• 제목/요약/키워드: compound materials

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Studies on Microstructural Phenomena Caused by Atomic Diffusion in Sintered Materials

  • Hayashi, Koji
    • 한국분말재료학회지
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    • 제10권6호
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    • pp.374-382
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    • 2003
  • During the sintering of powder materials, many these are microstructural phenomena are caused by atomic diffusion. (1) neck formation and compact densification, (2) grain growth, i.e., growth of matrix grains and dispersed grains, (3) alloying or generation of compound, (4) generations of peculiar and hard layers near sintered compact surface, etc. The studies of the present author and co-workers on these phenomena which were carried out during 40 years are briefly introduced.

1,2-비스(4-피리딜)에탄을 이용한 직선형 착화합물의 구축 (Preparation of Linear Complex Compound with 1,2-Bis(4-pyridyl)ethane)

  • 권윤정
    • 한국염색가공학회지
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    • 제12권4호
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    • pp.264-268
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    • 2000
  • Molecular-based materials with such functions as catalysis, magnetism and coordinate clathrations of one-, two-, and three-dimensional infinite frameworks have been extensively studied. Although rigid bridged ligands were frequently employed to construct these materials, flexible ligands were exploited less for this purpose. A one-dimensional polymer ${[Cd_2(=mu-bpe)_2](\mu-bpe)}(NO_3)_4}_n$ is prepared ; its structure is strikingly characterized by heptacoordinate Cd ions as well as by a unique main framework.

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Ruthenium Complex Catalyzed Synthesis of 2-Substituted Benzoxazoles from o-Aminophenol and Alcohol with Spontaneous Hydrogen Evolution

  • Keun-Tae Huh;Sang Chul Shim
    • Bulletin of the Korean Chemical Society
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    • 제14권4호
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    • pp.449-452
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    • 1993
  • o-Aminophenols react with alcohols in the presense of a catalytic amount of ruthenium catalyst at 180$^{\circ}C$ to give 2-substituted benzoxazole in good yield. The yields of 2-substituted benzoxazoles were affected by the yield of N-alkylation compound from o-aminophenol and alcohol as starting materials. During the reaction, a stoichiometric amount of hydrogen was spontaneously evolved into the gas phase.

New green fluorescent materials for OLEDs

  • Lee, Chil-Won;Lee, Eun-Jung;Kim, Joon-Woo;Yun, Jong-Hyeok;Lee, Jun-Yeob;Gong, Myoung-Seon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.628-631
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    • 2007
  • We developed new green emitting materials based on the spiro moieties. The introduction of a spiro linkage into the structure of DJGH series lead to a reduction in crystallization tendency and an increase in glass transition temperature. they showed much better emitting efficiency and color purity than commercial host material $Alq_3$.

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저탄소강의 질화침탄과 산화처리시 분위기 변화에 따른 조직 및 부식특성에 관한 연구 (A Study on the Corrosion Properties and Microstructure of the Nitrocarburized and Oxidized Low Carbon Steel according to the Treatment Atmospheres)

  • 신평우;이구현;남기석;박율민;조형준
    • 열처리공학회지
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    • 제17권2호
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    • pp.87-93
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    • 2004
  • Nitrocarburizing was carried out with various $CH_4$ gas composition with 4 torr gas pressure at $570^{\circ}C$ for 3 hours and post oxidation was carried out with 100% $O_2$ gas atmosphere with 4 torr at different temperatures for various time. In the case of plasma nitrocarburizing, It is that the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) and ${\gamma}^{\prime}-Fe_4$(C, N), which comprise the compound layer phase, depend on concentrations of $N_2$ gas and $CH_4$ such that when the concentration of $N_2$ and $CH_4$ increased, the ratio of ${\gamma}^{\prime}-Fe_4$(C, N) decreased, but the ratio of ${\varepsilon}-Fe_{2-3}$(N, C) increased. The thickness of compound layer consistently increased as gas concentration increased regardless of $N_2$ and $CH_4$ expect when the concentration of $CH_4$ was 3.5 volume%, it decreased insignificantly. When oxidizing for 15min in the temperature range of $460{\sim}570{^\circ}C$, the study found small amount of $Fe_3O_4$ at the temperature of $460{^\circ}C$ and also found that amounts of $Fe_2O_3$. and $Fe_3O_4$ on the surface and amount of ${\gamma}^{\prime}-Fe_4$(C, N) in the compound layer increased as the increased over $460^{\circ}C$, but the thickness of the compound layer decreased. Corrosion resistance was influenced by oxidation times and temperature.

수열법에 의한 $(Li,Al)MnO_{2}(OH)_{2}$:Co 화합물의 합성 (Hydrothermal synthesis of $(Li,Al)MnO_2(OH)_2$:Co compound)

  • 최종건;황완인;김판채
    • 한국결정성장학회지
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    • 제11권4호
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    • pp.154-159
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    • 2001
  • (Li,Al)$MnO_2(OH)_2$:Co 화합물의 합성르 수열법에 의해 행하였다. 출발원료는 $MnO_2$, LiOH.$H_2$O, $Co_3O_4$, $Al(OH)_3$이 사용되었으며, 단일상의 (Li,Al)$MnO_2(OH)_2$:Co 화합물을 얻을 수 있는 최적의 합성조건은 다음과 같았다. 반응온도 : $200^{\circ}C$ 반응시간 ; 3일간, 반응장치 ; 시이소형, 수열용매 ; 3M-KOH, (Li,Al)$MnO_2(OH)_2$:Co 의 원자비 = 1:2.1:2.5~2:0.5~1. 수열합성된 단사의 (Li,Al)$MnO_2(OH)_2$:Co 화합물은 결정성이 우수하였으며, 청색안료로써 천연 오수에 필적하는 발색효과를 나타내었다. 합성된 (Li,Al)$MnO_2(OH)_2$:Co 화합물의 형태는 육각 판싱이였으며, 입자의 크기는 0.5~1 $\mu\textrm{m}$의 미립자이였다.

