• Economic and Environmental Geology
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• v.15 no.3
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• pp.155-166
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• 1982

Sulfur isotope compositions (${\delta}^{34}S$) of seventy one sulfide minerals from the Shinyemi ore deposits were determined to range from -10.1 to +5.0‰ with a mean value of +2.1‰. These values are roughly comparable to those of various hydrothermal ore deposits in Korea, about +2.0 to +7.0‰ in ${\delta}^{34}S$, suggesting that they are to be same in source of sulfur. The Shinyemi deposits are grouped into two types; the western bedded skarn orebodies and the eastern small pipes and veins. The ${\delta}^{34}S$ values of sulfide minerals from the bedded orebodies (early mineralization) are ranging from -10.1 to +2.5‰, which is relatively wide in range, whereas those of the pipes and veins. (later mineralization) have a narrow range of ${\delta}^{34}S$ values, +2.7 to +5.0‰, regardless of the kind of sulfide minerals. Isotopic temperature obtained from the sphalerite-galena mineral pairs of the New B orebody appeared to be about 400 to $540^{\circ}C$ are reasonably good agreement with the comparable data of skarn mineral assemblages. It is concluded that the west orebodies were formed in earlier stage at higher temperatures than the east orebodies formed later at lower temperatures. Judging from the various data from the present study, the Shinyemi deposits can be defined as a typical contact metasomatic deposit. The source of sulfur in the hydrothermal solutions is considered to be comagmatic with the Shinyemi granodiorite.

• Economic and Environmental Geology
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• v.26 no.1
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• pp.11-20
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• 1993

In the present study, three representative hydrothermal clay deposits, named the Seongsan, Ogmaesan and Haenam deposits, were selected for oxygen and hydrogen isotope studies. Oxygen and hydrogen isotopic compositions of quartz, sericite, alunite and kaolin minerals from Seongsan, Ogmaesan, Haenam deposits and surrounded rocks of clay deposits have been measured. The ${\delta}^{18}O$ values of quartz, kaolin, sericite and alunite in the Seongsan mine are +8.4 to +11.1‰, +3.6 to 5.4‰, +4.8 to +5.8‰ and + 3.0 to +6.6‰, respectively. In the Ogmaesan mine, the ${\delta}^{18}O$ values of quartz, kaolin, sericite and alunite are +8.0 to +13.6‰, +2.8 to +6.7‰, +4.8 to +8.4‰ and +0.9 to +2.4‰, respectively. The ${\delta}^{18}O$ values of the Haenam mine range from +7.9 to +10.1‰ for quartz and from +4.5 to +6.5‰ for sericite. The ${\delta}^{18}O$ values of the whole-rocks range from + 3.0 to + 7.8‰ for the granitic rocks. The ${\delta}^{18}O$ values of the whole-rocks range from + 3.2 to + 10.7‰ for the volcanic rocks. The 8D values of kaolin, sericite and alunite in the Seongsan mine are -78 to -86‰, -71 to -90‰ and -43 to -77‰, respectively. In the Ogmaesan mine, the ${\delta}D$ values of kaolin, sericite and alunite are -73 to -80‰, -74 to -88‰ and -57 to -98‰, respectively. The ${\delta}D$ values of the Haenam mine range from -76 to -85‰ for sericite. The ${\delta}D$ values of the whole-rocks range from -77 to -105‰ for the granitic rocks. The ${\delta}D$ values of the wholerocks range from -76 to -100‰ for the volcanic rocks. The main result obtained oxygen and hydrogen isotope data can lead to the following interpretations on the origin of hydrothermal fluids in the clay deposits: Through the oxygen isotopic study, the formation temperature of the clay deposits was estimated from the coexisting minerals such as quartz-kaolin minerals and -sericite. Formation temperature of the acidic alteration zone is 165 to $280^{\circ}C$ in the Seongsan deposits, 175 to $250^{\circ}C$ in the Ogmaesan deposits and 250 to $350^{\circ}C$ in the Haenam deposits. Three clay deposits has been formed by magmatic water mixed with meteoric water. Furthermore, from this isotopic data, it is clarified that kaolin minerals and alunite are hypogene in origin, and has been formed by oxidation of hydrogen sulfide in the steam-heated environment, and that alunite has been produced in the spectacular solfataric alteration observed at the surface of some present-day hydrothermal systems. Oxidation of the $H_2S$ is thought to be generated when the vapor phase generated by boiling of the deep-seated water under the water table.

