• Title/Summary/Keyword: compound system

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APPLICATION OF DISPROPORTIONATION REACTION TO SURFACE TREATMENT

  • Oki, Takeo
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.478-481
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    • 1996
  • Disproportionation reaction is very important and interesting reaction to be applied to such surface treatment as metal, alloy, compound coating, a surface etching and so on. In gaseous system, the reaction of Al chloride is applied to Al and Al alloy coating, and the similar reaction of Ti chloride is also used for Ti, Ti alloy and Ti compound coating. As for aqueous system, this reaction is utilized to such metal coat as Sn etc. and metal etching such as Cu, Fe and so on. Also in molten salts system, this reaction has many application for surface treatment like metal, alloy and compound coatings for corrosion, wear, heat resistance and so forth. For instance, carbide film, nitride film, boride film, alloy film, quite new different film from the components of substrate material are coated in single and multiple component film system by the disproportionation reaction.

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Hybrid Recommendation Based Brokerage Agent Service System under the Compound Logistics (공동물류 환경의 혼합추천시스템 기반 차주-화주 중개서비스 구현)

  • Jang, Sangyoung;Choi, Myoungjin;Yang, Jaekyung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.39 no.4
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    • pp.60-66
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    • 2016
  • Compound logistics is a service aimed to enhance logistics efficiency by supporting that shippers and consigners jointly use logistics facilities. Many of these services have taken place both domestically and internationally, but the joint logistics services for e-commerce have not been spread yet, since the number of the parcels that the consigners transact business is usually small. As one of meaningful ways to improve utilization of compound logistics, we propose a brokerage service for shipper and consigners based on the hybrid recommendation system using very well-known classification and clustering methods. The existing recommendation system has drawn a relatively low satisfaction as it brought about one-to-one matches between consignors and logistics vendors in that such matching constrains choice range of the users to one-to-one matching each other. However, the implemented hybrid recommendation system based brokerage agent service system can provide multiple choice options to mutual users with descending ranks, which is a result of the recommendation considering transaction preferences of the users. In addition, we applied feature selection methods in order to avoid inducing a meaningless large size recommendation model and reduce a simple model. Finally, we implemented the hybrid recommendation system based brokerage agent service system that shippers and consigners can join, which is the system having capability previously described functions such as feature selection and recommendation. As a result, it turns out that the proposed hybrid recommendation based brokerage service system showed the enhanced efficiency with respect to logistics management, compared to the existing one by reporting two round simulation results.

Studies on the Crosslinking Density and Reinforcement of Rubber Compounds by Cure System (가황조건별 배합고무의 가교밀도와 고무보강성에 관한 연구)

  • Park, Nam-Cook;Lee, Seog
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.315-323
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    • 1998
  • The purpose of this study was to investigate the crosslinking density and reinforcement of rubber compounds with various carbon black loadings, cure systems and cure temperatures. Bound rubber content increased with volume fraction of carbon black in rubber compounds, but total crosslinking density decreased with increasing the bound rubber content. Rate constant of cure reaction was changed significantly by cure system and cure temperature, especially it showed strong dependence on the cure temperature. High activation energys of cure reaction were shown in the rubber compound with high loading of carbon black under EC system and in the rubber compound with low loading of carbon black under CC system. High total crosslinking density of vulcanized compounds appeared in the rubber compound with low loading of carbon black and CC system among cure systems. Typical change of total crosslinking density by EC system was not shown. The highest elastic constant by Mooney-Rivlin equation was shown in the rubber compound with low loading of carbon black and SEC system. Modulus increased as increasing the loading of carbon black in the rubber compounds and showed the order of SEC, CC, and EC system for cure system.

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Wear Particulate Matters and Physical Properties of ENR/BR Tread Compounds with Different Ratio of Silica and Carbon Black Binary Filler Systems

  • Ryu, Gyeongchan;Kim, Donghyuk;Song, Sanghoon;Lee, Hyun Hee;Ha, Jin Uk;Kim, Wonho
    • Elastomers and Composites
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    • v.56 no.4
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    • pp.234-242
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    • 2021
  • The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, the properties of epoxidized natural rubber (ENR) containing a silica-friendly functional group were evaluated by considering it as a base rubber and varying the silica ratio in this binary filler system. The results showed that the wear resistance of the NR/BR blend compound decreased as the silica ratio increased. In contrast, the ENR/BR blend compound exhibited an increase in wear resistance as the silica ratio was increased. In particular, the ENR-50/BR blend compound showed the best wear resistance due to the presence of several epoxide groups. Furthermore, we observed that for tan 𝛿 at 60℃, higher epoxide content resulted in the higher Tg of the rubber, indicating a higher tan 𝛿 at 60℃. On the other hand, it was confirmed that increasing the silica ratio decreased the value of tan 𝛿 at 60℃ in all compounds. In addition, we measured the amount of wear particulate matters generated from the compound wear. These measurements confirmed that in the binary filler system, regardless of the filler type, the quantity of the generated wear particulate matters as the filler-rubber interaction increased. In conclusion, the silica filled ENR/BR blend compound exhibited the lowest generation of wear particulate matters.

