• 제목/요약/키워드: conductive composites

검색결과 229건 처리시간 0.027초

SPS법에 의한 SiC-$ZrB_2$ 복합체의 특성에 미치는 몰드의 영향 (Effects of Mold on Properties of SiC-$ZrB_2$ Composites through SPS)

  • 신용덕;이정훈;박진형;주진영;이희승
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1515-1516
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    • 2011
  • Conductive SiC-$ZrB_2$ composites were produced by subjection a 40:60(vol%) mixture of zirconium diborided ($ZrB_2$) powder and ${\beta}$-silicon carbide (SiC) matrix to spark plasma sintering (SPS) under argon atmosphere. Inner diameters of graphite mold were $15mm{\varphi}$ and $20mm{\varphi}$, respectively. The relative densities of $15mm{\varphi}$ and $20mm{\varphi}$ sample were 99.4% and 97.88%, respectively. Reactions between ${\beta}$-SiC and $ZrB_2$ were not observed via x-ray diffraction (hereafter, XRD) analysis. The result of FE-SEM of fracture face of $15mm{\varphi}$ sample was intergranular fracture and that of $20mm{\varphi}$ sample was transgranular fracture. Because the fracture strength of $15mm{\varphi}$ sample was much higher than that of $20mm{\varphi}$ sample. The electrical resistivity, $9.37{\times}10^{-4}{\Omega}{\cdot}cm$ of $15mm{\varphi}$ sample was higher than that, $6.17{\times}10^{-4}{\Omega}{\cdot}cm$ of $20mm{\varphi}$ sample because of densification. Although sintering condition of SPS is same. the properties of sintered SiC-$ZrB_2$ compacts were changed according to inner diameter of graphite mold.

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샌드위치 구조를 갖는 전자기파 흡수체에 관한 연구 (A Study on Electromagnetic Wave Absorbing Sandwich Structures)

  • 박기연;이상의;김천곤;이인;한재흥
    • 한국항공우주학회지
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    • 제32권6호
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    • pp.64-71
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    • 2004
  • 본 연구의 목표는 X-band 대역 주파수에서의 샌드위치 구조를 갖는 레이더 흡수 구조체 (RAS)를 설계하는 것이다. 면재로는 전도성의 카본블랙을 함유한 유리직물/에폭시 복합재료와 카본직물/에폭시 복합재료를 사용하였다. 심재로는 다중벽의 탄소나노튜브를 함유한 폴리우레탄 폼을 사용하였다. X-band에서의 유전율은 전송선법을 사용하여 측정하였다. 샌드위치 구조에서의 반사손실 특성은 다층을 갖는 구조에서의 투과 반사에 대한 이론을 사용하여 고찰하였다. 그 결과로부터 세 가지 종류의 모델을 선택하고 제작하여 자유공간 기법으로 반사손실을 측정하였다. 이들의 실험결과는 10 dB 흡수 영역의 대역폭은 계산된 결과와 거의 일치하는 경향을 보였다.

음극 전기영동법에 의해 제조된 구리/탄소 나노입자 하이브리드 복합재료의 전기적/기계적 특성 평가 (Electrical and Mechanical Properties of Cu/Carbon Nano-Particle Hybrids Composites by Cathodic Electrophoresis)

  • 이원오;이상복;최오영;이진우;변준형
    • 대한금속재료학회지
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    • 제48권12호
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    • pp.1130-1135
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    • 2010
  • Cu/carbon nano-particle hybrids were fabricated through the cathodic electrophoretic deposition (EPD) process. CNT and CNF nano-particles were modified to give positive charges by polyethyleneimine (PEI) treatment before depositing them on the substrate. Since a Cu plate was used as an anode in the EPD process, Cu particles were also deposited along with the carbon nano-particles. Experimental observation showed the nano-hybrids constructed a novel formicary-like nano-structure which is strong and highly conductive. Utilizing the hybrids, carbon fiber composites were manufactured, and their electrical conductivity and interlaminar shear strength were measured. In addition, the deposition morphology and failure surface were examined by SEM observations. Results demonstrated that the electrical conductivities in the through-the-thickness direction and the interlaminar shear strength significantly increased by 350~2100% and 14%, respectively.