• Economic and Environmental Geology
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• v.42 no.4
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• pp.289-300
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• 2009

The Geodo mine area, had been developed for Fe and Cu ores since 1963 and abandoned in recent decades, is located in the central part of the Taebaeksan mineralized district. This area comprises of the Jangsan, Myobong, Pungchon, Hwajeol, Dongjeom, and Dumugol Formations in ascending stratigraphic order. These Formations were intruded by the Cretaceous Eopyeong granitoids that appears to produce the Geodo skarn. Their compositions are relatively oxidized quartz monzodiorite to granodiorite (magnetite series, $Fe_2O_3/FeO=0.3{\sim}1.1$). Mineralizations related skarn deposit occur in the Myobong, Pungchon, and Hwajeol Formations. The proximal skarn is zoned from andraditic garnet ($Ad_{44-95}Gr_{1-53}$) predominant adjacent to the Eopyeong granitoids to diopsidic pyroxene ($Hd_{10-100}Di_{0-89}$) predominant away from the one. The differential proportion of garnet and pyroxene is generated by water/rock ratio and their source, such as magmatic and meteoric water. This is useful tool for assessment the overall oxidation state of the entire skarn system. Gold occurs in proximal red to brownish garnet skarn, and genetically associated with Bi- and Te-bearing minerals. Skarn deposit developed in the Geodo mine area is considered as oxidized Au skarn category, based on chemical composition of the Eopyeong granitoids, zonation of skarn, and gold occurrences. Garnet-rich skarn zone will be the main target for exploration of gold in the study area. However, it is needed to the detailed survey on vertical zonation of this area as well as lateral zonation. The result of this survey would provide an important basis for the exploration of the skarn Au deposit in the Geodo mine area.

• Economic and Environmental Geology
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• v.42 no.2
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• pp.121-131
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• 2009

The distribution characteristics of heavy metals for surface sediments in east oceanic dumping area (EDA) and west oceanic dumping area (WDA) are evaluated by grain sizes, minerals, sedimentation rates and compositions of heavy metals. The mean grain sizes in EDA and WDA range from $7.95{\Phi}$ to $8.51{\Phi}$ and $7.42{\Phi}$ to $8.15{\Phi}$, respectively. These are mostly belonging to the M (mud) type. Minerals in the surface sediments consist of illite with chlorite, smectite, and kaolinite. Sedimentation rates estimated by $^{210}Pb$ method in EDA and WDA are 1.11 mm/yr$\sim$1.73 mm/yr and 1.87 mm/yr, respectively. According to the interrelationship, concentrations of Ni, Cu, Cr, and Zn are closely associated with mean grain size, Al, and Fe, whereas concentrations of Cd and Pb are poorly associated with ones. The enrichment factors of these elements are higher than 1.5, suggesting that the concentrations of Cd and Pb in the surface sediments are affected by anthropogenic sources. The $I_{geo}$-class numbers of Cd and Pb in the surface sediments are mostly classified in 2 to 4, showing moderate to strongly polluted. These numbers in EDA are higher than that of WDA, and the highest number is 4, indicative of the strongly polluted class. Our results show that the disposed wastes at EDA include mineralogical wastes, dredged materials from sewage disposals, and sludges from constructions having materials of WDA. The annual amount of oceanic dumping in EDA is double than that in WDA.

• Economic and Environmental Geology
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• v.50 no.4
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• pp.303-311
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• 2017

The laboratory scale experiment was performed to evaluate the sealing capacity of the capping rock such as tuff and mudstone, measuring the intial supercritical $CO_2$ ($scCO_2$) injection pressure and the $scCO_2$-water-rock reaction for 90 days. The drilling cores sampled from 800 m in depth around the Janggi basin, Korea were used for the experiment. The mineralogical changes of mudstone and tuff were measured to evaluate the geochemical stability during the $scCO_2$-water-rock reaction at $CO_2$ storage condition (100 bar and $50^{\circ}C$). The rock core was fixed in the high pressurized stainless steel cell and was saturated with distilled water at 100 bar of pore water pressure. The effluent of the cell was connected to the large tank filled with 3 L of water and 2 L of $scCO_2$ at 100 bar, simulating the subsurface injection condition. The $scCO_2$ injection pressure, which was higher than 100 bar, was controlled at the influent port of the cell until the $scCO_2$ begin to penetrate into the rock and the initial injection pressure (> 100 bar) of $scCO_2$ into the rock was measured for each rock. The mineralogical compositions of mudstones after 90 days reaction were similar to those before the reaction, suggesting that the mudstone in the Janggi basin has remained relatively stable for the $scCO_2$ involved geochemical reaction. The initial $scCO_2$ injection pressure (${\Delta}P$) of a tuff in the Janggi basin was 15 bar and the continuous $scCO_2$ injection into the tuff core occurred at higher than 20 bar of injection pressure. For the mudstone in the Janggi basin, the initial $scCO_2$ injection pressure was higher than 150 bar (10 times higher than that of the tuff). From the results, the mudstone in Janggi basin was more suitable than the tuff to shield the $scCO_2$ leakage from the reservoir rock at subsurface.

