• 제목/요약/키워드: concentration rate

검색결과 10,249건 처리시간 0.042초

유체환경 중에서 연강재의 간극부식에 관한 연구 (Study on the Crevice Corrosion of Mild Steel in Fluid Environment)

  • 임우조;윤병두
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2000년도 유체기계 연구개발 발표회 논문집
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    • pp.373-378
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    • 2000
  • The crevice corrosion of local corrosion occur when the gap exist on metal surface. This crevice corrosion happen to region such as flange of pipe, contact part of casing, under gasket and packing, between valve disk and seat of pump etc. Especially The crevice corrosion of mild steel(SS 400) get serious. This paper was studied on the crevice corrosion of SS 400 in fluid environment. In $0\%,\;2\%,\;3.5\%,\;5\% NaCl$ solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by $3.5\%$ but the concentration increased over $3.5\%$, the current density was low drained. 3) The weight loss rate of SS 400 was increased as concentration of NaCl solution Increased by $3.5\%$, but the concentration increased over $3.5\%$, that of SS 400 was decreased. 4) Effect of oxygen for crevice corrosion in the concentration of $3.5\%$ NaCl solution become sensitive than that $0\%$ NaCl solution.

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서울시 미세먼지 농도의 지역적 특성파악을 위한 연구 - 구별 분포 특성 및 차량등록대수와의 관계 - (Understanding on Regional Characteristics of Particular Matter in Seoul - Distribution of Concentration in Borough Spatial Area and Relation with the Number of Registered Vehicles -)

  • 박종길;최윤정;정우식
    • 한국환경과학회지
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    • 제26권1호
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    • pp.55-65
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    • 2017
  • Average concentration of PM in Seoul metropolitan area satisfied the Korean air quality standard in 2010. Furthermore, concentration of PM in all boroughs across Seoul met the air environment standard in 2012. $PM_{10}$ concentration was relatively higher in center of Seoul in comparison to the rest, while $PM_{2.5}$ concentration showed exactly the contrary result. We analyzed the effect that PM emissions from vehicles would have on PM concentrations across Seoul. The results showed that average annual PM concentration recently decreased in Seoul although the number of vehicles registered annually continued its upward trend. By contrast, average fine dust concentrations in Seoul showed a decline which suggested that correlation between annual average PM concentrations and number of registered vehicles remained low. However, year-on-year vehicle registration rate recently showed a declining tendency in the same way as the trend of changes in average PM concentrations. Particularly, the upward trend in annual average PM concentrations in 2002 and 2007 was consistent with the increase in vehicle registration rate, suggesting that vehicle registration rate was closely associated with changes in PM concentrations.

소형형광등(Compact Fluorescent Lamp)의 파쇄에 따른 기상에서의 수은농도 특성 (Characteristics of Mercury Concentration in Vapor Phase from Compact Fluorescent Lamp)

  • 이승희
    • Korean Chemical Engineering Research
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    • 제52권5호
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    • pp.652-656
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    • 2014
  • 소형형광등(Compact fluorescent Lamp; CFL) 3종류를 파쇄할 때 발생하는 수은의 기상농도와 대기로 방출되는 수은 양을 평가하였다. CFL 파쇄 시 배출되는 수은 농도는 초기에 매우 급격하게 감소되었으나 24시간 이후에는 수은농도의 변화가 점차 작아졌으며, 이 후 42시간까지 일정 농도를 유지되었다. 이러한 일정한 농도를 안정화 농도(Stabilized concentration)로 나타내었고 안정화 농도는 기체상 수은이 거의 배출되어 파쇄장치에 잔류하는 액체상 수은이 온도와 기압에 의한 영향으로 기화되어 배출되는 것으로 판단되었다. 소형형광등에서 발생되는 수은농도는 회사별로 A사 < B사 < C사 순으로 나타났으며, 회사별로 수은의 안정화 농도와 안정화 시간은 A사 < B사 < C사 순으로 높았다. 공기유량이 증가함에 따라 수은 부분압은 감소하였으며, 이는 대기 중 수은의 양이 낮아짐을 의미하고 안정화 농도도 감소하는 것으로 나타났다. CFL 파쇄 시 초기의 수은 농도는 공기유량에 관계없이 $0.1mg/m^3$인 지정시설의 환경기준보다 매우 높으므로 소형형광등을 파쇄할 때 기상의 수은을 관리하는 것이 절대적으로 필요하다.

