• 제목/요약/키워드: composite inorganic fiber

검색결과 37건 처리시간 0.025초

난연성 폴리아크릴로니트릴 고분자 섬유 및 복합소재 연구 동향 (A Review of Flame Retarding Polyacrylonitrile (PAN) Fibers and Composites)

  • 김종호;구본철
    • Composites Research
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    • 제32권6호
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    • pp.342-348
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    • 2019
  • 고분자 재료의 사용이 늘어남에 따라 난연성 고분자 재료에 대한 연구가 더욱 활발히 진행되고 있다. 고분자 재료의 난연성 향상을 위한 방법으로 제조된 섬유의 후처리 또는 섬유내 난연제의 도입에 관한 연구가 진행되고 있다. 많은 고분자들 중 탄소섬유 전구체인 폴리아크릴로니트릴(PAN)은 의류용으로도 많이 사용되고 있어서 낮은 난연성을 지닌 PAN으로 이루어진 소재의 난연성 향상이 절실히 요구되고 있다. 본 총설 논문에서는 PAN 섬유의 후처리(안정화 또는 화학반응)을 통한 난연성 PAN 섬유와, 유/무기 소재(실리카, 2차원 소재, 탄소나노튜브)과 함께 혼합하여 섬유로 제조하는 난연성 PAN 복합소재의 제조에 대한 연구를 소개하고자 한다.

유·무기섬유 혼입비 및 혼입율 변화에 따른 HPFRCC의 기초물성 변화 (Changing Fundamental Properties of HPFRCC Depending on Combination and Content of Organic and Inorganic Fibers)

  • 이제현;문병룡;박용준;조성준;김종;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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    • pp.28-29
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    • 2016
  • Recently, the attention on high tensile, and high performance cementitious composite (HPFRCC) which can minimize the damage from explosion of inflammable gas and chemicals has been increased. In spite of outstanding tensile performance, HPFRCC has the drawbacks of fiber ball, undesirable cost, and high autogenous shrinkage. therefore, in this research, to develop the optimum HPFRCC, the fundamental properties and autogenous shrinkage of HPFRCC was analyzed depending on various combination and content of organic and inorganic fibers.

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Glass Fiber Post와 Composite Resin Core의 전단결합강도 (A STUDY FOR THE BONDING STRENGTH OF COMPOSITE RESIN CORE TO GLASS FIBER POST)

  • 김태형;심준성;이근우
    • 대한치과보철학회지
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    • 제43권4호
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    • pp.415-425
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    • 2005
  • Statement of problem : Fracture of composite resin core will be occulted by progress of crack. Bonding interface of different materials has large possibility of starting point of crack line. Therefore, the bond strength of glass fiber post to composite resin core is important for prevention of fracture. Purpose: This in vitro study tried to find out how to get the higher strength of glass fiber post to composite resin core through surveying the maximum load that fractures the post and cote complex. Materials and methods: 40 specimens made with glass fiber Posts(Style $post^{(R)}$, Metalor, Swiss) and composite resin core ($Z-100^{(R)}$, 3M, USA) were prepared and loaded to failure with push-out type shear-bond strength test in a universal test machine. The maximum fracture load and fracture mode were investigated in the specimens that were restored with four different surface treatments. With the data. ANOVA test was used to validate the significance between the test groups, and Bonferroni method was used to check if there is any significant statistical difference between each test group. Evely analysis was approved with 95% reliance. Results: On measuring the maximum fracture load of specimens, both the treatments of sandblasted and acid-etched one statistically showed the strength increase rather than the control group (p<0.005). The scanning electric microscope revealed that sand blasting made more micro-retention form not only on the resin matrix but on the glass fiber, and acid-etching contributed to increase in surface retention form, eliminated the inorganic particles in resin matrix. Specimen fracture modes investigation represented that sand blasted groups showed lower bonding failure than no-sand blasted groups. Conclusion: Referring to the values of maximum fracture load of specimens, the bonding strength was increased by sand blasting and acid-etching.

저탄소 무기결합재의 섬유보강에 따른 강도 특성에 관한 연구 (A Study on the Strength Properties as according to the Fiber Reinforced of Low Carbon Inorganic Composite)

  • 문지환;이윤성;이강필;김상철;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 춘계 학술논문 발표대회 1부
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    • pp.59-60
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    • 2011
  • The purpose of this study is to produce the low-carbon eco-friendly inorganic composite at room temperature by an alkali accelerator without firing process at high temperature, and complement the problem of previous studies, the deterioration in strength caused by cracking, with incorporation of PVA fibers. Results of reviewing the changes in the strength properties of PVA showed that test body mixed with PVA fibers had the superiority in strength expression.

