties with Addition of Hydrophobically Modified Fumed Silica

  • Lee, Nam Kyu;Kim, Young Hoon;Im, Tae Gyu;Lee, Dong Uk;Shon, MinYoung;Moon, Myung Jun
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.232-242
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    • 2019
  • In this study, hydrophobically modified fumed silica was added to the PVDF coating to improve corrosion protection performance. Two types of silane modifiers, trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ), were used for hydrophobic modification of the fumed silica. The composition of modified fumed silica was analyzed by Fourier transform infrared, X-ray photoelectron spectroscopy, and elemental analysis. The dispersion of modified fumed silica in the PVDF coating was observed by the transmission electron microscopy, and the hydrophobicity of PVDF coating was analyzed by the water contact angle. Surface properties were examined by the field emission scanning electron microscopy and scanning probe microscopy. Potentiodynamic polarization was conducted to confirm corrosion protection performance of PVDF coating in terms of hydrophobically-modified fumed silica contents. As a result, the average surface roughness and the water contact angle of the PVDF coating increased with modifier contents. The results of the potentiodynamic polarization test showed an increase of the Ecorr values with increase of the hydrophobicity of PVDF coating. Thus, it clearly indicates that the corrosion protection performance of PVDF coating improved with the addition of the hydrophobic-modified fumed silica that prevents the penetration of moisture into the PVDF coating.

Investigation on the Liquid Water Droplet Instability in a Simulated Flow Channel of PEMFC (고분자전해질형 연료전지의 유로 채널 모사를 통한 단일 액적의 불안정성 관찰)

  • Kim, Bo-Kyung;Kim, Han-Sang;Min, Kyung-Doug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.2
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    • pp.93-98
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    • 2008
  • To investigate the characteristics of water droplet on the gas diffusion layer from both top-view and side-view of the flow channel, a rig test apparatus was designed and fabricated with prism attached plate. This experimental device is used to simulate the growth of single liquid water droplet and its transport process with various air flow velocity and channel height. The contact angle hysteresis and height of water droplet are measured and analyzed. It is found that droplet tends towards to be instable by decreasing channel height, increasing flow velocity or making GDL more hydrophobic. Also, the simplified force balance model matches with experimental data only in a restricted range of operating conditions and shows discrepancy as the air flow velocity and channel height increases.

Facile Modification of Surface of Silica Particles with Organosilanepolyol and Their Characterization

  • Lee, Joongseok;Han, Joon Soo;Yoo, Bok Ryul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3805-3810
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    • 2013
  • The surface modification of silica particles (SPs) was systemically conducted by the treatment of 0.1-10 wt % phenylsilanetriol (PST) on the basis of SPs used through two step processes: 1) the PST coating of SPs via evaporation under reduced pressure and 2) their thermal condensation leading to Si-O-Si bond formation via heating at $130^{\circ}C$. The evaluation of the modified SPs was conducted by the simple floating test on water and the measurement of the contact angle (CA) of water droplet on the 2-dimensional layer of modified SPs on slide glass. When PST was used about 2 wt % or above on the basis of SPs (about average size: 50 nm) used, the modified SPs were fully floated on the water and all dispersed into upper organic solvent layer after a shaking with the mixture of the water and benzene, indicating that the modified SPs have hydrophobic properties. The modified SPs were characterized by $^{29}Si$ MAS NMR and physicochemical properties including SEM, TEM, BET, adsorption/desorption isotherms, etc. were measured and compared each other in details. This research demonstrates that the organosilanetriol is a good modifier applicable for the surface modification of inorganic oxide particles using a low amount of modifier on the basis of oxide particles used.

The Annealing Effect of Diamond-like Carbon Films for RF MEMS Switch

  • Hwang, Hyun-Suk;Choi, Won-Seok;Cha, Jae-Sang
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.11A
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    • pp.1091-1096
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    • 2010
  • Stiction in microelectromechanical systems (MEMS) has been a major failure mechanism. Especially, in RF MEMS switches, moving parts often suffered in-use and release related stiction problems. Some materials and methods have been used to prevent this problem. Diamond-like carbon (DLC) has not only been used as a protective material owing to its good mechanical properties but also has been used as a hydrophobic material. Its properties could be controlled by post annealing treatment in various conditions. We synthesized DLC films using a radio frequency plasma enhanced chemical vapor deposition (RF PECVD) method on silicon substrates using methane ($CH_4$) and hydrogen ($H_2$) gas. Then, the change of the hydrophobic property of the films was investigated undervarious annealing temperatures in nitrogen and in oxygen ambient. The films, that were annealed above $700^{\circ}C$ in nitrogen ambient, showed a high contact angle of water (> $90^{\circ}$) even though their mechanical property was sacrificed to some degree. The structural variation and the changes of the hydrophobic and mechanical properties of the DLC films were analyzed by Raman spectrum, contact angle measurement, surface profiler, and a nanoindentation test.

