• Title/Summary/Keyword: conductivity/resistivity

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Investigation of Water Leakage in Seosan A-Region Sea Wall using Integrated Analysis of Remote Sensing, Electrical Resistivity Survey, Electromagnetic Survey, and Borehole Survey (원격탐사, 전기탐사, 전자기탐사 및 시추공영상의 융합적 분석을 통한 서산지역 방조제 누수구역 판별)

  • Hong, Seong-In;Lee, Dongik;Baek, Gwanghyun;Yoo, Youngcheol;Lim, Kookmook;Yu, Jaehyung
    • Economic and Environmental Geology
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    • v.46 no.2
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    • pp.105-121
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    • 2013
  • This study introduces integrated approach on detection of a leakage in a sea wall based on remote sensing, electric resistivity survey, electromagnetic survey, and borehole survey for the Seosan A-Region sea wall. The satellite temperature distribution from Landsat ETM+ data identifies water leakage distribution and period by analyzing temperature mixing patterns between sea water and fresh water. Electric resistivity survey provides both horizontal and vertical anomaly distributions over the sea wall showing below average electric resistivity. Electromagnetic survey(electrical conductivity survey) reveals the potential possible leakage areas with minimal background impact by comparing electrical conductivity values between high and low tides. Borehole image processing system confirmed the locations of anomalies identified from the other survey methods and distributions of vertical fracture zones. The integrated approach identified 41.7% of the sea wall being the most probable area vulnerable to water leakage and effectively approximated both horizontal and vertical distribution of water leakage. The integrated analysis of remote sensing, electric resistivity survey, electromagnetic survey and borehole survey is considered to be an optimal method in identifying water leakage distribution, period, and extent of fractures knowledged from the boreholes.

A Study on the Characteristics of Plasma Blacks Prepared by Plasma Pyrolysis Over Metals Coated Honeycomb Catalysts

  • Park, Soo-Yeop;Lee, Joong-Kee;Yoo, Kyung-Seun;Cho, Won-Ihl;Baek, Young-Soon
    • Carbon letters
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    • v.4 no.2
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    • pp.74-78
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    • 2003
  • Four kinds of plasma blacks were prepared by plasma pyrolysis under various metallic catalysts coated on honeycomb, and investigated the catalytic effect on the characteristics of the plasma blacks prepared under plasma pyrolysis condition. Pt, Pt-Rh, and Pd catalysts were employed as active materials to prepare the plasma blacks. In the experimental range studied, the metallic catalysts influenced on surface area, particle size, surface oxygen content and electrical conductivity of the plasma blacks prepared. It was showed that more dense particle of plasma blacks were prepared under existence of metallic catalysts. Presence of the metallic catalyst reduces the electrical resistivity of plasma blacks due to the decrease in the amount of oxygen functional groups. The highest electrical conductivity of plasma black was observed in the Pt catalyst and then followed by those Pt-Rh, Pd and bare cordierite honeycomb.

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Effects of Plasma Spray Conditions on Photoelectric Properties of Plasma Sprayed $TiO_2$ Semiconductor ($TiO_2$ 반도체 용사피막의 광전극 특성에 미치는 용사조건의 영향)

  • 박정식;박경채
    • Journal of Welding and Joining
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    • v.12 no.1
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    • pp.94-101
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    • 1994
  • In this study, plasma spraying has been used to produce $TiO_2$ polycrystalline coatings from $TiO_2$ powders. The physical and chemical properties of plasma sprayed $TiO_2$ coatings depend greatly on plasma spraying conditions. The electrical resistivity, oxygen concentration, photocurrent and crystal structure of plasma sprayed $TiO_2$ coating has been studied. The results are as follows: 1. The oxygen loss and electrical conductivity of $TiO_2$ plasma sprayed coatings increased by low pressure and high amount of auxiliary gas, hydrogen in plasma spraying. 2. Oxygen loss increase electrical conductivity, and decrease photocurrent of $TiO_2$ plasma sprayed coatings. 3. Photocurrent of $TiO_2$ plasma sprayed coatings manufactured in atmospheric pressure is higher than that of low pressure.

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Experimental evaluation of electrical conductivity of carbon fiber reinforced fly-ash based geopolymer

  • Vaidya, Saiprasad;Allouche, Erez N.
    • Smart Structures and Systems
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    • v.7 no.1
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    • pp.27-40
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    • 2011
  • Geopolymer concrete is finding a growing number of niche applications in the field of civil engineering due to its high compressive strength and strength gain rate, retainage of structural properties in elevated temperature environments, chemical stability in highly acidic conditions and environmental benefits. Combining the above mentioned characteristics with induced electrical conductivity, could enable geopolymer cement to serve as a smart and sustainable cementitious material suitable for health monitoring of civil structures. Carbon fibers were added to fresh geopolymer and OPC (ordinary Portland cement) mixes to enhance their electrical conductivities. AC-impedance spectroscopy analysis was performed on the specimens with fiber fraction ranging from 0.008 to 0.8 with respect to the weight of cementitious binder, to measure their electrical resistivity values and to determine the maximum beneficial fiber content required to attain electrical percolation. Experimental observations suggest that CFR-geopolymer cement exhibits superior performance to CFR-OPC in terms of conducting electrical current.

