• Title/Summary/Keyword: conductivity.

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Development of Conductivity Cell and Suppressor for Capillary Column Ion Chromatography (모세관 컬럼 이온 크로마토그래피를 위한 Conductivity Cell과 Suppressor의 개발)

  • Pyo, Dongjin;Kim, Hohyun
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.89-93
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    • 1999
  • In this study, conductivity cell and suppressor for micro-column ion chromatography were developed to analyze ions in small columns of samples. With a capillary column, the flow rate of the mobile phase is so small (usually $5{\sim}20{\mu}L/min$) that the usual conductivity cell can not be used. Therefore, we developed a new type of conductivity cell and suppressor which have small inner volumes. The conductivity cell was made with two Pt hypodermic needles (i.d. 0.010 mm) which are slightly separated (about $2{\mu}m$), and the suppressor was made of Nafion tubings. When several anions(fluoride, nitrite, nitrate, chlorate) were analyzed using developed conductivity cell and suppressor, a good chromatogram was obtained.

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Improvement of Thermal and Electrical Conductivity of Epoxy/boron Nitride/silver Nanoparticle Composite (열전도도 및 전기전도도가 향상된 에폭시/보론나이트라이드/은나노입자 복합체의 제조)

  • Kim, Seungyong;Lim, Soonho
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.426-429
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    • 2017
  • In this study, we investigated the effect of BN (boron nitride) on the thermal and the electrical conductivity of composites. In case of epoxy/BN composites, the thermal conductivity was increased as the BN contents were increased. Epoxy/AgNP (Ag nanoparticle) nanocomposites exhibited a slight change of thermal conductivity and showed a electrical percolation threshold at 20 vol% of Ag nanoparticles. At the fixed Ag nanoparticle content below the electrical percolation threshold, increasing the amount of BN enhanced the electrical conductivity as well as thermal conductivity for the epoxy/AgNP/BN composites.

Electrical Conduction in $SrZr_{0.95}Y_{0.05}O_{2.975}$ Ceramics

  • Baek, Hyun-Deok;Noh, Jin-Hyo
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.288-295
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    • 1999
  • Partial conductivities contributed by electron holes, oxygen ions, and protons were caluclated in $SrZr_{0.95}Y_{0.05}O_{2.975}$, using the reported formulae derived from the defect chemistry of HTPCs. Required parameters were obtained from the graphical analysis of total conductivity variation against partial pressure of water vapor and oxygen. Predicted overall conductivities showed a reasonable agreement with experimental measurements. The conductivity of the material showed a linear increase with square root of the water vapor pressure. This increase was due to proton conduction in an almost pure ionic conductivity. The calculation of partial conductivities at $800^{\circ}C$ resulted in an almost pure ionic conductivity at $P_{02}=10^{-10}$ atm and a predominant hole conductivity at $P_{02}=10^{-10}$ atm. Pure proton conduction was not expected at this temperature, contrary to the earlier reports. Discussions were made in relation with reported thermodynamic data and defect structure of the material. It was shown that from the total conductivity dependence on water vapor pressure, the pure ionic conductivity at low oxygen partial pressures could be separated into protonic and oxygen ionic conductivity in $ZrO_2$-based HTPCs.

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Long-Term Hydraulic Conductivity and Cation Exchange of a Geosynthetic Clay Liner (GCL) Permeated with Inorganic Salt Solutions

  • Jo, Ho Young;Benson, Craig H.;Edil, Tuncer B.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.59-62
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    • 2004
  • Hydraulic conductivity tests were conducted on a geosynthetic clay liner (GCL) for more than 2.5 yr using inorganic salt solutions to evaluate how the long-term hydraulic conductivity is affected by cation concentration and valence. Only small changes (i.e., $\leq$ 2X) in hydraulic conductivity (K) occurred during the test duration when the permeant solution was deionized (DI) water or 100 mM KCl and NaCl solutions. For weak CaCl$_2$ solutions ($\leq$ 20 mM), the hydraulic conductivities initially (< 0.2 yr) were comparable to the hydraulic conductivity obtained with DI water, but gradually increased by a factor of 2 to 13 over a period of nearly 2 yr. In contrast, the GCL permeated with strong CaCl$_2$ solutions ($\geq$ 50 mM) reached equilibrium nearly immediately, with a hydraulic conductivity approximately 2 orders of magnitude higher than the hydraulic conductivity to DI water.

