• Title/Summary/Keyword: composite coatings

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Effects of Interphase Condition and Short-fiber Content on the Fatigue Properties of Reinforced Rubber (계면상 조건과 단섬유 함유량이 강화고무의 피로특성에 미치는 영향)

  • 류상렬;이동주
    • Composites Research
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    • v.13 no.5
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    • pp.10-17
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    • 2000
  • The fatigue properties of short nylon66 fiber reinforced Chloroprene rubber have been investigated as functions of interphase conditions and fiber content. The spring constant of rubber decreased about 21% after the fatigue test. On the contrary, that of reinforced rubber increased in all cases. The changing rate of spring constant for reinforced rubber decreased with increasing fiber content. This means that the better interphase condition, the smaller changing rate of spring constant. Temperature of matrix increased about 2.5 times and one of reinforced rubber showed 1.7∼2 times up after the test. The changing rate of temperature for reinforced rubber during fatigue test decreased with increasing fiber content. It is found that the better interphase condition, the smaller changing rate of specimen temperature at the same fiber content. Double coatings of bonding agent 402 and rubber solution became the best interphase model in this study. And, we have investigated the possibility of applying short-fiber reinforced rubber to automotive engine mount rubber, bush and stopper.

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Manufacturing and Properties of Low Vacuum Plasma Sprayed W-Carbide Hybrid Coating Layer (진공 플라즈마 스프레이 공정을 이용한 W계 복합 코팅층의 제조 및 특성 연구)

  • Cho, Jin-Hyeon;Jin, Young-Min;Ahn, Jee-Hoon;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.226-237
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    • 2011
  • W-ZrC and W-HfC composite powders were fabricated by the Plasma Alloying & Spheroidization (PAS) method and the powders were sprayed into hybrid coating layers by using Low Vacuum Plasma Spray (LVPS) process, respectively. Microstructure, mechanical properties, and ablation characteristics of the fabricated coating layers were investigated. The LVPS process led to successful production of W-Carbide hybrid coatings, approximately 400 ${\mu}M$ or above in thickness. As the substrate preheating temperature increased from $870^{\circ}C$ to $917^{\circ}C$, the hardness of the W-ZrC coating layer increased due to decreased porosity. Vickers hardness showed higher value (about 108.4 HV) in W-ZrC hybrid coating material compared to that of W-HfC while adhesive strength was found to be similar in both coating layers. The plasma torch test revealed good ablation resistance of the W-Carbide hybrid coating layers. The relatively high performance W-ZrC coating layer at the elevated temperature is thought to be attributed to both the strengthening effect of ZrC particle remained in the layer and the formation of ZrO2 phase with high temperature stability.

Development of High Entropy Alloy Film using Magnetron Sputtering

  • Kim, Young Seok;Lim, Ki Seong;Kim, Ki Buem
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.129-129
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    • 2018
  • Hard coating application is effective way of cutting tool for hard-to-machine materials such as Inconel, Ti and composite materials focused on high-tech industries which are widely employed in aerospace, automobile and the medical device industry also Information Technology. In cutting tool for hard-to-machine materials, high hardness is one of necessary condition along with high temperature stability and wear resistance. In recent years, high-entropy alloys (HEAs) which consist of five or more principal elements having an equi-atomic percentage were reported by Yeh. The main features of novel HEAs reveal thermodynamically stable, high strength, corrosion resistance and wear resistance by four characteristic features called high entropy, sluggish diffusion, several-lattice distortion and cocktail effect. It can be possible to significantly extend the field of application such as cutting tool for difficult-to-machine materials in extreme conditions. Base on this understanding, surface coatings using HEAs more recently have been developed with considerable interest due to their useful properties such as high hardness and phase transformation stability of high temperature. In present study, the nanocomposite coating layers with high hardness on WC substrate are investigated using high entropy alloy target made a powder metallurgy. Among the many surface coating methods, reactive magnetron sputtering is considered to be a proper process because of homogeneity of microstructure, improvement of productivity and simplicity of independent control for several critical deposition parameters. The N2 is applied to reactive gas to make nitride system with transition metals which is much harder than only alloy systems. The acceleration voltage from 100W to 300W is controlled by direct current power with various deposition times. The coating layers are systemically investigated by structural identification (XRD), evaluation of microstructure (FE-SEM, TEM) and mechanical properties (Nano-indenter).