• Journal of Environmental Impact Assessment
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• v.26 no.6
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• pp.404-417
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• 2017

In this study, we analyzed response patterns of rotifer community to eutrophic state, and estimated the applicability of rotifer community as an environmental indicator for highly eutrophicated reservoirs. In order to evaluate the relationships among spatial and temporal distributions and the water quality of rotifer community, we selected the Jundae Reservoir and Chodae Reservoir in Chungcheongnam-do, Korea, which are geographically adjacent but have different water quality, particularly in their eutrophic states. For the analyses on their correlations, monthly survey of water quality and rotifer community, was conducted from April to November 2013 in both reservoirs. The rotifer community was divided into different compositions of functional groups as well as species. Functional groups were classified according to the structure and shape of trophi which can represent feeding behavior of rotifer genus. To reflect ecological characteristics of species, body size and habitat preferences were also considered. Species-based composition did not show a consistent tendency with water quality parameters related with eutrophication. On the contrary, functional group composition showed relatively clear group-specific patterns, increasing or decreasing according to the parameters. The results suggest the possible application of rotifer functional group composition as an indicatorforthe lentic systems, especially hyper-eutrophicated reservoirs. The present study can suggest the applicability based on the field observations from the limited time scale and sites, and further studies on feeding behavior of the rotifer functional group and its interactions with environmental variables are necessary for the further application.

• Journal of Animal Environmental Science
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• v.17 no.1
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• pp.11-22
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• 2011

This work was carried out to investigate the quantity of manure excreta and characteristics in growth and production phase of Holstein dairy cattle. The average manure production of dairy cattle under condition of ad libitum feeding was 41.5 kg/head/day (feces 24.9, urine 16.4 kg). The average moisture contents of feces and urine were 85.0% and 93.9%, respectively. Water pollutant concentration, $BOD_5$, $COD_{Mn}$ and SS excreted from dairy cattle were 15,444 mg/${\ell}$, 53,159 mg/${\ell}$, and 40,528 mg/${\ell}$ in feces and 8,454 mg/${\ell}$1,116 mg/${\ell}$, and 962 mg/${\ell}$in urine, respectively. And The daily loading amount of $BOD_5$, $COD_{Mn}$, SS in dairy cattle manure were 523 g, 1,416 g and 1,025 g, respectively. N, P and K contents of manure produced by dairy cattle were 0.33, 0.49 and 0.20% in feces, and 1.02, 0.27 and 1.03 in urine, respectively. In the concentrations of mineral and heavy metal of manure, Ca, Na and Mg contents were 1.56, 0.24 and 0.69%, and Zn, Cu, Cr, Pb and As were 69.23, 19.14, 2.89, 7.73 and 2.94 ppm, respectively. In conclusion, Dairy farms can be estimated optimum nutrient and pollutant balance to effectively manage the manure produced.

• Korean Journal of Food Science and Technology
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• v.12 no.3
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• pp.185-192
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• 1980

To study lipid components of Panax ginseng produced in Korea, the lipids of fresh ginsengs were extracted with the mixture of chloroform-methanol (2:1, v/v) and those of dried ginsengs were extracted with diethyl ether respectively. The lipid components extracted were separated and quantitated by column, thin layer and gas-liquid chromatographies. The results were summarized as follows : 1. Fresh ginseng contained 0.62% total lipid of which 45.28% were neutral lipids, 18.12% glycolipids, and 36.60% phospholipids. But dried ginseng contained 0.89% total lipids of which 86.48% were neutral lipids, 9.20% glycolipids, and 4.32% phospholipids. 2. Triglycerides (37.6 to 42.5% of the total neutral lipids) and sterol esters (16.5 to 19.6%) in all the fresh and dried ginseng were the major components among the neutral lipids. Monoglycerides, diglycerides, free fatty acids and free sterols were minor components. 3. Digalactosyl diglycerides (23.5% of the total glycolipids) in the fresh ginseng and steryl liglycosides (28.9%) in the dried ginseng were predominant components among the glycopids, respectively, Esterified steryl glycosides and monogalactosyl diglycerides were also identified, and four unknown spots in the fresh ginseng and two unknown spots in the dried ginseng were present. 4. Phosphatidyl cholines (31.3 to 31.9% of the total phospholipids) and phosphatidyl glycerols (34.8 to 36.7%) in all the fresh and dried ginseng were the major components among the phospholipids. Phosphatidyl inositols and phosphatidyl ethanolamines were also identified. 5. The major fatty acids in the fresh and dried ginseng were linoleic $(62.29{\sim}64.32%)$, palmitic $(13.16{\sim}15.63%)$, oleic $(5.73{sim}7.23%)$ and linolenic $(5.73{sim}7.23%)$. The fatty acid compositions in neutral lipid fraction was similar to the pattern in those of the total lipids. But glycolipid and phospholipid fractions contained a lower percent of linoleic acid and a higher percent of palmitic acid than the neutral lipid fraction.

