• Title/Summary/Keyword: concrete durability.

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Durability of Polymer-Modified Mortars Using Acrylic Latexes with Methyl Methacrylate (MMA계 아크릴 라텍스를 혼입한 폴리머시멘트 모르타르의 내구성)

  • Hyung Won-Gil;Kim Wan-Ki;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.411-418
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    • 2005
  • Polymer-modified mortar and concrete are prepared by mixing either a polymer or monomer in a dispersed, or liquid form with fresh cement mortar and concrete mixtures, and subsequently curing, and if necessary, the monomer contained in the mortar or concrete is polymerized in situ. Although polymers and monomers in any form such as latexes, water-soluble polymers, liquid resins, and monomers are used in cement composites such as mortar and concrete, it is very important that both cement hydration and polymer phase formation proceed well the yield a monolithic matrix phase with a network structure in which the hydrated cement phase and polymer phase interpenetrate. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete. The purpose of this study is to obtain the necessary basic data to develope appropriate latexes as cement modifiers, and to clarify the effects of the monomer ratios and amount of emulsifier on the properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate(MMA/BA) and methyl methacrylate-ethyl acrylate(MMA/EA) latexes. The results of this study are as follows, the water absorption, chloride ion penetration depth and carbonation depth of MMA/BA-modified mortar are lowest. However, they are greatly affected by the polymer-cement ratio rather than the bound MMA content and type of polymer.

The Experimental Study on the Heat Hydration Properties of Concrete According to Binder Conditions (결합재 조건에 따른 콘크리트의 수화발열 특성에 관한 연구)

  • Choi, Sung-Woo;Jo, Hyun-Tae;Ryu, Deuk-Hyun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.769-776
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    • 2006
  • Recently, owing to the development of industry and the improvement of building techniques, concrete structures are becoming larger and higher. In hardening of these large connote structures, the heat of hydration gives rise to considerable thermal stress depending on the size and environmental condition of concrete, which might cause thermal cracking. Especially, the crack may cause severe damage to the safety and the durability of concrete structure. This study investigates the thermal properties of concrete according to several binder conditions, such as OPC, Belite rich cement(BRC), slag cement(SC), blast furnace slag(B) added cement fly ash(F) added cement and blast-furnace-slag and fly ash added cement. As a result of this study, the properly of concrete is most better BRC than others, and fly ash(25%) added cement and BFS(35%)-fly ash(15%) added cement gets superior effect in the control of heat hydration. But synthetically considered properties of concrete, workablity, strength heat hydration, etc, it is more effective to use mineral admixture. Especially, to be used Blast Furnace slag is more effective.

Performance Evaluation of Recycled Aggregate Concrete Made of Recycled Aggregate Modified by Carbonation (탄산화 개질 순환 골재를 사용한 순환 골재 콘크리트의 성능 평가)

  • Ha, Jung-Soo;Shin, Jin-Hak;Chung, Lan;Kim, Han-Sic
    • Journal of the Korea Concrete Institute
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    • v.28 no.4
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    • pp.445-454
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    • 2016
  • With the increase of decrepit facilities, construction waste increased to a certain level and now the increase is more or less stabilized. Yet construction waste still constitutes the largest portion of the overall wastes. Also, it is inevitable to spend a huge amount of the national budget due to the aggravating shortage of aggregate caused by prohibition on collection of natural aggregates as well as due to the damage to the land and environment caused by development of the sources of aggregates. As a countermeasure to the situation, the Ministry of Land, Infrastructure and Transport promulgated the quality standard for recycled aggregate to manage the usage of recycled aggregate according to its quality. But use of recycled aggregate for the purpose of high added value still remains nominal. Therefore, this research aims to study the applicability of recycled aggregate concrete as structural concrete by evaluating the quality improvement effects and the performance of the recycled aggregate concrete including recycled fine aggregate and recycled coarse aggregate that have undergone carbonation for 4 days and 14 days respectively in the condition of 60% RH, 20% $CO_2$ and $20^{\circ}C$ temperature, suggested for carbonation modifying from the advance research. The result shows carbonation modify contributed to quality improvement with 0.91% decrease in absorption rate for recycled fine aggregate and 0.7% decrease in absorption rate for recycled coarse aggregate. The physical properties and durability of the recycled aggregate made of aggregate modified by carbonation showed results similar to general concrete, which confirmed the possibility of applying the recycled aggregate made of recycled aggregate modified by carbonation to structural concrete.

