• 한국환경과학회지
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• 제9권3호
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• pp.253-259
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• 2000

The purpose of this study is to investigate the physicochemical characteristics of salinization of groundwater at the estern area of Cheju island. For this purpose, the major ions of groundwater, spring water are analyzed. The concentration of $Cl^-$ and Na^++K^+$/ contained in the groundwater at near the coastline are higher than those at inland area away from the coastline. The water quality components of groundwater observed at this area can be classified into 4 types such as Na-Cl, $HCO_3, Na-Cl-HCO_3$ and Ca-HCO$_3$. The concentration ratio of $SO_4^1 to Cl^- is 0.1354(R^2=0.972)$ at this area. This value is very similar with Dittomer's ratio of 0.13. For Na^+, K^+, and Mg^{2+}/ versus Cl^-$, their ratios also show a significant relationship between sea water and groundwater in this area. From the chloride-bicarbonate ratio, it can be estimated that the intrusion distance of seawater from coastline to inland area is 2.8km at Onpyung-Nansan, Sangdo and Pyungdae areas, and 5.4km at Kosung-Susan area. The mixing ratio between seawater and fresh water by the intrusion of seawater is decreased with the distance toward inland from coastline. This ratio(fresh water : seawater) is 80:20 in spring water adjacent the coastlines, Onpyung area and 99.8:0.2 in the well at No.3 of Susan located at inland away from the coastline. The concentration of $Na^+$ observed at field is 25~45% lower than that theoretically calculated by this mixing ratio. Based on the data of EC, the equipotential line of 500$\mu$mhos/cm is located at 4~5km poing at Kosung-Susan area and 2.5km point at the other area. The equation of correlation between $Cl^-$ concentration and EC values is $Cl^-$=0.1927EC-16.683 for the area lower than 500 $\mu$mhos/cm and $Cl^-$=0.2773EC for the area beyond 500 $\mu$mhos/cm.

• Corrosion Science and Technology
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• 제13권4호
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• pp.145-151
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• 2014

The objectives of this study are to investigate the effect of the concentration ratios of Ni and Fe ions on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the Ni and Fe concentration ratios of 20:20 ppm, 39:1 ppm and 1:39 ppm at $325^{\circ}C$ for 14 days. In the case of the same Ni and Fe ion ratio (20:20), nickel ferrite with a polyhedral shape was formed. Nickel oxide deposits with a needle shape were formed in the condition of high Ni to Fe ion ratio (39:1), While polyhedral iron oxide and needle-like nickel oxide formed in the condition of low Ni to Fe ion ratio (1:39). The amount of deposits increased, when Fe oxides were formed. This indicates that Fe rich oxides stimulated Ni oxide deposition.

• 한국환경과학회지
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• 제23권11호
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• pp.1835-1842
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• 2014

The goal of this study was to evaluate micro-bubble concentration ($C_{air}$) in water by air/water ratio (A/W ratio) with a micro-bubble generating pump. The estimation of micro-bubble concentration is based on the balance of inlet/outlet air and water flow rate. On net A/W ratio to be generated micro-bubble, we found that the obtained the $C_{air}$ are shown as a function of discharge pressure ($P_g$) of the micro-bubble generating pump. The correlation of the $C_{air}$ and the $P_g$ ($C_{air}=3.261P_g-1.754$) was adequately described by the least square methods with a high correlation coefficient (r = 0.9459) and calculated values fit the experimental data quite well. The $C_{air}$ was lower than theoretical dissolved air concentration ($C_{aq}$) calculated by Henry's law. The $C_{air}$ for being operated the micro-bubble generating pump was 6.75 - 39.53 mL/L, however, we found that the optimum of the $C_{air}$ to generate micro-bubble was the range from 10 to 12 mL/L.