애기장대의 종자 발아에 미치는 맥반석과 녹차의 중금속 제거 효과 (Removal Effect of Biostone and Green Tea on the Heavy Metal Toxicity during Seed Germination of Arabidopsis thaliana)

  • 박종범
    • 한국환경과학회지
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    • 제12권12호
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    • pp.1303-1308
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    • 2003
  • This experiment was carried out to investigate the effects of heavy metals (cadmium, chromium, copper and lead) on the seed germination of Arabidopsis thaliana, and examinated the removal effects of biostone and green tea on the heavy metal toxicity. Cadmium and chromium among the four heavy metals had no effect on the seed germination even in the concentration fifty times higher than in the official standard concentration of pollutant exhaust notified by the Ministry of Environment. However, seeds were not germinated in the concentration of copper ten times higher and in the concentration of lead fifty times higher than the official standard concentration. When seeds were sown in the solutions of lead (15, 20, 25 and 30 mg/L) and copper(15 and 20 mg/L), the seed germination rates were 0% and less than 10%, respectively. However, when biostone(3 g/30 $m\ell$) was added, the seed germination rate was 100% in all the concentrations. The germination rate was 100% in distilled water and copper solution (5 mg/L). However, green tea (0.2 g/30 $m\ell$) was added, the seed germination rate was 0% in both. The results show that cadmiun and chromium had no effect on the seed germination, but lead and copper decreased the rate of seed germination of Arabidopsis thaliana, Biostone removed heavy metal toxicity, but green tea did not removed heavy metal toxicity during germination.

단기간 생물농축계수의 측정에 있어서 실험어류의 종에 따른 차이 (Difference in Species of Test Fish on the Determination of Short-term Bioconcentration Factor)

  • 민경진;차춘근;전봉식;김근배
    • 한국환경보건학회지
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    • 제24권1호
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    • pp.24-31
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    • 1998
  • This study was performed to investigate the difference in species of test fish on the determination of short-term bioconcentration factor in zebrafish(Brachydanio rerio), red sword tail(Xiphophorus hellieri) and goldfish(Carassius auratus). Experimental concentrations of carbamates were 0.05 and 0.10 ppm and chlorothalonil were 0.005 and 0.01 ppm for 3 and 5 days, respectively. This paper reports the measured BCF value on pesticides in various species of test fish, under steady state, and examined correlation between the BCF value and depuration rate constant or LC$_{50}$ or lipid content. Carbamates and chlorothalonil concentration in fish extract and BCF of carbamate and chlorothalonil were increased as incresing test concentration. Carbamates concentration in fish extract and BCF of carbamate were decreased as incresing test period, but chlorothalonil concentration in fish extract and BCF of chlorothalonil were increased as prolonging test period. Determined pesticide concentration in fish extract and BCF were highest in red sword tail, and followed by goldfish, and zebrafish. Determined depuration rate constant were highest in zebrafish, and followed by goldfish, and red sword tail. 96hr-LC$_{50}$ were highest in red sword tail, and followed by zebrafish, and goldfish. Lipid compositions were highest in red sword tail, and followed by goldfish, and zebrafish. Therefore, it is suggested that the difference of BCF between each pesticide due to those of lipid composition of fish and deputation rate constant, while LC$_{50}$ have no effect on BCF.

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Evaporation Rate in Protein Crystallization Via Vapor Diffusion can be Controlled through a Simple Multistep-concentration Setting in Capillaries

  • Lee, Min-Nyung;Chung, Yong-Je
    • 한국결정학회지
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    • 제14권1호
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    • pp.35-38
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    • 2003
  • 증기-확산 단백질 결정화의 물-증발 속도를 조절하기 위해서, 간결한 모세관 내의 다중-단계 농도 장착법 (multistep-concentration setting in capillaries) 이 이용되었다. “조절 용액 (regulatory solution)”이라고 일컬어지는 2차 침전 용액이 이용되어, 이 방법으로 다양한 증발 속도 곡선들이 얻어졌다. 이때, 조절 용액은 단백질 용액에 직접적으로 노출되지 않는다. 모델 단백질인 lysozyme의 결정화에 이 그래프들이 적용되었다. 결정 성장은 증발속도에 달려있다는 것을 실험 결과들이 명백하게 보여주었다. 특히나. 단백질 용액의 침전 농도가 어떤 점까지 증가하다가 평형 농도로 줄어드는 decoupling 곡선이 가장 좋은 결정들을 만들어냈다.

TiO2 코팅 석탄회 복합체의 기상 Acetaldehyde 광분해 특성 (Photocatalytic Degradation of Gaseous Acetaldehyde through TiO2-Coated Fly Ash Composites)

  • 신대용;김경남
    • 한국세라믹학회지
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    • 제45권1호
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    • pp.43-47
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    • 2008
  • The photocatalyst of $TiO_2$ coated on a fly ash composites (TCF) was prepared from precipitant dropping method to remove the acetaldehyde by photocatalytic reaction. The TCF were characterized by crystal aize, crystal structure and specific surface area. The photodegradation of acetaldehyde has been investigated using a UV-illuminated fixed photocatalytic reactor with TCF catalyst and P-25 catalyst in gas phase. The effect of photodegradation reaction conditions, such as initial concentration of acetaldehyde, concentration of oxidant in mixed gas and the light intensity on the photodegradation of acetaldehyde were investigated. P-25 catalyst showed the highest photodegradation of acetaldehyde and anatase $TiO_2$ coated TCF showed higher decomposition rate than rutile coated TCF. The photodegradation rate of acetaldehyde increased with the decrease of flow rate, initial concentration of acetaldehyde ($C_i$) and water vapor, however, it was increased with the increas of UV light intensity. The optimum conditions were weight of TCF=10 g, flow rate=50 ml/min $C_i$=100 ppm, concentration of oxygen=20%, concentration of water vapor=100 ppm.