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Fundamental Study of Deicing Pavement System Using Conductive Materials (전도성 재료를 사용한 도로결빙방지 포장시스템 개발을 위한 기초연구)

  • Lee, Kanghwi;Lee, Jaejun
    • International Journal of Highway Engineering
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    • v.17 no.5
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    • pp.11-18
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    • 2015
  • PURPOSES : The purpose of this study is to develop a deicing pavement system using carbon fiber or graphite with high electrical conductivity and thermal conductivity. METHODS: Based on literature reviews, in general, conventional concrete does not exhibit electrical and thermal conductivity. In order to achieve a new physical property, experiments were conducted by adding graphite and carbon fiber to a mortar specimen. RESULTS: The result of the laboratory experiment indicates that the addition of graphite can significantly reduce the compressive strength and improve the thermal conductivity of concrete. In the case of carbon fiber, however, the compressive strength of the concrete is slightly increased, whereas, the thermal conductivity is slightly decreased against the plain mortar irrespective of the length of the carbon fiber. In addition, a mixture of the graphite and carbon fiber can greatly improve the degree of heating test. CONCLUSIONS : Various properties of cement mortar change with the use of carbon fiber or graphite. To enhance the conductivity of concrete for deicing during winter, both carbon fiber and graphite are required to be used simultaneously.

RF Conductivity Measurement of Conductive Zell Fabric

  • Nguyen, Tien Manh;Chung, Jae-Young
    • Journal of electromagnetic engineering and science
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    • v.16 no.1
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    • pp.24-28
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    • 2016
  • This study presents a conductivity measurement technique that is applicable at radio frequencies (RF). Of particular interest is the measurement of the RF conductivity of a flexible Zell fabric, which is often used to implement wearable antennas on clothes. First, the transmission coefficient is measured using a planar microstrip ring resonator, where the ring is made of a Zell fabric. Then, the fabric's conductivity is determined by comparing the measured transmission coefficient to a set of simulation data. Specifically, a MATLAB-based root-searching algorithm is used to find the minimum of an error function composed of measured and simulation data. Several error functions have been tested, and the results showed that an error function employing only the magnitude of the transmission coefficient was the best for determining the conductivity. The effectiveness of this technique is verified by the measurement of a known copper foil before characterizing the Zell fabric. The conductivity of the Zell fabric at 2 GHz appears to be within the order of $10^4S/m$, which is lower than the DC conductivity of $5{\times}10^5S/m$.

Relationship Between Electrical Conductivity, Exchangeable Sodium Percentage and pH During Desalinization of Reclaimed Tidelands (간척지토양의 제염과정중 전기전도도와 치환성 나트륨 백분율 및 pH 사이의 관계)

  • 구자웅;은종호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.30 no.4
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    • pp.127-133
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    • 1988
  • This study was performed to obtain the basic data analyzing salt movement and desalinization effects, and two different desalinization experiments through leaching and rinsing were carried out, using samples of silt loam soil and silty clay loam soil collected in reclaimed tidelands. The relationships between the electrical conductivity of saturation extract and the electrical conductivity at various dilutions, and the correlations between electrical conductivity, total salt concentration, exchangeable sodium percentage and pH during the desalinization of reclaimed tidelands, were analyzed by the statistical method. The results obtained from this study were summarized as follows: 1.The sample soils used in this study were saline-sodic soils in accordance with the USDA classi- fication system of salt affected soils. 2.The electrical conductivity of saturation extract could be estimated conveniently, using the electrical conductivity of extract from various different soil-water suspensions. 3.The total salt concentration could be expressed in the electrical conductivity, but there was a little difference by soil textures. 4.The regression analysis showed that the relationship between the electrical conductivity of saturation extract and the exchangeable sodium percentage during the desalinization of reclaimed lands could be described by a linear regression equation. 5.The value of pH showed a tendency to increase according as the exchangeable sodium percentage decreased during the desalinization of reclaimed tidelands.