• 대한환경공학회지
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• 제28권4호
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• pp.402-406
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• 2006

본 연구에서는 pH가 7과 8인 조건에서 디메칠아민 농도를 0.05 mM로 고정시키고 클로라민 농도 변화에 따른 NDMA 생성농도를 측정하여 회귀식을 개발하였다. 클로라민/디메칠아민 비율이 1보다 클 때와 작을 때에 NDMA 생성에 큰 차이를 보여 통계분석에서 구분하여 회귀식을 제시하였다. NDMA 생성 농도는 클로라민/디메칠아민 비율에 높은 상관성을 보여 주었다. 개발한 회귀식을 근거로 하여 NDMA 생성 농도를 기존 연구에 적용한 결과 상대오차는 $-79{\sim}163%$로 조사되었다. 상수 처리장에서 원수의 디메칠아민 농도를 알 경우 이 식을 적용 하면 NDMA 발생 범위를 제시하여 주입할 클로라민 농도나 전처리 필요성을 결정하는데 도움을 줄 것으로 생각된다.

• The Korean Journal of Ecology
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• 제26권6호
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• pp.313-319
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• 2003

Dry weight loss and nutrient release from leaf litter for six tree species were studied using litter bag methods. The litter bags were incubated for f6 months on the forest floor in temperate deciduous forest in Mt. Cheonma, located at the middle part of Korean Peninsula. The changes in nutrient content and the rate of dry weight loss in leaf litter varied with litter types. The litter of Pinus densiflora showed the lowest rate of mass loss (k=0.33), nitrogen concentration (0.89%) and ash concentration (2.50%), while showed the highest C/N ratio (63.40). On the other hand, the litter of Acer pseudo-sieboldianum showed the fastest rate of mass loss (k=0.82), the highest nitrogen concentration (1.11%), and the lowest C/N ratio (49.40). During the decomposition, nitrogen, phosphorus and calcium in the leaf litters showed relatively slow decreasing pattern compared to other elements (carbon, potassium, magnesium, manganese and sodium), but potassium and sodium decreased at early stage of the decomposition for all leaf litters. Differences in annual decomposition rates of litter among species were consistent with the particular chemical characteristics of their leaf litters. The initial concentration of nitrogen was positively correlated with litter decomposition rate for six species, while litter decomposition rate of six species was negatively correlated with C:N ratio of initial leaf litters.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2005년도 춘계 학술발표회 논문집
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• pp.1108-1117
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• 2005

RAP(rammed aggregate pier) method which is intermediate foundation of deep and shallow foundation is used to improve the ground with high compaction energy. This method is widely spread around the world, but there are few examples and systemic researches for failure mechanism and bearing capacity of this method are not organized yet. In this paper, soil laboratory tests were carried out to evaluate the applicability of RAP method as the foundation of a structure. And the bearing capacity and the failure mechanism of RAP method were studied with respect to various relative densities(35%, 65%, 90%), diameters(45mm, 60mm) and lengths(20cm, 30cm, 40cm). As results, stress concentration ratio decreased as diameter of RAP was increasing or length of RAP was decreased or relative density was decreased. however these results were not always constant. because systematic interaction between relative density and diameter and length of RAP can affect stress concentration ratio, more studies on stress concentration ratio are needed throughout laboratory and field tests.

• Membrane and Water Treatment
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• 제10권5호
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• pp.361-372
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• 2019

Effect of different alkane based solvents on the stability of emulsion liquid membrane was investigated using normal alkanes (n-hexane, n-heptane, n-octane and n-decane) under various operating parameters of surfactant concentration, emulsification time, internal phase concentration, volume ratio of internal phase to organic phase, volume ratio of emulsion phase to external phase and stirring speed. Results of stability revealed that emulsion liquid membrane containing n-octane as solvent and span-80 (5 % (w/w)) as emulsifying agent presented the highest amount of emulsion stability (the lowest breakage) compared with other solvents; however, operating parameters (surfactant concentration (5% (w/w)), emulsification time (6 min), internal phase concentration (0.05 M), volume ratio of internal phase to organic phase (1/1), volume ratio of emulsion phase to external phase (1/5) and stirring speed (300 rpm)) were also influential on improving the stability (about 0.2% breakage) and on achieving the most stable emulsion. The membrane with the highest stability was employed to extract acridine orange with various concentrations (10, 20 and 40 ppm) from water. The emulsion liquid membrane prepared with n-octane as the best solvent almost removed 99.5% of acridine orange from water. Also, the prepared liquid membrane eliminated completely (100%) other cationic dyes (methylene blue, methyl violet and crystal violet) from water demonstrating the efficacy of prepared emulsion liquid membrane in treatment of dye polluted waters.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제39차 학술발표회
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• pp.13-14
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• 2008