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유-무기 하이브리드 형 Abaca 셀룰로오스/이산화 티타늄 복합체의 제조 및 이의 광촉매적 특성 (Preparation and Photocatalyric Properties of Organic-Inorganic Hybrid Abaca Cellulose@Titanium Dioxide Composite)

  • 강수아;김영호
    • 공업화학
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    • 제34권1호
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    • pp.57-63
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    • 2023
  • 본 연구에서는 Abaca 나노 셀룰로오스와 이산화 티타늄(TiO2)의 유-무기 하이브리드 복합체를 제조하였다. Abaca 나노 셀룰로오스는 Abaca 셀룰로오스를 산화시키는 방법으로 제조하였으며, 촉매로서 TEMPO (2,2,6,6-tetramethyl-piperidine-1-oxyl)를 이용하였다. TiO2 나노입자는 sol-gel법으로 제조하였으며 이를 나노 셀룰로오스와 하이브리드(hybrid) 시켜 복합체를 제조하였다. 제조 pH 변화에 따른 복합체의 특성과 그의 물성을 비교해 본 결과, 나노 셀룰로오스와 이산화 티타늄 결합 시 pH의 영향이 매우 컸으며, 본 실험 조건에서 pH 8에서 최적의 결합성능을 나타냈다. 또한, 제조된 복합체는 광촉매 특성을 보였으며, 이산화 티타늄의 함량이 높을수록 UV광 조사에 따라 복합체의 친수성이 증가하였다.

Titanium Dioxide Nanofibers Prepared by Using Electrospinning Method

  • Ding, Bin;Kim, Chul Ki;Kim, Hak Yong;Seo, Min Kang;Park, Soo Jin
    • Fibers and Polymers
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    • 제5권2호
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    • pp.105-109
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    • 2004
  • The synthesis of titanium dioxide nanofibers with 200-300nm diameter was presented. The new inorganic-organic hybrid nanofibers were prepared by sol-gel processing and electrospinning technique using a viscous solution of titanium isopropoxide (TiP)/poly(vinyl acetate) (PVAc). Pure titanium dioxide nanofibers were obtained by high temperature calcination of the inorganic-organic composite fibers. SEM, FT-IR, and WAXD techniques were employed to characterize these nanofibers. The titanium dioxide nanostructured fibers have rougher surface and smaller diameter compare with PVAc/TiP composite nanofibers. The anatase to rutile phase transformation occurred when the calcination temperature was increased from $600^{\circ}C$ to $1000^{\circ}C$.

Heat-ray Shielding Property of Nanocomposites of Poly(acrylic acid) Doped with Copper Sulfide

  • Gotoh, Yasuo;Shibata, Kazuaki;Fujimori, Yoshie;Ohkoshi, Yutaka;Nagura, Masanobu
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.71-72
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    • 2003
  • The aim of our study is to prepare nanocomposites consisting polymer/inorganic nanoparticles and investigate their physical properties as a functional material. In this study, a nanocomposite of copper sulfide (CuS) nanoparticles introduced into a poly(acrylic acid) matrix was prepared and the optical absorption property was measured. The composite exhibited strong absorption of both ultraviolet and near-infrared rays, indicating that the composite is applicable to a solar radiation shielding filter. The wavelength of the near infrared absorption was controlled from ca.1000 nm to 1700 nm by heat and acidic solution treatments.

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플라즈마 표면처리 기법에 의한 무기절연물의 젖음성 변화에 관한 연구 (A Study on the Wettability of Inorganic Insulator due to Plasma Surface Treatment Technique)

  • 황영한;엄무수;박홍태;이규철;이종호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1292-1294
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    • 1994
  • With the contact angle of phase epoxy resin on the inorganic filler(glass plate) surface treated with air plasma, we have studied about the interface between epoxy resin and glass plate as simple model of a glass fiber reinforced composite materials. The contact angle on the inorganic filler surface varied with surface treatment conditions. The contact angle significantly depends on plasma treating time and environment temperature of the oven.

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무기절연물 표면상의 젖음성 변화에 관한 연구 (A Study on the Surface Wettability of Inorganic Insulator)

  • 황영한;엄무수;이규철;이종호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1993년도 하계학술대회 논문집 B
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    • pp.1233-1235
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    • 1993
  • With the Contact angle of phase epoxy resin on the inorganic filler(glass plate) surface treated with air plasma, we have studied about the interface between epoxy resin and glass plate as simple model of a glass fiber reinforced composite materials. The contact angle on the inorganic filler surface varied with ambient temperature and surface treatment conditions.

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