• Title/Summary/Keyword: complex oxide

Search Result 394, Processing Time 0.043 seconds

Electrical Conductivity Change of Manganese oxide with Addition of Transition Metal (천이금속 첨가에 따른 이산화망간의 전기전도도 변화)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Chung, Won-Sub
    • Proceedings of the KIEE Conference
    • /
    • 2005.07c
    • /
    • pp.2028-2030
    • /
    • 2005
  • The electrical conductivity of manganese oxide and complex manganese oxide produced by anodic deposition method was measured. The additive transition metal is Cu, Co and Fe. The transition metals like as Cu, Co and Fe improved electrical conductivity of complex manganese oxide compared with manganese oxide. This is coincide with the results of molecular orbital calculation by DV-Xa.

  • PDF

Effect of Admix Ratio of Free-machining Agent 'KSX' that Contains Complex Calcium Oxide Powder on Machinability

  • Furuta, Satoshi;Masuda, Shinsuke
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09a
    • /
    • pp.297-298
    • /
    • 2006
  • Free-machining agent 'KSX' contains complex calcium oxide is developed. The effect of admix ratio of KSX on mechanical properties and machinability with two different cutting speeds is reported. KSX displays improved machinability without deterioration of mechanical properties up to 0.3mass% addition. It was observed that KSX is effective with a small addition of 0.1mass% at slower cutting speed, and increased of admix ratio is effective at faster cutting speed.

  • PDF

Large-scale Synthesis of Uniform-sized Nanoparticles for Multifunctional Medical Applications

  • Hyeon, Taeg-Hwan
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.1-1
    • /
    • 2011
  • We developed a new generalized synthetic procedure, called as "heat-up process," to produce uniform-sized nanocrystals of many transition metals and oxides without a size selection process. We were able to synthesize uniform magnetite nanocrystals as much as 1 kilogram-scale from the thermolysis of Fe-oleate complex. Clever combination of different nanoscale materials will lead to the development of multifunctional nano-biomedical platforms for simultaneous targeted delivery, fast diagnosis, and efficient therapy. In this presentation, I would like to present some of our group's recent results on the designed fabrication of multifunctional nanostructured materials based on uniform-sized magnetite nanoparticles and their medical applications. Uniform ultrasmall iron oxide nanoparticles of <3 nm were synthesized by thermal decomposition of iron-oleate complex in the presence of oleyl alcohol. These ultrasmall iron oxide nanoparticles exhibited good T1 contrast effect. In in vivo T1 weighted blood pool magnetic resonance imaging (MRI), iron oxide nanoparticles showed longer circulation time than commercial gadolinium complex, enabling high resolution imaging. We used 80 nm-sized ferrimagnetic iron oxide nanocrystals for T2 MRI contrast agent for tracking transplanted pancreatic islet cells and single-cell MR imaging. We reported on the fabrication of monodisperse magnetite nanoparticles immobilized with uniform pore-sized mesoporous silica spheres for simultaneous MRI, fluorescence imaging, and drug delivery. We synthesized hollow magnetite nanocapsules and used them for both the MRI contrast agent and magnetic guided drug delivery vehicle.

  • PDF

Properties and Application as the Indicator of N-4-Salicyloamido-2-Amino-6-Piperidinopyrimidine 3-Oxide Fe(III) Complex (N-4-살리실로아미도-2-아미노-6-피페리디노피리미딘 3-옥사이드${\cdot}$철(III) 착체의 물성 및 지시약적 응용성)

  • Lee, Jong-Pill;Shin, Joon-Su;Kim, Kyoung-Soon;Hong, Seon-Pyo;Kim, Kyeong-Ho;Kim, Bak-Kwang
    • YAKHAK HOEJI
    • /
    • v.40 no.6
    • /
    • pp.670-678
    • /
    • 1996
  • The combinations of N-4-salicyloamido-2-amino-6-piperidinopyrimidine 3-oxide (Salmi) and two transitional metals were colored. Among metals, Fe(III) made a distinct colored comp lex with Salmi. The mole ratio of Salmi and Fe(III) in the complex was 1:1. This Salmi-Fe(III) complex was recrystallized in Hexane/Acetone(=10/1, v/v) and investigated its physicochemical properties. The color of this complex was changed by pH.; deep violet pink in acids, orange in neutral, and yellow in bases. The range of color change was approximately 0.7 pH unit. Acid-base titration of various acidic or basic drugs using Salmi-Fe(III) complex as an indicator showed good accuracy and reproducibility.