Conduction Mechanism for PAP and Comparison of Physical Properties of PAP with other Polyaniline-based Conducting Polymers

  • Choi, Kyung-Moon;Lee, Eun-Ju;Kim, Keu-Hong
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.371-376
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    • 1990
  • Polyaniline perchlorate (PAP) was synthesized by the chemical oxidation of aniline using ferric perchlorate as a strong oxidant. The electrical conductivity of PAP was measured at temperatures from - 170 to 25$^{\circ}C$. It is suggested from the conductivity measurements that the conduction mechanism for PAP is a polaron hopping conduction. From the dependence of resistivity on the reciprocal temperature, the activation energy was computed to be 0.072 eV. From the comparison of the ESR parameterks and conductivity at 25$^{\circ}C$ for the polyaniline-based conducting polymers, the conductivities of PAP, PATFB and PATS increase with increasing ${\Delta}H_{pp}$, decreasing A/B ratio and decreasing g-value, respectively. It is shown by TGA results for PAP, PATFB and PATS that the maximum weight loss rates (Pr) are 0.185 (at 269$^{\circ}C$ ), 0.366 (at 324$^{\circ}C$) and 0.23 mg/min (at 338$^{\circ}C$), respectively.

Surface Morphology and Electron Transport Properties of Composite Films by Poly-N-vinylcarbazole/Polyaniline

  • Basavaraja, C.;Jo, Eun-Ae;Kim, Bong-Sung;Mallikarjuna, H.;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2967-2972
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    • 2010
  • Poly-N-vinylcarbazole/polyaniline (PVK-PANI) composites are synthesized by varying target loading concentrations of aniline (0.025 - 0.1 M). The surface morphology of the composites is studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The temperature-dependent DC conductivity of PVK-PANI composite films was studied at the temperature range of 300 - 500 K. The data suggest that the conductivity increase with an increase in aniline concentration in the composite with an increase in temperature. Further based on the conductivity behavior we can suggest that the PVK-PANI composites show a semiconducting behavior with a positive temperature coefficient of resistivity (TCR). The enhanced conductivity and the positive TCR of the PVK-PANI composite films may be due to the strong interaction between PANI and PVK in the composite films.

The Characterization of the Resin Bonded Graphite Composite Bipolar Plate using Isotropic Graphite Powder for PEM Fuel Cell

  • Cho, Kwang-Youn;Riu, Doh-Hyung;Hui, Seung-Hun;Kim, Hong-Suk;Chung, Yoon-Jung;Lim, Yun-Soo
    • Carbon letters
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    • v.8 no.4
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    • pp.326-334
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    • 2007
  • In this study, graphite composites were fabricated by warm press molding method to realize commercialization of PEM fuel cells. Graphite composites have been considered as alternative economic materials for bipolar plate of PEM fuel cells. Graphite powder that enables to provide electrical conductivity was selected as the main substance. The graphite powder was mixed with phenolic resin and the mixture was pressed using a warm press method. First of all, the graphite powder was pulverized with a ball mill for the dense packing of composite. As the ball milling time increases, the average size of particles decreases and the size distribution becomes narrow. This allows for improvement of the uniformity of graphite composite. However, the surface electrical resistivity of graphite composite increases as the ball milling time increases. It is due to that graphite particles with amorphous phase are generated on the surface due to the friction and collision of particles during pulverizing. We found that the contact electrical resistivity of graphite particles increases as the particle size decreases. The contact electrical resistivity of graphite powders was reduced due to high molding pressure by warm press molding. This leads to improvement of the mechanical properties of graphite composite. Hydrogen gas impermeability was measured with the graphite composite, showing a possibility of the application for bipolar plate in fuel cell. And, I-V curves of the graphite composite bipolar plate exhibit a similar performance to the graphite bipolar plate.

