• Title/Summary/Keyword: concentration reduction

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A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

NO Reduction and Oxidation over PAN based-ACF

  • Kim, Je-Young;Lee, Jong-Gyu;Hong, Ik-Pyo
    • Carbon letters
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    • v.1 no.1
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    • pp.17-21
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    • 2000
  • Catalytic reduction and oxidation of NO over polyacrylonitrile based activated carbon fibers (PAN-ACF) under various conditions were carried out to develop removal process of NO from the flue gas. The effect of temperature, oxygen concentration and the moisture content for the reduction of NO with ammonia as a reducing agent was investigated. The reduction of NO increased with the oxygen concentration, but decreased with the increased temperature. The moisture content in the flue gas affects the reduction of NO as the inhibition of the adsorption of the other components and the reaction on the surface of ACE For the oxidation of NO to $NO_2$ over PAN-ACF without using a reducing gas, it showed the temperature and the oxygen concentration of the flue gas are the important factors for the NO conversion in which the conversion increased with oxygen concentration and decreased with the temperature increase and might be the alternative option for the selective catalytic reduction process.

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The Degumming and Sericin Recovery of the Silk fabric Using the Electrolytic Water(II) (전해수를 이용한 견섬유 정련 및 세리신 회수(II)-분리막에 의한 세리신 농축을 중심으로-)

  • 배기서;이태상;노덕길;홍영기
    • Textile Coloration and Finishing
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    • v.16 no.4
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    • pp.10-18
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    • 2004
  • In this work, Aqueous sericin solution was prepared by degumming process with electrolytic reduction water. Then, the microfiltration and ultrafiltration systems were applied to the concentration of aqueous sericin solution. The objective of this study was to select the optimum operating condition among the different pressure. The permeate flux and rejection ratio were observed with time, pressure, flow rate and concentration. and, the wastewater and permeated water quality values such as pH, BOD, COD, and NH levels were measured. In order to see the influence of electrolytic reduction water, the flux of pure water and electrolytic reduction water by PVDF22(MF) and PS100(UF) membrane was measured. In microfiltration system, the relative flux reduction decreased rapidly to 0.02 in the 30min, as the concentration polarization and gel layer formation were increased. and then the sericin concentration rejection ratio was 40%. In ultrafiltration system, the permeate flux decreased with time and concentration, and increased with the operating pressure and flow rate. Optimal condition in PS100 membrane system for sericin concentration was operating pressure 1.464kgf/$cm^24, operating flow rate $7\ell/min at\; 40^{\circ}C$. At that time, sericin concentration rejection ratio was 83% respectably. The sericin solution was concentrated from 0.1wt% solution to 0.2 wt % solution during about 2 hrs by the UF filteration membrane system.

Natural Indigo Dyeing of Hanji Fabric using Baker's Yeast: Effect of Yeast Concentration and Repeat Dyeing (효모를 사용한 한지직물의 천연인디고 염색 : 효모농도와 반복염색 효과)

  • Son, Kyunghee;Shin, Younsook;Yoo, Dong Il
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.191-201
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    • 2021
  • In this study, an eco-friendly indigo reduction system(scale up reduction, use of buffer solution, and pH control) using baker's yeast(Saccharomyces cerevisiae) was applied for natural indigo(Polygonum tinctorium) dyeing of Hanji fabric and Hanji-mixture fabric(Hanji/Cotton, Hanji/Silk). The effect of concentration of baker's yeast, repeat dyeing, and bath reuse was investigated in terms of dye uptake indicating reduction power. And the oxidation-reduction potential(ORP) was monitored. We also evaluated color properties and colorfastness according to the color strength. The yeast concentration did not significantly affect the maximum reduction power. However, the highest yeast concentration was effective in improving the initial dye uptake, and its the reduction retention power was the most excellent. Even on the last reduction day, the effect of increasing the dye uptake by repeat dyeing was observed. And it was confirmed that the reduction bath could be reused for up to 30 days by supplementing yeast at the end of reduction. For all the fabrics used, deeper and darker PB color were obtained by repeat dyeing. As dyeing was repeated, purplish tint got stronger on the Hanji/Silk fabric compared to other fabrics. Regardless of the composition of Hanji fabrics and color strength, washing and dry cleaning fastness were relatively good with above rating 4-5, and fastness to rubbing and light were acceptable with a rating 3-4 ~ 4-5. The eco-friendly natural indigo dyeing process using niram and baker's yeast would offer global marketability and diversity of Hanji product as a sustainable high value-added material.

Photocatalytic Reduction of Hexavalent Chromium Induced by Photolysis of Ferric/tartrate Complex

  • Feng, Xianghua;Ding, Shimin;Zhang, Lixian
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3691-3695
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    • 2012
  • Photocatalytic reduction of hexavalent chromium (Cr(VI)) in ferric-tartrate system under irradiation of visible light was investigated. Effects of light resources, initial pH value and initial concentration of various reactants on Cr(VI) photocatalytic reduction were studied. Photoreaction kinetics was discussed and a possible photochemical pathway was proposed. The results indicate that Fe(III)-tartrate system is able to rapidly and effectively photocatalytically reduce Cr(VI) utilizing visible light. Initial pH variations resulte in the concentration changes of Fe(III)-tartrate complex in this system, and pH at 3.0 is optimal for Cr(VI) photocatalytic reduction. Efficiency of Cr(VI) photocatalytic reduction increases with increasing initial concentrations of Cr(VI), Fe(III) and tartrate. Kinetics analysis indicates that initial Fe(III) concentration affects Cr(VI) photoreduction most significantly.