In black dyeing of PET fabric, high concentrations of disperse dyes of three primary color are generally used, which leads low exhaustion level of dye and discharge of a large amount of unfixed dye into dyehouse effluent. In this study, the effect of combination ratio of dye concentration, liquor ratio, and dyeing pH on dyeing and color property of black dyed PET fabric was investigated.

• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.507-512
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• 2010

The effect of catholyte to anolyte amount ratio on the electrodialysis cell performance for HI concentration was investigated. For this purpose, the electrodialysis cell was assembled with Nafion 117 as PEM membrane and activated carbon fiber cloth as electrodes. The initial amount of catholyte was 310 g and that of anolyte varied from 1 to 3 of amount ratio. The calculated electro motive force (EMF) increased with time and the increment enhanced as the amount ratio of catholyte to anolyte decreased. The mole ratios of HI to $H_2O$ (HI molarity) in catholyte were almost the same and exceeded pseudo-azeotropic composition for all amount ratios after 2 h operation. The HI molarity continuously increased with time for 10 h operation. The mole ratio of $I_2$ to HI decreased in catholyte but increased in anolyte. The increment of mole ratio of $I_2$ to HI in anolyte rose as the amount ratio of catholyte to anolyte decreased. In case of 1:1 amount ratio, the cell operation was stopped for the safety at approximately 6 h operation, since the mole ratio of $I_2$ to HI reached solubility limit. The cell voltage of the electrodialysis cell increased with time and the rate of increase was high at low amount ratio. This suggests that the amount ratio of catholyte to anolyte not only crucially influences the cell voltage, but also cell operation condition.

• 유기물자원화
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• 제22권3호
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• pp.41-52
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• 2014

본 연구에서는 부정기적 발생 오수의 생분해도 특성 parameters를 현장 시료채취 및 분석실험을 실시하여 조사 및 분석하였으며 결과는 다음과 같다. TCODcr (Total CODcr)의 1,2차 평균 농도는 325.5 mg/L 이며 TCOD 분율은 100% 로 분석되었다. SCODcr (Soluble CODcr)의 1,2차 평균 농도 는 135.9 mg/L 이며 TCOD 분율은 41.8% 로 분석되었다. Ss (Readily biodegradable substrate)의 1,2차 평균 농도는 74.1 mg/L 이며 TCOD 분율은 22.8% 이다. $S_I$ (Soluble inert non-biodegradable substrate)의 1,2차 평균 농도는 61.8 mg/L 이며 TCOD 분율은 19.0% 이다. Xs(Slowly Biodegradable Substrate)의 1,2차 평균 농도는 27.8 mg/L 이며 TCOD 분율은 8.5% 이다. $X_H$의 1,2차 평균 농도는 103.4 mg/L 이며 TCOD 분율은 31.8% 이다. $X_I$ (Particulate inert non-biodegradable substrate)의 1,2차 평균 농도는 58.5 mg/L 이며 TCOD 분율은 18.0% 이다. 따라서 대상 시료의 용존성 생분해 가능 유기물질은 41.8%로 분석되었으며, 이중 생분해가 용이한 분율은 22.8%로 나타났다. 이와 같이 부정기적인 유입 유량으로 인한 유량조정 또는 균등조의 운전으로 유입부하 변동폭에 대한 영향은 크지 않을 것으로 판단된다.