• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.921-923
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• 2002

• Bulletin of the Korean Chemical Society
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• v.22 no.1
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• pp.113-116
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• 2001

• Korea-Australia Rheology Journal
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• v.16 no.1
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• pp.17-26
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• 2004

We examine rigorous computations on microstructural as well as rheological properties of concentrated dispersions of bidisperse colloids. The NVT Monte Carlo simulation is applied to obtain the radial distribution function for the concentrated system. The long-range electrostatic interactions between dissimilar spherical colloids are determined using the singularity method, which provides explicit solutions to the linearized electrostatic field. The increasing trend of osmotic pressure with increasing total particle concentration is reduced as the concentration ratio between large and small particles is increased. From the estimation of total structure factor, we observe the strong correlations developed between dissimilar spheres. As the particle concentration increases at a given ionic strength, the magnitude of the first peak in structure factors increases and also moves to higher wave number values. The increase of electrostatic interaction between same charged particles caused by the Debye screening effect provides an increase in both the osmotic pressure and the shear modulus. The higher volume fraction ratio providing larger interparticle spacing yields decreasing high frequency limit of the shear modulus, due to decreasing the particle interaction energy.

• Fibers and Polymers
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• v.2 no.2
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• pp.64-70
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• 2001

A three-dimensional, porous collagen/chitosan complex sponge was prepared to closely simulate basic extracellular matrix (ECM) constitutes, collagen and glycosaminoglycan. The complex sponge was prepared by a lyophilization method and had the regular network with highly porous structure, suitable for cell adhesion and growth. The pores were well interconnected, and their distribution was fairly homogeneous. The complex sponge was crosslinked using 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide (EDC) and N-hydroxysuccinimide (NHS) to increase its boilogical stability and enhance its mechanical properties. The crosslinking medium has a great effect on the inner structure of the sponge. The homogeneous, porous structure of the sponge was remarkably collapsed in an aqueous crosslinking medium. However, the morphology of the sponge remained almost intact in a water/ethanol mixture crosslinking milieu. Mechanical properties of the collagen/chitosan sponge were significantly enhanced by EDC-mediated crosslinking. The potential of the sponge as a scaffold for tissue engineering was investigated using a Chinese hamster ovary cell (CHO-K1) line.

• Journal of Electrical Engineering and Technology
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• v.13 no.2
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• pp.989-997
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• 2018

Massive event stream brings us great challenges in its volume, velocity, variety, value and veracity. Picking up some valuable information from it often faces with long detection time, high memory consumption and low detection efficiency. Aiming to solve the problems above, an efficient complex event detection method based on NFA_HTS (Nondeterministic Finite Automaton_Hash Table Structure) is proposed in this paper. The achievement of this paper lies that we successfully use NFA_HTS to realize the detection of complex event from massive RFID event stream. Specially, in our scheme, after using NFA to capture the related RFID primitive events, we use HTS to store and process the large matched results, as a result, our scheme can effectively solve the problems above existed in current methods by reducing lots of search, storage and computation operations on the basis of taking advantage of the quick classification and storage technologies of hash table structure. The simulation results show that our proposed NFA_HTS scheme in this paper outperforms some general processing methods in reducing detection time, lowering memory consumption and improving event throughput.

• Smart Structures and Systems
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• v.15 no.1
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• pp.81-97
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• 2015

Recently, a new output-only modal identification method based on time-frequency independent component analysis (ICA) has been developed by the authors and shown to be useful for even highly-damped structures. In many cases, it is of interest to identify the complex modes of structures with non-proportional damping. This study extends the time-frequency ICA based method to a complex ICA formulation for output-only modal identification of non-proportionally-damped structures. The connection is established between complex ICA model and the complex-valued modal expansion with sparse time-frequency representation, thereby blindly separating the measured structural responses into the complex mode matrix and complex-valued modal responses. Numerical simulation on a non-proportionally-damped system, laboratory experiment on a highly-damped three-story frame, and a real-world highly-damped base-isolated structure identification example demonstrate the capability of the time-frequency complex ICA method for identification of structures with complex modes in a straightforward and efficient manner.

• Journal of Computational Design and Engineering
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• v.2 no.4
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• pp.248-252
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• 2015

Currently composite manufacturing process, such as linear friction welding plus NC machining, is the main method for the manufacturing and repairing of complex parts with integrated structure. Due to different datum position and inevitable distortion from different processes, it is important to ensure sufficient machining allowance for complex parts during the NC machining process. In this paper, a workpiece localization approach for machining allowance optimization of complex parts based on CMM inspection is developed. This technique concerns an alignment process to ensure sufficient stock allowance for the single parts as well as the whole integrated parts. The mathematical model of the constrained alignment is firstly established, and then the symmetric block solution strategy is proposed to solve the optimization model. Experiment result shows that the approach is appropriate and feasible to distribute the machining allowance for the single and whole parts for adaptive machining of complex parts.

• Journal of the Korean Chemical Society
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• v.62 no.6
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• pp.427-432
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• 2018

The reaction of [$[Ni(L)]Cl_2{\cdot}2H_2O$ (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[$14,4,0^{1.18},0^{7.12}$]docosane) with 1,1-cyclohexanediacetic acid ($H_2cda$) yields mononuclear nickel(II) complex, [$Ni(L)(Hcda^-)_2$] (1). This complex has been characterized by X-ray crystallography, electronic absorption, cyclic voltammetry and thermogravimetric analyzer. The crystal structure of 1 exhibits a distorted octahedral geometry with four nitrogen atoms of the macrocycle and two 1,1-cyclohexanediacetate ligands. It crystallizes in the triclinic system P-1 with a = 11.3918(7), b = 12.6196(8), $c=12.8700(8){\AA}$, $V=1579.9(2){\AA}^3$, Z = 2. Electronic spectrum of 1 also reveals a high-spin octahedral environment. Cyclic voltammetry of 1 undergoes one wave of a one-electron transfer corresponding to $Ni^{II}/Ni^{III}$ process. TGA curve for 1 shows three-step weight loss. The electronic spectra, electrochemical and TGA behavior of the complex are significantly affected by the nature of the axial $Hcda^-$ ligand.

• Bulletin of the Korean Chemical Society
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• v.25 no.3
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• pp.373-376
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• 2004

A novel Er(III) complex with oxydiacetate and 1,10-phenanthroline was synthesized and its structure and luminescence properties were characterized. The complex of $[Er(ODA){\cdot}(phen){\cdot}4H_2O]^+$ crystallizes in the monoclinic space group $P2_1$/n with a = 12.216(4) ${\AA}$, b = 16.680(2) ${\AA}$, c = 12.627(3) ${\AA}$, ${\beta}=108.30(2)^{\circ}$, V = 2442.7(11) ${\AA}^3$, Z = 4 and ${\rho}=1.841 g/cm^3$. When the complex is excited at the He-Cd 325-nm line, it produces two broad bands spanning the regions 350-650 nm and 1200-1650 nm. The emission band of the complex is characterized by a series of spectral dips in the visible emission profile. The complex exhibits sensitized near- IR emission via two kinds of energy transfers from phen to Er(III): nonradiative and radiative energy transfers.

• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.903-907
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• 2002