전기적 응용을 위한 바나듐옥사이드 나노선/폴리비닐 알코올 복합체 제작 (Fabrication of $V_2O_5$ Nanowire/PVA (Polyvinyl Alcohol) Composites for the Electric Applications)

  • 이재우;이강호;김규태
    • 전기전자학회논문지
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    • 제13권2호
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    • pp.216-219
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    • 2009
  • $V_2O_5$ 나노선/폴리비닐 알코올(PVA) 고분자 복합체를 나일론 제조법을 응용하여 제작하였고 전기적 특성을 연구하였다. PVA가 아세톤, 에탄올, 메탄올 등의 벤젠기와 반응하여 얇은 막을 형성하는 것을 이용하여 나일론 섬유 제작방법과 유사하게 실타래를 감아올려 나노선 섬유가 섞인 폴리머 섬유를 만들었다. 폴리머-나노선 복합체는 내부에서 전도성이 있는 $V_2O_5$나노선 다발이 네트워크를 형성하기 때문에 전자기장을 차폐할 수 있는 고분자 섬유 등에 적용할 수 있다.

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전자차폐(電磁遮蔽)를 위한 플라스틱 복합재료용(複合材料用) 강화재(强化材)의 성능평가(性能評價) (Performance Evaluation on the Reinforcing Material of Plastic Composites for the Electromagnetic Shielding)

  • 김동진;촌상리일
    • 대한기계학회논문집A
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    • 제23권6호
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    • pp.1048-1054
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    • 1999
  • It is important to study the shielding effectiveness(SE) of reinforcing material of plastic composite materials against the electromagnetic(EM) waves. In this paper, SE of the shielding material of EM waves was investigated with actual experiments. The materials used in this study were made up of film, fiber and powder of conductive materials - Cu, Al, CF etc. Also, The resin film was used as matrix. The experiment was carried out by using a shielding evaluator(Shielding box) TR17302 with an ADVANTEST spectrum analyzer, model R3361C. It was found from the experimental results that copper, aluminum and carbon fiber were good candidates as a shielding material against the EM waves with increasing the SE as the composite was laminated. The characteristics of the SE against the EM waves depended on a mode of preparation of specimen. The effects of interval of wires on the SE were studied when the orientation and the space of Cu wires were changed. The SE strongly depended on the. orientation and the space of the Cu wire. SE decreased as the space of the Cu wires was increasing.

A Study on a Radar Absorbing Structure for Aircraft Leading Edge Application

  • Baek, Sang Min;Lee, Won Jun;Joo, Young Sik
    • International Journal of Aeronautical and Space Sciences
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    • 제18권2호
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    • pp.215-221
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    • 2017
  • An electromagnetic (EM) wave absorber reduces the possibility of radar detection by minimizing the radar cross section (RCS) of structures. In this study, a radar absorbing structure (RAS) was applied to the leading edge of a blended wing body aircraft to reduce RCS in X-band (8.2~12.4GHz) radar. The RAS was composed of a periodic pattern resistive sheet with conductive lossy material and glass-fiber/epoxy composite as a spacer. The applied RAS is a multifunctional composite structure which has both electromagnetic (EM) wave absorbing ability and load-bearing ability. A two dimensional unit absorber was designed first in a flat-plate shape, and then the fabricated leading edge structure incorporating the above RAS was investigated, using simulated and free-space measured reflection loss data from the flat-plate absorber. The leading edge was implemented on the aircraft, and its RCS was measured with respect to various azimuth angles in both polarizations (VV and HH). The RCS reduction effect of the RAS was evaluated in comparison with a leading edge of carbon fabric reinforced plastics (CFRP). The designed leading edge structure was examined through static structural analysis for various aircraft load cases to check structural integrity in terms of margin of safety. The mechanical and structural characteristics of CFRP, RAS and CFRP with RAM structures were also discussed in terms of their weight.