TMA-Water Clathrate Compound of Cooling Characteristics for Low Temperature Latent Heat Storage (저온잠열축열을 위한 TMA-물계 포접화합물의 냉각특성)

  • Kim, Chang-Oh;Chung, Hyoun-Ho;Chung, Nak-Kyu
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.296-301
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    • 2009
  • The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25wt% has the average phase change temperature of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

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The Cooling Characteristics of Clathrate Compound according to Concentration of TMA

  • Lee, Jong-In;Kim, Chang-Oh;Chung, Nak-Kyu
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.1
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    • pp.32-36
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    • 2009
  • The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N$) of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25 wt% has the average phase change tempera ture of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

Effect of Tracer Composition on Spectrum and Intensity of Burning Flame (예광제 조성이 연소 불꽃의 스펙트럼 및 광도에 미치는 영향)

  • Kwon, Soon-Kil;Hwang, Jun-Sik;Lee, Sang-Mu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.9 no.4
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    • pp.90-96
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    • 2006
  • Computer simulation was carried out to develop the tracer composition of a high performance to be able to be observed by not only the naked eye but also the thermal imaging system attached to the weapon system. The results of computer simulation show that the optimum Mg content among the trace compositions is about 40% and the formulation consisted of Viton A has a higher flame temperature compared with that of chloride compound. But the only use of Viton A radiates a yellow light and the composition adding a chloride compound radiates the red light. The light intensity of the tracer composition involving Viton A is higher than that of chloride compound. The tracer composition involving Viton A shows more clear images in case of all tests.

Synthesis and Photoluminescent Property of Diheteryl-substituted Triphenylamine Compound (Diheteryl-substituted triphenylamine 화합물의 합성과 형광 특성)

  • Kim, Byung-Soon;Kim, Sung-Hoon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.6
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    • pp.35-38
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    • 2007
  • FTriphenylamine dye compound having diheteryl moiety was synthesized and its photoluminescent property was investigated. Organic luminescent materials have received great attentions due to potential application subjects onto full color image displays. In this context, the dye (III) for light emitting materials was synthesized using 2-(4-amino-2-hydroxyphenyl)benzoxazole (I) and 4,4'-diformyltriphenylamine (II). It is well known that the amino groups of compound (I) react with carbonyl groups, especially an aldehyde, to afford azomethine linkages. The dye shows bulish-green fluorescence property, which is anticipated for the light-emitting material for display devices. In this context, our aim is to synthesize diheteryl-substituted triphenylamine fluorescent dye as an emitting material. The spectroscopic characteristics and the fluorescent properties of this dye molecule were examined and determined.

The Study on the Performance of the Fuel Cell Driven Compound Source Hybrid Heat Pump Heating and Cooling System to Large Community Building (대형 Community 건물의 연료전지 구동 복합열원 하이브리드 히트펌프 냉.난방 시스템 성능 해석)

  • Byun, Jae-Ki;Jeong, Dong-Hwa;Choi, Young-Don
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.82-87
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    • 2007
  • In the present study, the simulation on the annual performance evaluation of a renewable energy systems with fuel cell driven compound source hybrid heat pump systems is applied to the heating and cooling of large community building. The large community building has the economical advantage to apply heat pump cooling and heating systems the long period operation. If air and ground source hybrid heat pump systems are combined, COP of the system can be increased largely. Fuel cell driven compound source hybrid heat pump system can reduced the fuel cost as well as thermal storage tank sharply.

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On Renewable Energy Technology Valuation Using System Dynamics and Compound Real Options (시스템다이내믹스와 복합 리얼옵션 기반 신·재생에너지 기술가치평가)

  • Jeon, Chanwoong;Shin, Juneseuk
    • Journal of Korean Institute of Industrial Engineers
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    • v.40 no.2
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    • pp.195-204
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    • 2014
  • The transition from fossil to renewable energy is inevitable due to fossil depletion. So, Renewable energy is very important for energy security and economic growth although it's R&D is long-term and high risky project. We propose new valuation method which combined system dynamics and compound real option method for long-term and high risk projects such as renewable energy. This method can show dynamic valuation results for the complex causal interaction and be easy for Monte-Carlo simulation to estimate volatility. And it can reflect the value of flexible decision for uncertainty. We applied the empirical analysis for Korea's photovoltaic industry by using this method. As results by empirical analysis, photovoltaic's R&D has high valuation using this method compared by traditional valuation methods such as DCF.