Effects of Cheunhwasangamibang on serum glucose concentration and lipid composition in high fat diet induced diabetic rat (천화산가미방(天花散加味方)이 고지방식이에 의한 당뇨병 유발 쥐의 혈청 Glucose농도와 지질구성에 미치는 영향)

  • Kim Byoung-Woo
    • The Journal of Internal Korean Medicine
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    • v.24 no.2
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    • pp.358-364
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    • 2003
  • Effects of Cheunhwasangamibang on serum glucose and lipid composition were investigated in high fat diet induced diabetic rat. Plasma glucose and free fatty acids concentration showed a high reduction in Cheunhwasangamibang groups compared to those of control group and these values decreased to increasing Cheunhwasangamibang concentration. Plasma ${\beta}$-lipoprotein and triglyceride concentration showed a low values in Cheunhwasangamibang groups, however these values showed no significantly different in 4 ml and 6 ml treatment groups. Total cholesterol concentration showed no significantly different in control group and 2 ml Cheunhwasangamibang group, however these values in 4 ml and 6 ml treatment groups showed a reduction compared to those of control group. Plasma LDL-cholesterol concentration showed a reduction in Cheunhwasangamibang group and HDL-cholesterol showed no significantly different in all treatment groups.

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The Impact of Bake-Out Method on the Reduction of Pollutant Concentration in New Apartments (Bake-Out에 의한 신축 아파트의 실내 오염물질농도 저감효과 평가)

  • Pang Seung-Ki;Park Byung-Yoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.4
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    • pp.335-343
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    • 2006
  • Indoor air pollution has been significantly aggravated due to hazardous pollutants emitted from petrochemical finishing materials in new apartments. Pollutants emitted into indoor environment have significant effects on the health of occupants, causing undesirable symptoms related to sick building syndrome such as headache, dizziness, difficulty in concentration, etc. Therefore, this paper attempted to investigate the reduction effect of bake out on VOCs emission in new apartments. Experiments were carried out in three households, one of which was naturally ventilated. The naturally ventilated showed the lowest indoor pollutant concentration and also showed the highest reduction rate by the use of bake out. The most desirable result was observed when the household was naturally ventilated after bake out. More detailed experiments are expected to be carried out afterwards on the prediction of reduction rate of each pollutant.

Adsorptive Binding of Plasma Proteins to Red Blood Cell Ghosts (플라즈마 단백질의 고스트 적혈구 흡착 특성)

  • 김동욱;차운오
    • KSBB Journal
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    • v.11 no.6
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    • pp.630-635
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    • 1996
  • Blood plasma proteins dissolved in isotonic phosphate-buffered saline were found to be adsorbed to red blood cell ghosts suspended in the solution. This was evidenced by concentration reduction of the plasma proteins in the bulk solution. For initial concentration of 0.1mg/mL immuno globulin, concentration reduction increased from 14% to 45% as the volume fraction of red blood cell ghosts in the solution increased from 5% to 45%. For initial concentration of 0.075mg/mL albumin, the concentration reduction increased from 12% to 47% as the volume fraction of red blood cell ghosts in the solution increased from 5% to 70%. The concentration reduction of plasma proteins in hardened red blood cell ghosts was higher than that in red blood cell ghosts. The number of adsorbed protein molecules per a red blood cell ghost were reduced as volume fraction of the ghosts in the solution increased.

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Fluid and Heat Transfer Characterization of Surfactant Turbulent Pipe Flows (계면활성제가 첨가된 관내 난류의 열유동 특성에 관한 고찰)

  • Shin, Kwang-Ho;Yoon, Hyung-Kee;Chang, Ki-Chang;Ra, Ho-Sang
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.982-987
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    • 2006
  • The fluid mechanics and heat transfer of surfactant turbulent pipe flows are characterized with particular emphasis on the effects of surfactant concentration and solution temperature on drag reduction and heat transfer reduction. The test fluids are the surfactant solutions of DR-IW616 supplied by Akzo Nobel Chemical in concentration of $100{\sim}3000ppm$. The solution temperatures studied are $5^{\circ}C$ to $50^{\circ}C$. The critical values of surfactant concentration and solution temperature are clearly identified for drag reduction phenomena.

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Analyzing the Changes in O3 Concentration due to Reduction in Emissions in a Metropolitan Area : A Case Study of Busan during the Summer of 2019 (대도시 지역의 배출량 저감에 따른 O3 농도 변화 분석: 부산광역시 2019년 여름 사례 )

  • Hyeonsik Choe;Wonbae Jeon;Dongjin Kim;Chae-Yeong Yang;Jeonghyeok Mun;Jaehyeong Park
    • Journal of Environmental Science International
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    • v.32 no.7
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    • pp.503-520
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    • 2023
  • In this study, numerical simulations using community multiscale air quality (CMAQ) were conducted to analyze the change in ozone (O3) concentration due to the reduction in nitrogen oxides (NOx)andvolatile organic compounds (VOCs) emissions in Busan. When the NOx and, VOCs emissions were reduced by 40% and, 31%, respectively, the average O3 concentration increased by 4.24 ppb, with the highest O3 change observed in the central region (4.59 ppb). This was attributed to the decrease in O3 titration by nitric oxide (NO) due to the reduction of NOx emissions in Busan, which is classified as a VOCs-limited area. The distribution of O3 concentration changes was closely related to NOx emissions per area, and inland emissions were highly correlated with daily maximum concentrations and 8-h average O3 concentrations. Contrastingly, the effect of emission reduction depended on the wind direction. This suggests that the emission reduction effects may vary depending on the environmental conditions. Further research is needed to comprehensively analyze the emission reduction effects in Busan.