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Study on Change of Thermal Conductivity According to Environmental Conditions (환경 조건에 따른 열전도율 변화에 관한 연구)

  • Seo, Eun-Seok;Kim, Bong-Joo;You, Nam-Gyu;Hong, Sang-Hun;Kim, Han-Nah;Jung, Ui-In
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.66-67
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    • 2019
  • Insulated buildings are exposed to the external environment due to aging and construction problems, resulting in a decrease in building energy efficiency. Therefore, the purpose of this paper is to provide a material for the change in thermal conductivity of the insulation when it is exposed to various external environments. In the experiment, five types of heat insulating materials were selected, stored under different environmental conditions, and the thermal conductivity was measured periodically to confirm the change in thermal conductivity. As a result, the thermal conductivity of all the insulating materials except the PF board increased with the passage of time. This is because thermal insulation absorbs atmospheric moisture under all environmental conditions and the thermal conductivity increases, and in the case of thermal insulation stored indoors in environmental conditions, the temperature differs from the thermal insulation stored outside. It is considered that there is little evaporation of moisture absorbed constantly, and the change in thermal conductivity is large.

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Evaluations of Thermal Diffusivity and Electrochemical Properties for Lithium Hydride and Electrolyte Composites (리튬계 수소화물 전해질 복합막의 열확산 및 전기화학적 특성평가)

  • Hwang, June-Hyeon;Hong, Tae-Whan
    • Korean Journal of Materials Research
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    • v.32 no.10
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    • pp.429-434
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    • 2022
  • There is ongoing research to develop lithium ion batteries as sustainable energy sources. Because of safety problems, solid state batteries, where electrolytes are replaced with solids, are attracting attention. Sulfide electrolytes, with a high ion conductivity of 10-3 S/cm or more, have the highest potential performance, but the price of the main materials is high. This study investigated lithium hydride materials, which offer economic advantages and low density. To analyze the change in ion conductivity in polymer electrolyte composites, PVDF, a representative polymer substance was used at a certain mass ratio. XRD, SEM, and BET were performed for metallurgical analyses of the materials, and ion conductivity was calculated through the EIS method. In addition, thermal conductivity was measured to analyze thermal stability, which is a major parameter of lithium ion batteries. As a result, the ion conductivity of LiH was found to be 10-6 S/cm, and the ion conductivity further decreased as the PVDF ratio increased when the composite was formed.

Effect of Abnormal Grain Growth on Ionic Conductivity in LATP (LATP 내 비정상 입자성장이 이온 전도도에 미치는 영향)

  • Hyungik Choi;Yoonsoo Han
    • Journal of Powder Materials
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    • v.31 no.1
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    • pp.23-29
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    • 2024
  • This study investigates the effect of the microstructure of Li1.3Al0.3Ti1.7(PO4)3 (LATP), a solid electrolyte, on its ionic conductivity. Solid electrolytes, a key component in electrochemical energy storage devices such as batteries, differ from traditional liquid electrolytes by utilizing solid-state ionic conductors. LATP, characterized by its NASICON structure, facilitates rapid lithium-ion movement and exhibits relatively high ionic conductivity, chemical stability, and good electrochemical compatibility. In this study, the microstructure and ionic conductivity of LATP specimens sintered at 850, 900, and 950℃ for various sintering times are analyzed. The results indicate that the changes in the microstructure due to sintering temperature and time significantly affect ionic conductivity. Notably, the specimens sintered at 900℃ for 30 min exhibit high ionic conductivity. This study presents a method to optimize the ionic conductivity of LATP. Additionally, it underscores the need for a deeper understanding of the Li-ion diffusion mechanism and quantitative microstructure analysis.