• 복합신소재구조학회 논문집
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• 제6권2호
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• pp.63-69
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• 2015

It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.409-412
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• 2000

Many researchers have been trying to evaluate the diffusion coefficient of chloride ion in concrete by using qualitative and quantitative electro-migration tests. Up to now, however, there has been no sufficient method to closely determine the diffusion coefficient of chloride ion through electro-migration test. In this paper, the diffusion coefficient of chloride ion in concrete was investigated through an electro-migration test, that is, AASHTO T 277, Dhir's method, Tang's method and Andrade's method. And the results of these test were compared with each other.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계학술발표회 논문집(I)
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• pp.594-597
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• 2006

Chloride ion penetration and carbonation are the most important factors in the durability problems of reinforced concrete structures. Most of the existing studies on those subjects are focused on the no-crack concrete, though the existence of crack may strongly affect the chloride ion penetration and carbonation. To evaluate the influence of crack on the chloride ion penetration and carbonation and to assess the service life of reinforced concrete more accurately, finite volume analyses (FVA) were performed based on the FV mesh containing the ideal crack whose width is uniform along the depth. Analytical results show that the influence of crack width and depth is much more pronounced for the chloride ion penetration than for the carbonation.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.297-300
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• 2003

A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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• pp.25-26
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• 2018

In this study, the device was developed for evaluating the effect of pressure on chloride ion penetration of concrete. And chloride-ion penetration depth and water soluble chloride contents was evaluated concrete using ordinary portland cement and blast-furnace slag cement using developed device. As a result, chloride ion penetration of concrete was promoted according to the action of pressure and the exposure period. and the incorporation of blast-furnace slag was effective for chloride attack resistibility under pressure.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 추계 학술논문 발표대회
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• pp.11-12
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• 2017

The properties of concrete produced by ready mixed concrete company in Busan were tested. Because the concrete was mixed with blast furnace slag and fly ash, the compressive strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design.

• 한국해양공학회지
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• 제14권4호
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• pp.23-29
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• 2000

When the concrete structures were being made with sand containing chloride ion it was knows that corrosion rate of reinforced steel embedded in concrete with chloride ion was higher than that of concrete with on chloride ion. In this study, the operation of Friedel salts affecting the corrosion behavior of reinforced steel embedded in cement mortar was investigated with electrochemical view. Corrosion potential of reinforced steel embedded in cement mortar with sand containing chloride ion was shifted noble direction than that of cement mortar with no chloride ion after immersed 5 month in natural sea water and also corrosion current density decreased with shifting corrosion potential to noble direction. However Friedel salts appeared from surface to 2.5cm of inside direction of mortar specimen, which is located at 11.5$\circ$(2$\theta$) in XRD analysis and the amount of Ca(OH)2 by SEM photograph in cement mortar with chloride ion was larger than that of cement mortar with mo chloride ion. Eventually it is suggested that Friedel salts was resulted from chloride ion and it acted as the corrosion inhibitor.

• Advances in concrete construction
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• 제14권3호
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• pp.205-214
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• 2022

Due to seawater's physical and chemical deterioration effects on concrete structures, it is crucial to investigate the durability of these structures in marine environments. In some conditions, concrete structures are exposed to seawater from the first days of construction or because of the lack of potable water, part of the concrete curing stage is done with seawater. In this research, the effects of exposure to seawater after 7 days of curing in standard conditions were evaluated. To improve the durability of concrete, fly ash has been used as a substitute for a part of the cement in the mixing design. For this purpose, 5, 15, and 30% of the mixing design cement were replaced with type F fly ash, and the samples were examined after curing in seawater. The resistance of concrete against chloride ion penetration based on the rapid chloride penetration test (RCPT), water permeability based on the depth of water penetration under pressure, and water absorption test was done. The changes in the compressive strength of concrete in different curing conditions were also investigated. The results show that the curing in seawater has slightly reduced concrete resistance to chloride ion permeation. In the long-term, samples containing FA cured in seawater had up to 10% less resistance to chloride ion penetration. The amount of reduction in chloride ion penetration resistance was more for samples without FA. Whiles, for both curing conditions in the long-term up to 15%, FA improved the chloride ion penetration resistance up to 40%. Curing in seawater slightly increased the penetration depth of water under pressure in samples containing FA, while this increase was up to 12% for samples without FA. In the long-term the compressive strength of samples cured in seawater is not much different from the compressive strength of samples cured in plain water, while at the age of 28 days, due to seawater salts' accelerating effects the difference is more noticeable.

• Computers and Concrete
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• 제33권1호
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• pp.1-11
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• 2024

Aggressive environmental conditions, and especially the acidic effects of sulfate ion penetration, have reduced the lifetime of concrete structures in some areas, especially coastal and marine areas. In this research, at first, samples made of type II and V cement were kept in a solution of magnesium sulfate (MgSO₄) for a period of 90 and 180 days, the change of appearance. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD), were used to analyze the microstructure and the complex mineral composition of the concrete after exposure to corrosive environments. Then solving the differential equation governing the sulfate ion penetration, which is based on the second Fick law, it has been tried to determine the concentration of sulfate ions inside the concrete. In the following, an attempt has been made to improve the prediction of sulfate ion concentration in concrete by using Crank's penetration equation. At the same time, the coefficient in the Crank's solution have been optimized by using the Particle Swarm Optimization (PSO algorithm). The comparison between the results shows that the values obtained from Crank's relation are closer to the experimental results than the equation obtained from Fick's second law and shows a more accurate prediction.

• 한국농공학회지
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• 제41권6호
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• pp.82-89
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• 1999

This paper present the strength estimation of precast concrete products by chloride ion penetration method. The relation between the strength of precast concrete product and the ion passing charge is linear and a numerical model of FCK =515.96-0.201Q is prposed. The results showe good agreement at about 9.0% error ration with the estimated model results for real precast concrete product.