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Modification of glass fiber bundle with functionalized coupling agents and phenolic resin (기능성 커플링제와 페놀수지에 의한 유리섬유 다발의 표면개질 연구)

  • Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.168-175
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    • 2016
  • The surface of glass fiber bundle was modified with functionalized silanes and phenolic resin to improve the tensile strength as well as the adhesion of glass fiber to matrix phenolic resin. The surface modification of reinforcing glass fiber can play a significant role in controlling whole composite characteristics. We applied surface modification of glass fiber with two different functionalized silanes, such as glycidyltrimethoxysilane(G-silane) and aminopropyltriethoxysilane (A-silane), and phenol formaldehyde(PF) resin in one pot or separated process under different coating compositions and temperatures. Thermal treatment temperature is very important factor to improve the mechanical properties of modified glass fiber. Modified glass fiber bundle treated at $170^{\circ}C$ showed the highest tensile strength of $10.05g_f/D$. Surface analyses by scanning electron microscope(SEM) and FT-IR spectroscopy were used to characterize the surface coatings on glass fiber bundles. Mechanical property changes as functions of treatment conditions and coupling agent types were also explained.

Adhesive Bonding Properties between NBR and Polyamide Woven Fabric with Atmospheric Pressure Plasma Treatment (대기압 플라즈마 처리한 폴리아미드 직물과 NBR의 접착특성)

  • Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Composites Research
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    • v.23 no.6
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    • pp.32-38
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    • 2010
  • The effect of the atmospheric pressure plasma(APP) treatments is experimentally investigated to ascertain the optimum condition to yield the best adhesive properties between a polyamide woven fabric and acrylonitrile butadiene rubber(NBR). For the atmospheric pressure flame plasma(APFP) treatment, the optimum number of treatment at given conditions is 2 times. The thermal deformation of the fabric is more serious with increasing the number of APFP treatment. The adhesive strength of the case with APFP treated fabric is increased about 35% when compare to the case with non-APFP treated one for the interface(bonding agent one or two coatings). When the surface is coated twice with the bonding agent, the adhesive energy with APFP treated fabric is increased about 4 times. It was found that the surface modification of polyamide woven fabric by APFP treatment is a fast, economic and applicable method to improve the adhesive properties between woven fabric and rubber when compared to other APP treatments.

Effect of Gamma Ray Irradiation on the Mechanical and Thermal Properties of MWNTs Reinforced Epoxy Resins

  • Shin, Bum Sik;Shin, Jin Wook;Jeun, Joon Pyo;Kim, Hyun Bin;Oh, Seung Hwan;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.137-143
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    • 2011
  • Epoxy resins are widely used as high performance thermosets in many industrial applications, such as coatings, adhesives and composites. Recently, a lot of research has been carried out in order to improve their mechanical properties and thermal stability in various fields. Carbon nanotubes possess high physical and mechanical properties that are considered to be ideal reinforcing materials in composites. CNT-reinforced epoxy system hold the promise of delivering superior composite materials with their high strength, light weight and multi functional features. Therefore, this study used multi-walled carbon nanotubes (MWNT) and gamma rays to improve the mechanical and thermal properties of epoxy. The diglycidyl ether of bisphenol A (DGEBA) as epoxy resins were cured by gamma ray irradiation with well-dispersed MWNTs as a reinforcing agent and triarylsulfonium hexafluoroantimonate (TASHFA) as an initiator. The flexural modulus was measured by UTM (universal testing machine). At this point, the flexural modulus factor exhibits an upper limit at 0.1 wt% MWNT. The thermal properties had improved by increasing the content of MWNT in the result of TGA (thermogravimetric analysis). However, they were decreased with increasing the radiation dose. The change of glass transition temperature by the radiation dose was characterized by DMA (dynamic mechanical analysis).

Nanocellulose-based Polymer Composites with Their Properties and Applications (나노셀룰로오스 기반 고분자 복합소재의 특성 및 응용)

  • Se Hun Kim;Young Jae Kwon;Yamini Sharma;MinYoung Shon;Sangho Cho;Kyung-Youl Baek;Kie Yong Cho
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.221-225
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    • 2023
  • Celluloses are naturally occurring polymers that can be easily obtained from various natural sources. Nanocellulose, a form of cellulose, can be derived from regular cellulose and has unique properties that make it ideal for multiple industrial applications. Nanocellulose is a renewable, sustainable, and eco-friendly composite material with exceptional mechanical properties and thermal stability, surpassing metal and ceramic composites. As a result, nanocelluloses are being extensively studied for their potential applications, including fillers, packaging, energy, medicine, and coatings. This review aims to summarize the current research on nanocelluloses and their applications.