Evaluation of Solid Surface Properties by Analysis of Liquid Penetration Rate into Powder Beds (분체층 내 액체 침투속도 해석에 의한 분체 표면성질의 평가)

  • Ha, Jong-Hak;Kim, Seong-Soo;Wang, Lin;Choi, Hee-Kyu
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.128-136
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    • 2008
  • Evaluation of the solid surface properties by an analysis of the liquid penetration rate into powder beds is very important in applications of powder products. The penetration rate is related the surface property in powder beds. In order to analyze the surface property of powders, the contact angle values of several powders were obtained using the Washbun equation and the Wicking method. The surface free energy value ${\gamma}S$ was divided into a polar component ${\gamma}S^p$ and a dispersion component ${\gamma}S^d$. Inorganic powders such as calcite were used as test samples. The effects of the particle size and the type of experimental liquid on the penetration rate were measured. It was confirmed that the surface free energy of the grinding sample is smaller than that of the classification sample.

Performance and Stability Enhancement of Organic Solar Cells by Surface Treatment Processes of Transparent Electrodes (표면 전처리 공정에 따른 투명전극 계면 특성 변화와 유기 태양전지 성능 및 안정성 향상)

  • Lee, Kwan-Yong;Kim, Do-Hyun;Park, Sun-Joo;Kim, Young-Joo
    • Transactions of the Society of Information Storage Systems
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    • v.9 no.2
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    • pp.42-47
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    • 2013
  • In this study, we have experimentally analyzed how the surface properties of transparent electrode layer influence the photovoltaic performance of bulk heterojunction organic solar cell by the contact angle measurement and X-ray photoelectron spectroscopy(XPS) observation. As a result, the power conversion efficiency of test devices improved from 0.64% to 1.83% and 2.15% by UV-ozone exposure and $O_2$ plasma treatment, respectively. Thus, we conclude that the surface activation process is very important for better performance and stability in addition to the cleaning process of carbonate residue on the surface.

Synthesis and Printability of Aqueous Ceramic Ink with Graft Polymer (Graft Polymer를 이용한 수계 세라믹 잉크의 합성 및 프린팅 특성평가)

  • Lee, Ji-Hyeon;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.639-646
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    • 2019
  • Ink-jet printing is a manufacturing process technology that directly prints a digitalized design pattern onto a substrate using a fine ink jetting system. In this study, environmentally friendly yellow aqueous ceramic ink is synthesized by mixture of distilled water, yellow ceramic pigment and additives for ink-jet printing. The graft polymer, which combines electrostatic repulsion and steric hindrance mechanism, is used as a surfactant for dispersion stability of aqueous ceramic ink. Synthesized ceramic ink with graft polymer surfactant shows better dispersion stability than did ceramic ink with PAA surfactant; synthesized ink also shows desirable ink-jet printability with the formation of a single ink droplet during printability test. Finally, ceramic ink printed on glass substrate and ceramic ink with graft polymer surfactant shows a high contact angle without surface treatment on glass substrate. Consequently, it is confirmed that the ceramic ink with graft polymer surfactant can achieve high printing resolution without additional surface treatment process.

Analysis of underground post-tensioned precast concrete box utility tunnel under normal fault displacement

  • Wu, Xiangguo;Nie, Chenhang;Qiu, Faqiang;Zhang, Xuesen;Hong, Li;Lee, Jong-Sub;Kang, Thomas H.K.
    • Computers and Concrete
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    • v.29 no.2
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    • pp.69-79
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    • 2022
  • For long underground box utility tunnels, post-tensioned precast concrete is often used. Between precast tunnel segments, sealed waterproof flexible joints are often specified. Fault displacement can lead to excessive deformation of the joints, which can lead to reduction in waterproofing due to diminished contact pressure between the sealant strip and the tunnel segment. This paper authenticates utilization of a finite element model for a prefabricated tunnel fault-crossing founded on ABAQUS software. In addition, material parameter selection, contact setting and boundary condition are reviewed. Analyzed under normal fault action are: the influence of fault displacement; buried depth; soil friction coefficient, and angle of crossing at the fault plane. In addition, distribution characteristics of the utility tunnel structure for vertical and longitudinal/horizontal relative displacement at segmented interface for the top and bottom slab are analyzed. It is found that the effect of increase in fault displacement on the splice joint deformation is significant, whereas the effects of changes in burial depth, pipe-soil friction coefficient and fault-crossing angle on the overall tunnel and joint deformations were not so significant.

Optimum Cam Profile Design and Experimental Verification on an OHC Type Cam-valve System (OHC형 캠-밸브 기구의 최적 캠 형상설계 및 실험적 검증)

  • 김성훈;김원경;박윤식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.11
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    • pp.2049-2058
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    • 1992
  • In this work, a 6 degree of freedom lumped mass model is constructed for an OHC-type cam valve train analysis, and the model is verified experimentally. Using the verified model, an optimum cam profile is designed to minimize the maximum contact force between cam and follower under the constraints such as cam lift and cam event angle. The designed cam was carefully machined and tested experimentally. As operating the designed cam shaft on the test rig, the valve motion was precisely measured with laser displacement meter and the contact force was indirectly monitored by measuring strain at a certain point of the finger follower. Judging from the model simulation and experiment results, the maximum contact force can be reduced as much as more than 16.7 percent under maintaining the original valve flow area by adopting the optimum cam profile.