• Journal of The Korean Society of Grassland and Forage Science
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• v.9 no.1
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• pp.34-42
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• 1989

This pot experiments were conducted to find out the optimal fertilization ratios of ${\Sigma}anion$ : ${\Sigma}cation$, ${\Sigma}A$/${\Sigma}C$, and the optimal application rates of total major nutrients in an orchardgrass/ladino clover mixed sward. The optimum ratios and concentrations in equivalent basis were computed by the Homes systematic variations technique. The results were summarized as follows; 1. The optimum fertilization ratios of ${\Sigma}A$ : ${\Sigma}C$ and the optimum application rates of total nutrients for the high yields by forage species in a mixed sward were obtained (Table 6 in detail); ${\Sigma}A$ : ${\Sigma}C$ = 2 : 1 at 80 and 320 meq/pot, and 3 : 2 at 560 and 800 meq for grass and grass plus legume, and ${\Sigma}A$ : ${\Sigma}C$ = 1 : 2 for legume in general. 2. The optimum application rates of total nutrients for the high yields of grass and grass plus kgum were increased by decreasing the ${\Sigma}A$/ ${\Sigma}C$: ratio, whereas these for legume showed a valible. range without significance. 3. The yields 01 grass and grass plus legume were generally increasing by increasing both the ${\Sigma}A$/ ${\Sigma}C$ ratio and total concentration, but they were significantly higher at the ${\Sigma}A$/ ${\Sigma}C$ = 1.273 than at the 2.125 under the high total ion concentration. The legume yields were proportional to ${\Sigma}C$ ratio and increased by increasing the total ion concentration under the condition of high ${\Sigma}C$ ratio. 4. The efficiencies of ${\Sigma}A$ and ${\Sigma}C$ in relation to the grass and grass plus legume yields were highest with the low ratios of each other and the low rates of total nutrients ${\Sigma}A$ efficiency m the legume yield tended to be similar to that of ${\Sigma}A$ in the grass yield noted above. The ${\Sigma}C$ efficiency in the legume yield, however, was generally proportional to the ${\Sigma}C$ ratio except at the low rate of 80 meqlpot. 5. The yields of grass plus legume, yield components and botanical compositions in a mixed sward were greatly influenced by the ${\Sigma}A$/${\Sigma}C$ ratios, the fertilization rates of total nutrients, and the interaction of ratio and rate noted above. These effects were generally different and opposite accading to grass and legume. In addition, the soil chemical properties and mineral contents of forages were partially influenced by these systematic variations.

• Journal of The Korean Society of Grassland and Forage Science
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• v.8 no.3
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• pp.92-98
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• 1988

With a purpose of finding out the effects of magnesium and boron enriched organic-compound fertilizer application on the dry matter yield, yield components and changes in the botanical composition on the hilly pasture, a field experiment was arranged with five different treatments as a randomized block design and lasted from September, 1984 to the end of growing season in 1986. The results obtained are summarized as follows : 1. As a early plant growth and development, winter hardiness, growth vigour and coverage of grasses at the plots with organic-compound fertilizer application were better comparing to single dressing. 2. Average dry matter yields for two years were shown significantly high due to increasing amount of fertilizer. This trend was same both single and organic-compound fertilizer. And dry matter yields with organic-compound fertilizer application of low (8, 693.1 kg/ha) and conventional level (12, 758.7 kg/ha) were appeared to increase by 10 and 15% than those of single dressing of Low (7, 930.6 kg/ha) and conventional level (11, 122.6 kg/ha), respectively. But it was not significant difference. 3. Dry matter yield of grasses was significantly gained by increasing amount of fertilizer. The yield of legumes at the plot without fertilization was significant higher comparing to fertilizing plots, but it was not different between low and conventional dressing levels. However, at the plots with organic-compound fertilizer application the yields of grasses were a little more increased by 8-14%, and legumes were much more gained by 26-29% than those of the same species groups with single dressing, but it was not significant between the different kinds of fertilizer in the same fertilizing level. 4. At the grassland management, the rate of legumes tended to dominate at the plot without fertilization gradually. On the other hand, the botanical compositions and the rates of grasses were much better maintained at the plots with fertilization. But the rates of legumes with organic-compound fertilizer application tended to increase a little more than those of single dressing gradually.