Tribological Behavior Analysis of WC-Ni-Cr + Cr3C2 and WC-Ni-Cr + YSZ Coatings Sprayed by HVOF (고속 화염 용사법으로 제조된 WC계 Cr3C2 코팅과 WC계 YSZ 코팅의 마찰 및 마모 거동 연구)

  • Tae-Jun Park;Gye-Won Lee ;Yoon-Suk Oh
    • Journal of Powder Materials
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    • v.30 no.5
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    • pp.415-423
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    • 2023
  • With the increasing attention to environmental pollution caused by particulate matter globally, the automotive industry has also become increasingly interested in particulate matter, especially particulate matter generated by automobile brake systems. Here, we designed a coating composition and analyzed its mechanical properties to reduce particulate matter generated by brake systems during braking of vehicles. We designed a composition to check the mechanical properties change by adding Cr3C2 and YSZ to the WC-Ni-Cr composite composition. Based on the designed composition, coating samples were manufactured, and the coating properties were analyzed by Vickers hardness and ball-on-disk tests. As a result of the experiments, we found that the hardness and friction coefficient of the coating increased as the amount of Cr3C2 added decreased. Furthermore, we found that the hardness of the coating layer decreased when YSZ was added at 20vol%, but the friction coefficient was higher than the composition with Cr3C2 addition.

Nonlocal bending, vibration and buckling of one-dimensional hexagonal quasicrystal layered nanoplates with imperfect interfaces

  • Haotian Wang;Junhong Guo
    • Structural Engineering and Mechanics
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    • v.89 no.6
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    • pp.557-570
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    • 2024
  • Due to interfacial ageing, chemical action and interfacial damage, the interface debonding may appear in the interfaces of composite laminates. Particularly, the laminates display a side-dependent effect at small scale. In this work, a three-dimensional (3D) and anisotropic thick nanoplate model is proposed to investigate the effects of imperfect interface and nonlocal parameter on the bending deformation, vibrational response and buckling stability of one-dimensional (1D) hexagonal quasicrystal (QC) layered nanoplates. By combining the linear spring model with the transferring matrix method, exact solutions of phonon and phason displacements, phonon and phason stresses of bending deformation, the natural frequencies of vibration and the critical buckling loads of 1D hexagonal QC layered nanoplates are derived with imperfect interfaces and nonlocal effects. Numerical examples are illustrated to demonstrate the effects of the imperfect interface parameter, aspect ratio, thickness, nonlocal parameter, and stacking sequence on the bending deformation, the vibrational response and the critical buckling load of 1D hexagonal QC layered nanoplate. The results indicate that both the interface debonding and nonlocal effect can reduce the stiffness and stability of layered nanoplates. Increasing thickness of QC coatings can enhance the stability of sandwich nanoplates with the perfect interfaces, while it can reduce first and then enhance the stability of sandwich nanoplates with the imperfect interfaces. The biaxial compression easily results in an instability of the QC layered nanoplates compared to uniaxial compression. QC material is suitable for surface layers in layered structures. The mechanical behavior of QC layered nanoplates can be optimized by imposing imperfect interfaces and controlling the stacking sequence artificially. The present solutions are helpful for the various numerical methods, thin nanoplate theories and the optimal design of QC nano-composites in engineering practice with interfacial debonding.

Low Cycle Fatigue Life Behavior of GFRP Coated Aluminum Plates According to Layup Number (적층수에 따른 GFRP 피막 Al 평활재의 저주기 피로수명 평가)

  • Myung, Nohjun;Seo, Jihye;Lee, Eunkyun;Choi, Nak-Sam
    • Composites Research
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    • v.31 no.6
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    • pp.332-339
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    • 2018
  • Fiber metal hybrid laminate (FML) can be used as an economic material with superior mechanical properties and light weight than conventional metal by bonding of metal and FRP. However, there are disadvantages that it is difficult to predict fracture behavior because of the large difference in properties depending on the type of fiber and lamination conditions. In this paper, we study the failure behavior of hybrid materials with laminated glass fiber reinforced plastics (GFRP, GEP118, woven type) in Al6061-T6 alloy. The Al alloys were coated with GFRP 1, 3, and 5 layers, and fracture behavior was analyzed by using a static test and a low cycle fatigue test. In the low cycle fatigue test, strain - life analysis and the total strain energy density method were used to analyze and predict the fatigue life. The Al alloy did not have tensile properties strengthening effect due to the GFRP coating. The fatigue hysteresis geometry followed the behavior of the Al alloy, the base material, regardless of the GFRP coating and number of coatings. As a result of the low cycle fatigue test, the fatigue strength was increased by the coating of GFRP, but it did not increase proportionally with the number of GFRP layers.