Theoretical Analysis of Critical Chloride Content in (Non)Carbonated Concrete Based on Characteristics of Hydration of Cement (시멘트 수화 특성 및 탄산화를 고려한 콘크리트의 임계 염소이온량에 대한 해석 기법)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.367-375
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    • 2007
  • Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.

Surface Properties of Color Concrete Using Acid Stained Agent (표면 착색용 산화제를 사용한 컬러 콘크리트의 표면 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Park, Hyo-Jin
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.265-272
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    • 2011
  • Even though concrete is the most important material for building structures, its intrinsic gray color degrades urban esthetics. In order to improve this problem, coloring methods of mixing pigment in concrete batch and painting the surface of concrete surface have been tried. However, applications of the coloring methods in construction field are difficult due to high cost and low durability. Recently, acid stain agent is emerging as a new coloring method for concrete. It is able to apply a remarkably thin colored layer on a concrete surface from chemical reaction between acid and alkaline solutions. This study has examined the changes and variations of the surface layer of mortar specimen from chemical reaction of acid stained agents. The colors were changed into natural irregular stains according to aging. After the staining, no shape change was found from visible inspections. Microstructure of the colored surface applied with acid stained agent was much rougher than that of original mortar. When the colored layer was compared to original surface, crystals of hydrate such as $Ca(OH)_2$ and C-S-H gel were observed. Surface hardness was same or slightly higher in the colored layer. The value of pH was reduced by approximately 10%, weight contents of elements such as Ca, Si, and Al were low. In the chemical composition of the colored layer, the non-cement based elements of Mn, Cr, and Cu increased. Also, Fe and alkali elements of K and Na increased.

Fundamental Properties of Fly ash Concrete Containing Lightly Burnt MgO Powder (저온 소성한 MgO 분말을 함유한 플라이애시 콘크리트의 기본 물성)

  • Choi, Seul-Woo;Jang, Bong-Seok;Lee, Kwang-Myong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.2
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    • pp.475-481
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    • 2013
  • Although the lightly burnt MgO at $850{\sim}1000^{\circ}C$ has expansibility, it does not lead to unsound concrete. The expansion of MgO could compensate for shrinkage of concrete for a long-term, because the hydration of MgO occurs at a slow pace. Recently, the study and application of mineral admixture such as fly ash and blast furnace slag have increased for the hydration heat reduction, durability improvement, and reducing $CO_2$ emission in the construction industry. Thus, it is necessary to research on the concrete that contains both a mineral admixture and MgO as an expansion agent. This study investigates fundamental properties of fly ash concrete with lightly burnt MgO through various experiments. The adiabatic temperature test results showed that the fly ash concrete with MgO of the 5% replacement ratio had the slower pace of the temperature rise and the lower final temperature than the fly ash concrete. The influences of MgO on long-term compressive strength varied depending on water-binder ratio, and the long-term length change test results indicated the expansion effects of the FA concrete containing MgO.

Mechanical Properties of Porous Concrete For Pavement Using Recycled Aggregate and Polymer (재생골재와 폴리머를 이용한 포장용 포러스 콘크리트의 역학적 특성)

  • Park Seung-Bum;Yoon Eui-Sik;Seo Dae-Seuk;Lee Jun
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.595-602
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    • 2005
  • The purpose of this study is to utilize recycled concrete aggregates as permeable pavement materials. This study evaluates mechanical properties and durability of porous concrete depending on mixing rates of recycled aggregates and polyme. As a result, void ratio and permeability coefficient of porous concrete for pavement increased a little as mixing rate of recycled aggregates increased. Void ratio and permeability coefficient increased a lot as mixing rate of polymer increased. As polymer was mixed $20\%$, national regulation of permeable concrete for pavement($8\%$ and 0.01cm/sec) was met. Compressive strength and flexural strength decreased as mixing rate of recycled aggregates increased but they increased a lot as mixing rate of polymer increased. Even when recycled aggregates were mixed $75\%\;with\;10\%$ polymer mixed, national regulation of pavement concrete(18MPa and 4.5MPa) was met. In addition, regarding sliding resistance, BPN increased as mixing rate of recycled aggregates increased. But BPN decreased as polymer was mixed. Compared to crushed stone aggregates, abrasion resistance and freeze-thaw resistance decreased as mixing rate of recycled aggregates Increased. When polymer was mixed, abrasion resistance and freeze-thaw resistance improved remarkably. Compared to non-mixture, $10\%$ mixture of polymer improved abrasion resistance and freeze-thaw resistance about $8.6\%$ and 3.8times respectively.