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컴파운더 보우 지레 시스템의 기구학적 해석 (Kinematic Analysis of Levering Systems in Compound Bows)

  • 이용성;김홍석;정성균;최웅재;김영근;박경래;신기훈
    • 대한기계학회논문집A
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    • 제37권1호
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    • pp.55-60
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    • 2013
  • 컴파운더 보우는 리커브 보우와 비교하여 케이블 및 캠 풀리로 구성되는 지레시스템을 사용하여, 궁사가 보우를 최대 위치로 당기기 위해 필요로 하는 힘을 줄이는 동시에 더 많은 에너지를 축적할 수 있도록 해준다. 지금까지 컴파운더 보우의 효율 및 성능을 향상시키기 위해 경험적인 방법에 기초하여 많은 특허가 제안되었지만, 해석적인 방법에 대한 연구는 별로 없었다. 그러므로 본 연구에서는 컴파운더 보우 지레 시스템의 기구학적인 해석을 위한 방법을 제안하여 지레시스템의 캠 형상 및 보우 날개의 재질변화에 따른 효과를 설계자가 쉽게 예측할 수 있도록 하고자 한다.

교합관계 기록 재료의 정확성에 관한 임상적 비교 연구 (AN EXPERIMENTAL STUDY ON THE ACCURACY OF INTEROCCLUSAL RECORDING MATERIALS)

  • 박홍렬;장익태;김광남
    • 대한치과보철학회지
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    • 제28권2호
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    • pp.91-108
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    • 1990
  • The purpose of this study was to compare the maganitude of the discrepancies of the mounting errors in according to the states of dentitions, and to the superoinferior, anteroposterior, and rightleft driecetions. GROUP I. : Fourteen patients 22 to 26 years of age with a full complement of teeth, were used in the study. The criteria fro patient selection were a complete dentition, sparse restorarive treatment, and adequate posterior and anterior occlusan stops. And they had no sign and sympton at TMG area. GROUPII. : Eigth patients 37 to 62 years of age with bilateral free ends. The criteria for patient selection were Kennedy classification class 1 cases, and adequate posterior and anterior stops. And the opposite dentitions were a full complement of teeth. Irreversible hydrocolloid impresiion of each arch was taken of each patient. These were immediatel poured in stone and mounted on a Denar Mark II. Articulator with the arbitrary slidematic face-bow. With hand articulation th e mandibular cast was mounted to the maxillary cast in centric occlusion. Five types of interocclusal records were taken of each patient : (1) aluwax (2) baseplate wax; (3) znic oxide-eugenol pasts; (4) polyether (Ramitec); (5) modeling compound. All measurement of the five selected recording materials were compared with those of the hand-articulated full arch models in centric occlusion or maximum interdigitation. The results were as follows; 1. There were statistical differences in amount of devitation in according to the materials and the states of dentition. The amount of deviation of compound was the largest. 2. There were statistical differences in amount of deviation in complete dentition at all directions. The amount of diviation of compound was the largest. And at the right-left direction the amount of znic oxide-eugenol paste was larger than that of baseplate wax. 3. There was a statistical difference in amount of diviations in partial edentulous dentition at the superoinferior direction. The amount of deviation of compound was larger than that of znic oxide-eugenol paste. 4. There was as statistical difference in amount of deviations in partial edentulous dentition at the right-left direction. The amount of deviation of baseplate wax was larger that tnat of polyether. 5. There was not a statistical difference in amount of diviation in partial edentulous dentition at the anteroposterior direction.

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Cu pillar 범프 내의 금속간화합물 성장거동에 미치는 시효처리의 영향 (Effect of Thermal Aging on the Intermetallic compound Growth kinetics in the Cu pillar bump)

  • 임기태;이장희;김병준;이기욱;이민재;주영창;박영배
    • 마이크로전자및패키징학회지
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    • 제14권4호
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    • pp.15-20
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    • 2007
  • 시효처리에 따른 Cu pillar 범프 내 다양한 계면에서의 금속간화합물 성장거동을 각각 120, 150, $165^{\circ}C$의 온도에서 300시간동안 시효처리하면서 연구하였다. 분석 결과 Cu pillar와 SnPb 계면에서는 $Cu_6Sn_5$$Cu_3Sn$이 관찰되었고, 시효처리 시간이 경과함에 따라 parabolic 형태로 성장하였다. 또한 시효처리 온도가 높을수록 시간에 따른 $Cu_6Sn_5$$Cu_3Sn$의 성장속도는 더욱 빨랐다. kirkendall void는 Cu Pillar와 $Cu_3Sn$ 사이의 계면과 $Cu_3Sn$ 내부에서 형성되었고, 시효처리 시간이 경과함에 따라 성장하였다. 리플로우 후에 SnPb와 Ni(P)사이의 계면에서는 $(Cu,Ni)_6Sn_5$가 형성되었고, 시효처리 시간에 따른 $(Cu,Ni)_6Sn_5$거 두께 변화는 관찰되지 않았다. 시효처리 온도와 시간에 따른 금속간화합물의 두께 변화를 이용하여 전체$(Cu_6Sn_5+Cu_3Sn)$금속간화합물과 $Cu_6Sn_5,\;Cu_3Sn$ 금속간화합물의 성장에 대한 활성화 에너지를 구해본 결과 각각 1.53, 1.84, 0.81 eV의 값을 가지고 있었다.

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