탄소나노튜브 강화 나노복합재료의 연구현황 (Research Status on the Carbon Nanotube Reinforced Nanocomposite)

  • 차승일;김경태;이경호;모찬빈;홍순형
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.25-28
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    • 2003
  • Carbon nanotubes(CNTs), since their first discovery, have been considered as new promising materials in various fields of applications including field emission displays, memory devices, electrodes, NEMS constituents, hydrogen storages and reinforcements in composites due to their extra-ordinary properties. The carbon nanotube reinforced nanocomposites have attracted attention owing to their outstanding mechanical and electrical properties and are expected to overcome the limit of conventional materials. Various application areas are possible for carbon nanotube reinforced nanocomposites through the functionalization of carbon nanotubes. Carbon nanotube reinforced polymer matrix nanocomposites have been fabricated by liquid phase process including surface functionalization and dispersion of CNTs within organic solvent. In case of carbon nanotube reinforced polymer matrix nanocomposites, the mechanical strength and electrical conducting can be improved by more than an order of magnitude. The carbon nanotube reinforced polymer matrix nanocomposites can be applied to high strength polymers, conductive polymers, optical limiters and EMI materials. In spite of successful development of carbon nanotube reinforced polymer matrix nanocomposites, the researches on carbon nanotube reinforced inorganic matrix nanocomposites show limitations due to a difficulty in homogeneous distribution of carbon nanotubes within inorganic matrix. Therefore, the enhancement of carbon nanotube reinforced inorganic nanocomposites is under investigation to maximize the excellent properties of carbon nanotubes. To overcome the current limitations, novel processes, including intensive milling process, sol-gel process, in-situ process and spark plasma sintering of nanocomposite powders are being investigated. In this presentation, current research status on carbon nanotube reinforced nanocomposites with various matrices are reviewed.

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EVA/Acetylene Black 복합체의 동역학적 점탄성 분석 (A Study on the Dynamic Viscoelasticity of EVA/Acetylene Black Composites)

  • 이경용;양종석;최용성;남종철;성백룡;박동하;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.140-141
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    • 2005
  • To measure elastic properties of semiconducting materials in power cable, we have investigated modulus of EVA/acetylene black composite showed by changing the content of acetylene black. The specimen was primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then this was produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive acetylene black were 20, 30 and 40[wt%], respectively. The modulus experiment was measured by DMA 2980. The ranges of measurement temperature were from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency is 1[Hz]. The modulus of specimens was increased according to an increment of acetylene black content. And modulus was rapidly decreased at the glass transition temperature. The tan$\delta$ of specimens was decreased according to an increment of acetylene black content.

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온도 변화에 따른 EBA/카본블랙 복합체의 점탄성 특성에 관한 연구 (Study on the viscoelasticity properties of EBA/Carbon Black composites by temperature changes)

  • 양종석;이경용;최용성;남종철;박동하;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.136-137
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    • 2005
  • To measure elastic properties of semiconducting materials in power cable, we have investigated modulus of EBA/carbon black composite showed by changing the content of carbon black. The specimen was primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then this was produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive carbon black were 20, 30 and 40[wt%], respectively. The modulus experiment was measured by DMA 2980. The ranges of measurement temperature were from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency is 1 [Hz]. The modulus of specimens was increased according to an increment of carbon black content And modulus was rapidly decreased at the glass transition temperature. The tan$\delta$ of specimens was decreased according to an increment of carbon black content.

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Microwave Absorbance of Polymer Composites Containing SiC Fibers Coated with Ni-Fe Thin Films

  • Liu, Tian;Kim, Sung-Soo;Choi, Woo-cheal;Yoon, Byungil
    • 한국분말재료학회지
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    • 제25권5호
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    • pp.375-378
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    • 2018
  • Conductive and dielectric SiC are fabricated using electroless plating of Ni-Fe films on SiC chopped fibers to obtain lightweight and high-strength microwave absorbers. The electroless plating of Ni-Fe films is achieved using a two-step process of surface sensitizing and metal plating. The complex permeability and permittivity are measured for the composite specimens with the metalized SiC chopped fibers dispersed in a silicone rubber matrix. The original non-coated SiC fibers exhibit considerable dielectric losses. The complex permeability spectrum does not change significantly with the Ni-Fe coating. Moreover, dielectric constant is sensitively increased with Ni-Fe coating, owing to the increase of the space charge polarization. The improvements in absorption capability (lower reflection loss and small matching thickness) are evident with Ni-Fe coating on SiC fibers. For the composite SiC fibers coated with Ni-Fe thin films, a -35 dB reflection loss is predicted at 7.6 GHz with a matching thickness of 4 mm.