• Title/Summary/Keyword: compound metal

Search Result 531, Processing Time 0.024 seconds

An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine (염소를 함유한 폐기물의 소각시 생성되는 유해 중금속류 결정에 대한 화학 평형 계산)

  • ;;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.19 no.12
    • /
    • pp.3372-3381
    • /
    • 1995
  • An equilibrium analysis was carried out to determine principal species of heavy metals in waste incineration and their behaviors with variation of temperature, chlorine concentration, excess air ratio, and C/H ratio. The waste was assumed as a compound of hydrocarbon fuel, chlorine, and metals. Calculated results showed that the most important parameter to determine the principal species was temperature. Chlorine concentration also affected on mole fractions of the principal species. Generally principal species at high temperature were chlorides while there were some metals of which principal species were oxides. At low temperature mole fractions of the principal species increased, but at high temperature mole fractions of some metal species decreased. C/H ratio of the hydrocarbon fuel and excess air ratio had little effect on mole fractions of the metal species, compared to the temperature and chlorine concentration.

A Study of the Change of Hall Effect as a Function of the V/III Ratio in n-GaAs compound Semiconductors

  • Kim, In-Sung
    • Transactions on Electrical and Electronic Materials
    • /
    • v.10 no.4
    • /
    • pp.107-110
    • /
    • 2009
  • In this study, the Hall effect has been studied in n-GaAs samples characterized by V/IIl growth ratios of 25, 50 and 100 and prepared by metal organic chemical vapor deposition. For the Hall effect measurements, the grown samples were cut to a size of 1${\times}$1 cm. The measurements were carried out at room temperature, using Indium contact metal at the four corners of the samples. According to the experimental results, the Schottky effect was not ovservation. Also for the n-GaAs sample of V/Ill 100 ratio the electron drift velocity was very high.

Creep Behavior Analysis of Pure Ti by Omega Method (Ti의 ${\Omega}$법을 이용한 고온 크리프 거동해석)

  • Cho, Ji-Hwa;Lee, Hen-Six;Jeong, Soon-Uk
    • Proceedings of the KSME Conference
    • /
    • 2004.11a
    • /
    • pp.388-393
    • /
    • 2004
  • Creep behavior of Ti had been studied in a stress from 9.8 to 29.4 MPa and temperature rang from 873K to 973K with a special reference to tertiary creep. It was found that stress exponent of Ti was larger than that of the general pure metal and the compound metal. The relationship between true strain and strain rate in tertiary creep was appeared as the equation, $ln{\dot{e}}$ = $ln{\dot{e}}_{0}$ + ${\Omega}$ e Also, Apparent activation energy of was appeared as 274.92kJ/mol by using the equation ${\dot{\varepsilon}}_{0}$ = A ${\sigma }_{0}^{\ast_0}$ exp$(-Q_{0}/RT)$

  • PDF

Microstructure Observation of Pd-Ga System Dental Alloy for Metal-Ceramic Restorations (치과 도재용 Pd-Ga계 합금의 미세조직 관찰)

  • 김기주;이진형
    • Journal of Biomedical Engineering Research
    • /
    • v.21 no.6
    • /
    • pp.537-542
    • /
    • 2000
  • Ga이 함유된 Pd-Ga계 합금은 우수한 기계적 성질, 심미성 및 생체적합성등으로 차세대 치과 도재용 합금으로 주목 받고 있다. 본 연구에서는 상용 77.3%Pd-6.0%Ga계 합금을 원심주조법으로 주조하고, 탈개스, 세라믹소성처리한 후 미세조직을 광학현미경, X-선 회절기, 투과전자현미경으로 관찰하였다. X-선 회절분석 및 투과전자현미경 관찰 결과, Pd고용체와 미세한 석출물에 의해 나타나는 줄무늬를 확인하였다. 공정점 86$0^{\circ}C$에서 5시간 유지시킨 상평형 열처리조건에서는 Pd고용체와 금속간화합물 Pd(sub)2Ga에 해당하는 보다 명확한 제한시야회절도형을 얻었다. 이러한 결과로 77.3%Pd-6.0%Ga계 합금은 Pd고용체와 미세한 구형의 금속간화합물 Pd(sub2)Ga으로 구성되었음을 알 수 있었다.