Resistance In Chloride ion Penetration and Pore Structure of Concrete Containing Pozzolanic Admixtures (포졸란재 함유 콘크리트의 세공구조와 염화물이온 침투 저항성)

  • 소양섭;소형석
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.100-109
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    • 2002
  • Significant damage to concrete results from the intrusion of corrosive solutions, for example, dissolved chlorides corrode reinforcing steel and cause spatting. Effectively blocks the penetration of these solutions will eliminate or greatly reduce this damage and lead to increased durability. This study is to investigate the effects of pozzolanic admixtures, fly ash and silica fume, and a blast furnace slag on the chloride ion penetration of concretes. The main experimental variables wore the water-cementitious material ratios, the types and amount of admixtures, and the curing time. And it is tested for the porosity and pore size distributions of cement paste, chloride ion permeability based on electrical conductance, and 180-day ponding test for chloride intrusion. The results show that the resistance of concrete to the penetration of chloride ions increases as the w/c was decreased, and the increasing of curing time. Also, concrete with pozzolans exhibited higher resistance to chloride ion penetration than the plain concrete. The significant reduction in chloride ion permeability(charge passed) of concrete with pozzolans due to formation of a discontinuous macro-pore system which inhibits flow. It is shown that there is a relationship between chloride ion permeability and depth of chloride ion penetration of concrete, based on the pore structure (porosity and pore size distributions) of cement paste.

Analysis of Chloride Ion Penetration Properties into Concrete on Road Facilities Depending on the Deterioration Environments (국도 상 도로시설물 대상 열화환경 조건 별 콘크리트 염화물 침투 특성 분석)

  • Min, Jiyoung;Lee, Jong-Suk;Lee, Tack-gon;Cha, Ki-Hyuk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.102-113
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    • 2021
  • The deterioration environments caused by de-icing salt and airborne chlorides in the seashore, evaluated in the "Detailed guideline for safety and management practice of facilities (performance evaluation)", were reviewed in terms of penetrated chlorides into concrete on various road facilities. Target concrete structures, in this study, were 4 concrete barriers in Gangwon area, 3 concrete barriers and 1 retaining wall in Busan area, and 4 bridges in Gangwon-do, Seoul, Gyeonggi-do, and Busan. The deterioration environments were classified into three categories: direct and indirect de-icing salt attack, and airborne salt attack depending on the distance to seashore and the height of pier, and the penetrated chlorides in to concrete were analyzed. The results showed that (1) the regional deterioration environments were clearly classified by de-icing salt sprayed days (snowfall days), (2) the penetrated chlorides increased significantly when leakage occurred through slabs or expansion joints, and (3) the airborne chlorides affected to a height of 20 m concrete in the seashore, Busan. From these, it could be confirmed that the chloride ion penetration properties depend on the exposed aging environment, member location and height, and deterioration status, even on the same structure, so the selection of target members and location is very important in the inspection and maintenance. If the database of penetrated chlorides properties in various deterioration environments is constructed, it is expected that the proactive durability management on concrete structures will be possible in the field.

Analysis of Failure Behavior of FRP Rebar Reinforced Concrete Slab based on FRP Reinforced Ratio (FRP 보강근비에 따른 FRP 보강 콘크리트 슬래브의 파괴거동 분석)

  • Jang, Nag-Seop;Kim, Young-Hwan;Oh, Hong-Seob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.173-181
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    • 2021
  • Reinforced concrete structures are exposed to various environments, resulting in reinforcement corrosion due to moisture and ions penetration. Reinforced concrete corrosion causes a decrease in the durability performance of reinforced concrete structures. One solution to mitigate such issues is using FRP rebars, which offer several advantages such as high tensile strength, corrosion resistance, and light-weight than conventional rebars, in reinforced concrete instead of conventional steel rebars. The FRP rebar used should be examined at the limit state because FRP reinforced concrete has linear behavior until its fracture and can generate excessive deflection due to the low elastic modulus. It should be considered while designing FRP reinforced concrete for flexure. In the ultimate limit state, the flexural strength of FRP reinforced concrete as per ACI 440.1R is significantly lower than the flexural strength by applying both the environmental reduction and strength reduction factors accounting for the material uncertainty of FRP rebar. Therefore, in this study, the experimental results were compared with the deflection of the proposed effective moment of inertia referring to the local and international standards. The experimental results of GFRP and BFRP reinforced concrete were compared with the flexural strength as determined by ACI 440.1R and Fib bulletin 40. The flexural strength obtained by the experimental results was more similar to that obtained by Fib bulletin 40 than ACI 440.1R. The flexural strength of ACI 440.1R was conservatively evaluated in the tension-controlled section.