• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.101-102
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• 2022

A new hydrazone derivatives namely (E)-N'-(4-(dimethylamino)benzylidene)-2-(5-methoxy-2-methyl-1H-indol-3-yl)acetohydrazide (HIND) has been confirmed for mitigating the corrosion of the steel rebar exposed to chloride contaminated synthetic concrete pore solution (ClSCPS). The mitigation of corrosion properties has been characterized by weight loss and electrochemical methods (Electrochemical impedance, Potentiodynamic polarization studies) as well as surface observations. The presence of HIND in the ClSCPS decreased the corrosion of steel rebar by adsorption of HIND molecules on the surface of the steel rebar. The optimal HIND concentration was 0.5 mmol/L, corresponding to an inhibition efficiency of 88.4%. The use of HIND enables the corrosion process to have a higher energy barrier. X-ray photo electron spectroscopy (XPS), atomic force microscopy (AFM), scanning electron microscopy-energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) spectroscopy interpretations confirmed that HIND mitigates the corrosion attack on the surface steel rebar.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.59-60
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• 2023

The corrosion of steel rebar embedded in the coastal areas is corroding once the chloride ions ingress through the pores of the concrete. Therefore, in the present study, a 100 ㎛ thick Al and Zn coating was deposited by an arc thermal spray process onto the steel. The corrosion studies of these deposited coatings were assessed in 3.5 wt.% NaCl contaminated concrete pore (CP) solution with immersion periods. The results show that the Al coating is more corrosion resistance compared to the Zn coating attributed to the formation of gibbsite (γ-Al(OH)₃) whereas Zn coating exhibits Zn(OH)₂ onto the coating surface as passive layer. The Zn(OH)₂ is readily soluble in an alkaline solution. Alternatively, γ-Al(OH)₃ on the Al coating surface is less solubility in the alkaline pH, which further provides barrier protection against corrosion.

• The Journal of Engineering Geology
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• v.26 no.1
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• pp.79-85
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• 2016

A concrete silo plays an important role in subsurface low- and intermediate-level waste facilities (LILW) by limiting the release of radionuclides from the silo geosphere. However, due to several physical and chemical processes the performance of the concrete structure decreases over time and consequently the concrete loses its effectiveness as a barrier against groundwater inflow and the release of radionuclides. Although a number of processes are responsible for degradation of the silo concrete, it is determined that the main cause is corrosion of the reinforcing steel. Therefore, the time it takes for the silo concrete to fail is calculated based on two factors: the initiation time of corrosion, defined as the time it takes for chloride ions to penetrate through the concrete cover, and the propagation time of corrosion. This paper aims to estimate the time taken for concrete to fail in a LILW disposal facility. Based on the United States Department of Energy (DOE) approach, which indicates that concrete fails completely once 50% of the volume of the reinforcing steel corrodes, the corrosion propagation time is calculated to be 640 years, which is the time it takes for corrosion to penetrate 0.640 cm into the reinforcing steel. In addition to the corrosion propagation time, a diffusion equation is used to calculate the initiation time of corrosion, yielding a time of 1284 years, which post-dates the closure time of the LILW disposal facility if we also consider the 640 years of corrosion propagation. The electrochemical conditions of the passive rebar surface were modified using an acceleration method. This is a useful approach because it can reduce the test time significantly by accelerating the transport of chlorides. Using instrumental analysis, the physicochemical properties of corrosion products were determined, thereby confirming that corrosion occurred, although we did not observe significant cracks in, or expansion of, the concrete. These results are consistent with those of Smartet al., 2006 who reported that corrosion products are easily compressed, meaning that cracks cannot be discerned by eye. Therefore, it is worth noting that rebar corrosion does not strongly influence the hydraulic conductivity of the concrete.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.4
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• pp.2414-2418
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• 2014

This study carried out three-dimensional finite element analysis and structural safety evaluation of attachable roadside barriers. The effects of diaphragm distance and the number of bolts on displacements and maximum stresses for various parameters are studied using the LS-DYNA finite element program for this study. In this study, the existing finite element analysis of barriers using the LS-DYNA program is further extended to study static behaviors and structural safety of the barrier with module structures connected by anchor bolt inserted through concrete bridge decks. The numerical results for six parameters are verified by comparing different models with displacements and stress distribution occurred in the barrier and shows good structural performance.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.20 no.9
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• pp.791-796
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• 2010

Installing noise barriers is the most common method for reducing the highway traffic noise to the road side residential area. After the report about edge potential concept of a noise barrier, various types of noise reducing devices(NRDs) called "noise reducers" have been suggested for getting more shielding effect on the top of highway noise barriers. But, it has been doubtful about effect of the NRDs in field because there was no appropriate and unified method to estimate the acoustic performance by using field measurement of the NRDs in Korea. In this study, the authors have considered to setup a practical method to test and estimate the acoustic performance of NRDs. For eliminating the noise reduction effect of the NRDs height itself, the source and measuring points are adjusted as highly as the NRDs height. For the frequency weighting in the estimation of the NRDs effect, the highway noise spectra were measured at asphalt and concrete road side and then averaged for a unit spectral parameter.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.1
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• pp.35-44
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• 2008

Long-term degradation of coment barrier by diffusion was studied with reactive transport modeling. The result of modeling showed that cement barrier was altered about 30cm thickness after 50,000 years. The pH decreased from 13.0 to 11.9 because of depletion of alkali ions, and dissolution/precipitation of portlandite and CSH (Calcium Silicate Hydrate). In addition, porosity increased about 0.3 because of dissolution of portlandite and $CSH2.0(Ca_2SiO_3(OH)_2:0.17H_2O)$. The solubility of uranium also increased with the increase of pe value The results of this study indicate that long-term degradation of comet can enhance the transport of nuclide by changing pH, pe, porosity in barrier.