  • PDF

The study of Ag etching effect by adding compound on the lead frame process (Lead frame 공정 중 화합물에 따른 Ag 에칭효과)

  • 이경수;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.859-862
    • /
    • 2001
  • This study describes a selective Ag etching solution for use with pattern on the surface of copper. This etching solution uses potassium iodide and potassium sulfate as the ligand that coordinates to the metal ions and ferricyanide as the oxidant. The etching rate was depended on the concentration of co-ligands and time. But the etching rate wasn't depended on the pH(2∼6), and oxidant(K$_3$Fe(CN)$\_$6/). Complete etching of silver can be achieved rapidly within 90sec for 4.46${\mu}$m thick metal films when aqueous solutions containing K$_3$Fe(CN)$\_$6/, K$_2$S$_2$O$\_$8/ and KI was used. This etching solution was characteristic of anisotropic etching.

  • PDF

Adsorption and catalytic ozonation of aquatic organic compound by acid-treated granular activated carbon (산 처리한 활성탄을 이용한 수중 유기물의 흡착 및 오존 분해)

  • Nam, Yun-Seon;Rhee, Dong-Seok
    • Journal of Industrial Technology
    • /
    • v.31 no.B
    • /
    • pp.127-132
    • /
    • 2011
  • Humic substances is accounted for for the largest proportion in natural organic matter(NOM) and NOM is widely distributed in varying concentration in all aquatic and soil. They can affect water quality adversely in several ways by contributing undesirable color, complexing with metal and yielding metal concentrations exceeding normal solubility. Ozonation is one of the efficient treatments for degradation of humic substances which cause some problems in water treatment. Especially, the combination of ozone and granular activated carbon was applied to degradation humic acid in aquatic system. The aim of this work to test the available of acid-treated granular activated carbon as catalyst in the ozonation of humic acid.

  • PDF

Electrical Properties and Structures of Spinel Type LiMn$_{2-y}$M$_y$O$_4$(M=Cr$^{3+}$) Doped with Transition Metal (전이금속으로 치환된 Spinel형 LiMn$_{2-y}$M$_y$O$_4$(M=Cr$^{3+}$)의 구조 및 전기적 성질)

  • 형경우;김중헌;권태윤
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.9
    • /
    • pp.930-936
    • /
    • 1999
  • For LiMn2O4 based spinel structures the stoichiometric reaction conditions need be considered carefully because the electrical properties depend on the structural stability. In order to obtain the homogeneous compound the Pechini process was chosen which could obtain a stoichiometry phase even low temperature and dependency of the synthetic condition on structural stability and electrochemical performance was investigated. X-ray diffraction studies showed that the compounds doped with transition metal have smaller lattice constants than those un doped. The dc conductivity was evaluated by a four probe method in the low and high temperature region respectively. The variations of basal spacings for the cathode were detected to be dependent on the extent of current flows (under dc)

  • PDF

Transport Behaviour of Electroactive Species in Ionic Compounds: A Focus on Li Diffusion through Transition Metal Oxide in Current Flowing Condition

  • Lee, Sung-Jai;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
    • /
    • v.12 no.1
    • /
    • pp.1-10
    • /
    • 2009
  • This article reviewed transport behaviours of electroactive species in ionic compounds, focusing on chemical diffusion of Li through the transition metal oxide in a current flowing condition. For this purpose, a distinction has been first briefly made between migration and diffusion with respect to current, driving force and charge of electroactive species considered. Then, the equations for chemical diffusion are derived theoretically in open-circuit and current flowing conditions. Finally, the experimental methods such as ac impedance spectroscopy and current (potential) transient techniques are described in details for characterising chemical diffusion. In addition, the role of the thermodynamic enhancement factor in chemical diffusion is discussed.

Development of Micro Press for Forming the Micro Thin Foil Valve (마이크로 박판 밸브 성형을 위한 마이크로 프레스 개발)

  • Lee, Hye-Jin;Lee, Nak-Kyu;Lee, Hyoung-Wook
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.16 no.5
    • /
    • pp.166-171
    • /
    • 2007
  • In this paper Research development about a micro metal forming manufacturing system has been developed. A micro forming system has been achieved in Japan and it's developed micro press is limited to single forming process. To coincide with the purpose to be more practical, research and development is necessary about the press which the multi forming process is possible. We set the development of the equipment including micro deep drawing, micro punching and micro restriking process to the goal. To achieve this goal, we set the application product to a micro thin foil valve which is used in the micro pump module. The compound die set has been designed and manufactured to make two step process. The material of thin foil valve is SUS-304 and its thickness is 50$\mu$m. We can get a good forming results from micro punching experiments in this paper.