• 한국수자원학회논문집
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• 제32권1호
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• pp.61-70
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• 1999

자연하천에 유입된 오염물질의 확산거동을 해석하기 위하여 통계학적인 개념을 이용하여 오염물질 입자의 운동을 묘사하는 2차원 Random-Walk 모형을 개발하였다. 개발된 모형을 검정한 결과, 고정격자의 개수를 증가시키거나 각각의 고정격자 내에 포함된 입자개수의 평균값을 증가시키면 해의 정밀도가 증가하는 것으로 나타났다. 본 모형의 현장 적용성을 검토하기 위하여 캐나다에 위치한 Grand River에서 수행된 정상상태의 색소실험 결과와 본 모형에 의한 계산결과를 비교하였다. 그 결과 본 모형은 단면과 곡률이 불규칙하게 변하는 자연하천에서의 횡확산을 정확하게 모의하는 것으로 나타났다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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• pp.54-56
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• 2006

Single-well-gas-sparging tests were developed and evaluated for assessing the feasibility of in-situ aerobic cometabolism of trichloroethylene (TCE), using propane as a growth substrate. To evaluate transport characteristics of dissolved solutes [sulfur hexafluoride (SF6) or bromide (non-reactive tracers), propane (a growth substrate), ethylene, propylene (nontoxic surrogates to probe for CAH transformation activity), and DO], push-pull transport tests were performed. Mass balance showed about 90% of the injected bromide and about 80% of the injected SF6 were recovered, and the recoveries of other solutes were comparable with bromide and slightly higher than SF6. A series of Gas-Sparging Biostimulation tests were performed by sparging propane/oxygen/argon/SF6 gas mixtures, and temporal ground water samples were obtained from the injection well under natural gradient 'drift' conditions. The decreased time for propane depletion and the longer time to deplete SF6 as a conservative tracer indicate the progress of biostimulation. Gas-Sparging Activity tests were performed. .Propane utilization, DO consumption, and ethylene and propylene cometabolism were well demonstrated. The stimulated propane-utilizers cometabolized ethylene and propylene to produce ethylene oxide and propylene oxide, as cometabolic by-products, respectively. Gas-Sparging Acetylene Blocking tests were performed by sparging gas mixtures including acetylene to demonstrate the involvement of monooxygenase enzymes. Gas substrate degradation was essentially completely Inhibited in the presence of acetylene, and no production of the corresponding oxides was also observed. The Gas-Sparging tests supports the evidences that the successive stimulation of propane-oxidizing microorganisms, cometabolic transformation of ethylene and propylene by the enzyme responsible for methane and propane degradation.