• Tunnel and Underground Space
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• v.16 no.3 s.62
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• pp.241-250
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• 2006

Ice ring formation, one of the core techniques in LNG storage in a lined rock cavern, is investigated through hydro-thermal coupled analysis. An ice ring acts as a secondary barrier in case of leakage of cryogenic liquid and as a primary barrier for groundwater intrusion into an LNG cavern. Therefore, the thickness and location of the ice ring are crucial factors for the safe operation of an LNG storage cavern, especially for maintaining the integrity of a primary barrier composed of concrete, PU foam, and steel membrane. Through numerical analyses, the position and thickness of the ice ring are estimated, and the temperature and groundwater level are compared with measured values. The temperature md groundwater level by numerical analyses show good agreement with the field measurements when temperature-dependent properties and phase change are taken into account. The schemes used in this paper can be applied for estimation of ice ring formation in designing a full-scale LNG cavern.

• Journal of Environmental Impact Assessment
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• v.28 no.4
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• pp.387-399
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• 2019

This research aimed to prepare the classification of the damage types and the damage rating system of noise barriers for expressway noise barriers and to develop deterioration evaluation method of noise barriers by reflecting them. The noise barrier consists of soundproof panels, foundations and posts and the soundproof panels with 10 different types of materials are used in a single or mixed form.In this paper, damage of soundproof panel shows a single or composite damage, and thus a evaluation model of deterioration has been developed for noise barriers that can reflect the characteristic of noise barriers. Materials used mainly for soundproof walls were divided into material types for metal, plastic, timber, transparent and concrete. And damage types for noise barrier were classified into corrosion, discoloration, deformation, spalling and dislocation and damage types were subdivided according to the noise barrier's components and materials. Damage rating was divided into good, minor, normal and severe for each major part of noise barrier to assess damage rating of soundproof panel, foundation and post. The deterioration degree of noise barrier was evaluated comprehensively by using the deterioration evaluation method of whole noise barrier using weighted average. Deterioration evaluation method that can be systematically assessed has been developed for noise barrier using single or mixed soundproof panel and noise barrier with single or complex damage types. Through such an evaluation system, it is deemed that the deterioration status of noise barrier installed can be systematically understood and utilized for efficient maintenance planning and implementation for repair and improvement of noise barriers.

• Journal of the Korea Concrete Institute
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• v.20 no.5
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• pp.653-660
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• 2008

The purpose of this study is to analyze the optimal mix design of the sound absorption material that is made from perlite and various binder systems for noise barrier wall. The polymer cement slurry which is made from two types of polymer dispersions, and silicone type inorganic material are used as binder. The test specimens are prepared with various polymer cement ratios, binder ratios, and tested for strengths, freezing and thawing and sound absorption performance by the tube and the reverberation room methods. From the test results, the difference of sound absorption coefficient by the tube method is a little recognized, however, noise reduction coefficient (NRC) of test specimens bound by the polymer cement slurry is in the ranges of 0.48 to 0.51. They are a little higher than those bound by cement only, and are lower values than recommended value of 0.7 by the Ministry of Environment. However, the sound absorption coefficient of test specimens at low frequency range of 250 to 500 Hz by reverberation room method shows very high values as 0.84 to 1.00, and 0.57 to 0.77 at the high frequency. The test specimens with polymer cement slurry binder have a good balance between performance and cost, and have proper properties in strengths, freezing and thawing resistance as sound absorption material for noise barrier wall. It is apparent that the good sound absorption material can be produced according to the optimum mix design that is recommended from this study.

• Earthquakes and Structures
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• v.15 no.3
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• pp.295-306
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• 2018

Reinforced concrete containment (RCC) building has long been considered as the last barrier for keeping the radiation from leaking into the environment. It is important to quantify the performance of these structures and facilities considering extreme conditions. However, the preceding research on evaluating nuclear power plant (NPP) structures, particularly considering mainshock-aftershock seismic sequences, is deficient. Therefore, this manuscript serves to investigate the seismic fragility of a typical RCC building subjected to mainshock-aftershock seismic sequences. The implementation of the fragility assessment has been performed based on the incremental dynamic analysis (IDA) method. A lumped mass RCC model considering the tri-linear skeleton curve and the maximum point-oriented hysteretic rule is employed for IDA analyses. The results indicate that the seismic capacity of the RCC building would be overestimated without taking into account the mainshock-aftershock effects. It is also found that the seismic capacity of the RCC building decreases with the increase of the relative intensity of aftershock ground motions to mainshock ground motions. In addition, the effects of artificial mainshock-aftershock ground motions generated from the repeated and randomized approaches and the polarity of the aftershock with respect to the mainshock on the evaluation of the RCC are also researched, respectively.