순수점성 비뉴톤유체의 물성치들에 대한 농도 및 온도의 영향 (Effects of the Concentration and the Temperature on the Thermophysical Properties of Purely-Viscous Non-Newtonian Fluid)

  • 조금남
    • 대한기계학회논문집
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    • 제18권3호
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    • pp.670-680
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    • 1994
  • The thermophysical properties of Non-Newtonian fluid as the function of the temperature and the concentration are needed in many rheological heat transfer and fluid mechanics problems. The present work investigated the effects of the concentration and the temperature on the thermophysical properties of purely-viscous Non-Newtonian fluids such as the isobaric thermal expansion coefficient, density, zero-shear-rate viscosity, and zero-shear-rate dynamic viscosity within the experimental temperature range from $25^{\circ}C$ to $55^{\circ}C$. The densities of the test fluids were determined as the function of the temperature by utilizing a reference density and the least square equation for the measured isobaric thermal expansion coefficient. As the concentration of purely-viscous Non-Newtonian fluid was increased up to 10,000 wppm, the densities were proportionally increased up to 0.4%. The zero-shear-rate viscosities of test fluids were measured before and after the measurements of the first thermal expansion coefficients and the densities of Non-Newtonian fluid. Even though they were changed up to approximately 22% due to thermal aging and cycling, they had no effects on the thermal expansion coefficients and the densities of Non-Newtonian fluid. The zero-shear-rate dynamic viscosities for purely-viscous Non-Newtonian fluids were compared with the values for distilled water. They showed the similar trend with the zero-shear-rate viscosities due to small differences in the densities for both distilled water and purely-viscous Non-Newtonian fluid.

미생물 고정화를 이용한 산성염료의 처리 (Treatment of Acid dye Using Microbial Immobilization)

  • 김정목;조무환;양용운
    • 한국염색가공학회지
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    • 제11권2호
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    • pp.19-26
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    • 1999
  • Strains degrading and decolorizing acid dyes, Nylosan red E-BL 150%. were isolated from natural system, was named as ARK3. The optimal culture conditions of temperature and pH were $35^\circ{C}$, 7.0, respectively. Growth rate of cells in conditions of aerobic shaking more than standing culture conspicuously increased, and optical density of those to strain ARK3 were found as 1.38 and 0.25 after 42 hrs. Decolorization efficiency in batch culture which used as immobilization media to natural zeolite was 15% after 6 hrs, while suspension culture was 5%, also its of immobilization and suspension culture were 90% and 85% after 48 hrs, respectively. Decolorization efficiency of air-lift bioreactor was more than 90% to a dilution rate of $0.038hr^{-1}$, but that was decreased as 70%, when the dilution rate was $0.05hr^{-1}$. Even though at maximum dilution rate of this study, there was not appeared "wash out" phenomienon of biomass. Decolorization efficiency was 97.7% at a dilution rate of $0.025hr^{-1}$, when influent dye concentration was $100mg/\ell$. But if influent dye concentration increased as $150mg/\ell$, even though MLVSS increased, that of treatment water decreased as 93%. Also, when influent dye concentration increased as $200mg/\ell$ and $300mg/\ell$, decolorization efficiencies of treatment water abruptly decreased as 85% and 63%, respectively. Decolorization efficiency was more than 92% to the limit volumetric loading rate of $3.75mg/\ell\cdot{hr}$hr, without regard to variation of influent dye concentration or hydraulic retention time. if volumetric loading rate was more than $3.80mg/\ell\cdot{hr}$, at same condition, decolorization efficiency was lower decrease of retention time than increase of influent dye concentration.entration.

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디젤 기관의 연소와 배출물에 관한 연구 -경유-물물의 유화연료 사용시- (A Study on Combustion And Exhaust Emissions of Diesel Engine -For Gas Oil-Water Emulsified Fuel-)

  • 조진호;김형섭;박정률
    • 대한기계학회논문집
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    • 제16권1호
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    • pp.180-188
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    • 1992
  • 본 연구에서는 와류실식 디젤 기관에 경유-물의 유화연료 사용시 시관의 회전 속도(1500rpm)가 일정인 경우 물의 첨가량(체적비, 0~20%)과 기관의 부하(BMEP,2.1~ 7.5kg/$\textrm{cm}^2$)변화에 따른 연소실내 압력, 압력상승률 및 열발생률, 착화지연 기간, 연료 소비율 등의 연소특성과 CO, HC, NOx 및 매연의 배출능도 등 유해 배출 가스에 미치는 영향에 관하여 실험적으로 구한 것이다.