Characteristics of Sea Water Intrusion Using Geostatistical Analysis of Geophysical Surveys at the Southeastern Coastal Area of Busan, Korea (지구물리 탐사자료의 지구통계학적 분석에 의한 부산 동남해안 지역의 해수침투 특성)

  • 심병완;정상용;김희준;성익환;김병우
    • Journal of Soil and Groundwater Environment
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    • v.7 no.3
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    • pp.3-17
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    • 2002
  • Data analysis of groundwater monitoring wells and geostatistical methods are used to identify the local characteristics of sea water intrusion and the range of sea water intrusion at the southeastern coastal area of Busan, Korea. Rainfall and groundwater level of two monitoring wells show a linear correlation because of the direct groundwater recharge by the precipitation. However, rainfall and electric conductivity have the inverse relationship because of the increase of groundwater. Electric conductivity rapidly increased at 24m depth and exceeded 20,000$\mu\textrm{s}$/cm near 26m depth in the monitoring wells. The variations of groundwater level and electric conductivity show that the interface between sea water and fresh water tends to move upward when groundwater level goes down. In the cross correlation analysis, groundwater level versus rainfall represents the largest cross correlation coefficient in 0 time lag but the cross correlation coefficient of electric conductivity versus rainfall is the largest when the time lag is 9 days. This suggests that the fluctuations of groundwater level respond to rainfall in a short time, but the interface between sea water and fresh water respond very slow to rainfall. Horizontal extents of sea water intrusion are estimated to 14 m from the east of Line 1, and 25 m from the southeast end of Line 2 in the inversion of dipole-dipole profiling data of two survey lines. The data of VES by the Schulumberger array in May and July show lognormal distributions. In the kriged apparent resistivity and earth resistivity distributions, the resistivities of July are increased comparing to those of May. This reflects that the concentration of sea water in aquifer is reduced due to the increased groundwater recharge from the rainfall in June and July. In analyzing the vertical and horizontal apparent resistivities and earth resistivity distributions, the geostatistical methods are very useful to identify the variations of earth resistivity distributions at the coastal area.

Interpretation of Electrical Resistivity Tomogram with Contents of Clay Minerals for the Land Creeping Area (점토광물 함유량을 고려한 땅밀림 산사태 지역의 전기비저항 자료의 해석)

  • Kim, Jeong-In;Kim, Ji-Soo;Lee, Sun-Joong;Cho, Kyoung-Seo;Kim, Jong-Woo
    • The Journal of Engineering Geology
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    • v.31 no.2
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    • pp.187-197
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    • 2021
  • Clay mineral content of weathered zone is a key parameter for landslide studies. Electrical resistivity tomography is usually performed to delineate the geometry of complex landslides and to identify the sliding surface. In clay-bearing weathered zone, parallel resistivity Archie equation is employed to investigate the effect of conductivity added (resistivity reduced) by clay minerals of kaolinite and montmorillonite, which is dependent on their specific surface area and cation exchange capacities (CEC). A decrease of overall resistivity and apparent formation factor is observed with increasing pore-water resistivity, significantly in montmorillonite. Formation factor is found decreased with increasing porosity and decreasing cementation factor. Parallel Archie equation was applied to the electrical resistivity data from the test area (Sinjindo-ri, Taean-gun, Chungcheongnam-do, Korea) which experienced land creeping in the year of 2014. A panel test with varying clay-mineral contents provides the best fit section when the theoretical section constructed with the assumed contents approaches the field section, from which the clay-mineral content of the weathered zone is estimated to be approximately 10%. Resistivity interpretation schemes including the clay mineral contents for land creeping studies explored in this paper can be challenged more when porosity, saturation, and pore-water resistivity are provided and they are included in the numerical resistivity modeling.

Effect of H2 Addition on the Properties of Transparent Conducting Oxide Films Deposited by Co-sputtering of ITO and AZO (동시 스퍼터링으로 제조한 AZO-ITO 혼합박막의 증착 중 수소 혼입 영향 분석)

  • Kim, Hye-Ri;Kim, Dong-Ho;Lee, Sung-Hun;Lee, Gun-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.42 no.6
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    • pp.267-271
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    • 2009
  • Multicomponent transparent conducting oxide films were deposited on glass substrates at 150 by dual magnetron sputtering of AZO and ITO targets. In the case of mixing a limited amount of ITO (10W), resistivity of TCO films was significantly increased compared to the AZO film; from $3.5{\times}10^{-3}$ to $9.7{\times}10^{-3}{\Omega}{\cdot}cm$. Deterioration of the electrical conductivity is attributed to the decreases in carrier concentration and Hall mobility. Improvement of the conductivity could be obtained for the films prepared with ITO powers larger than 40 W. The lowest resistivity ($\rho$) of $7.3{\times}10^{-4}{\Omega}{\cdot}cm$ was achieved when ITO power was 100 W. Effects of $H_2$ incorporation on the electrical and optical properties of AZO-ITO films were investigated in this work. Addition of small amount of hydrogen resulted in the increase of carrier concentration and the improvement of electrical conductivity. It is apparent that the roughness of AZO-ITO films decreases dramatically after the transition of microstructure from polycrystalline to amorphous phase, which gives practical advantages such as an excellent uniformity of surface and a high etching rate. AZO-ITO films grown at sputtering ambient with hydrogen gas are expected to be applicable to optoelectronic devices such as organic light emitting diodes and flexible displays due to their sufficient electrical and structural properties.