  • PDF

A Study on the Reaction Characteristics of Rare Earth Oxides with Lithium Oxide in LiCl Molten Salt (LiCl 용융염 중에서 희토류 산화물과 산화리튬의 반응특성에 관한 연구)

  • 오승철;박성빈;김상수;도재범;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2003.11a
    • /
    • pp.447-452
    • /
    • 2003
  • We had clarified the reactions of the rare earth oxides($RE_2O_3$) with lithium oxide produced in lithium reduction process of oxide fuels. Oxides of scandium, yttrium, praseodymium, neodymium, samarium, europium, gadolinium, ytterbium and lutetium reacted with lithium oxide in the higher concentration than the respective certain critical concentration of lithium oxide and formed complex oxides($LiREO_2$). The critical lithium oxide concentrations for the formation of complex oxides of scandium, yttrium, praseodymium, neodymium, samarium, europium, gadolinium, ytterbium and lutetium oxide were respectively 0.1 wt%, 1.9 wt%, 5.3 wt%, 5.0 wt%, 3.0 wt%, 3.9 wt% 2.9 wt%, 2.6 wt% and 0.3 wt%. Cerium and lanthanum oxide did not react with lithium oxide. These complex oxides obtained from experiments have limited solubility in lithium chloride at $650^{\circ}C$.

  • PDF

Study on the Cu/polyimide interface using XPS: Initial growth of Cu sputter-deposited on the polyimide at room temperature (I) (XPS를 이용한 Cu/Polyimide 계면에 관한 연구 : 상온에서 증착한 Cu의 초기성장과정(I))

  • 이연승;황정남
    • Journal of the Korean Vacuum Society
    • /
    • v.6 no.3
    • /
    • pp.187-193
    • /
    • 1997
  • We investigated the initial growth mode of Cu deposited on polyimide at room temperature using x-ray photoelectron spectroscopy. We could find that when Cu is sputter-deposited on the polymide, Cu-N-O complex of strong interaction is mainly formed first, Cu-oxide of weak interaction is formed successively, and then finally metallic Cu grow. From these results, we could conclude that Cu/polyimide interface consists of Cu-N-O complex and Cu-oxide.

  • PDF

Copolymerization and Oligomerization of Isobutylene Oxide (Isobutylene Oxide의 공중합 및 올리고머 반응)

  • 이윤배;김선길
    • Polymer(Korea)
    • /
    • v.24 no.1
    • /
    • pp.124-127
    • /
    • 2000
  • To improve various physical properties of poly(isobutylene oxide) copolymers of isobutylene oxide and cyclohexene oxide have been synthesized with triisobutylaluminum as catalyst. The molecular weights of the copolymers are rather lower than that of poly(isobutylene oxide) prepared with diethylzinc catalyst. The glass transition temperatures of the copolymers are between those of two homopolymers. The copolymers of isobutylene oxide and vinyl cyclohexene oxide showed better thermal stability. Oligomer of isobutylene oxide has been synthesized for polyol and lubricant application. Acid catalyzed oligomerization gave vary complex mixture. But base catalyzed reaction afforded the pentamer and hexamer rich oligomer mixtures.

  • PDF

The Research of Optimal Plant Layout Optimization based on Particle Swarm Optimization for Ethylene Oxide Plant (PSO 최적화 기법을 이용한 Ethylene Oxide Plant 배치에 관한 연구)

  • Park, Pyung Jae;Lee, Chang Jun
    • Journal of the Korean Society of Safety
    • /
    • v.30 no.3
    • /
    • pp.32-37
    • /
    • 2015
  • In the fields of plant layout optimization, the main goal is to minimize the construction cost including pipelines as satisfying all constraints such as safety and operating issues. However, what is the lacking of considerations in previous researches is to consider proper safety and maintenance spaces for a complex plant. Based on the mathematical programming, MILP(Mixed Integer Linear Programming) problems including various constraints can be formulated to find the optimal solution which is to achieve the best economic benefits. The objective function of this problem is the sum of piping cost, pumping cost and area cost. In general, many conventional optimization solvers are used to find a MILP problem. However, it is really hard to solve this problem due to complex inequality and equality constraints, since it is impossible to use the derivatives of objective functions and constraints. To resolve this problem, the PSO (Particle Swarm Optimization), which is one of the representative sampling approaches and does not need to use derivatives of equations, is employed to find the optimal solution considering various complex constraints in this study. The EO (Ethylene Oxide) plant is tested to verify the efficacy of the proposed method.

Electrical Characteristics of Poly(ethylene oxide)-urea Complex Films

  • Cho, Mi-Yeon;Cho, Kyoung-Ah;Kim, Sang-Sig
    • Transactions on Electrical and Electronic Materials
    • /
    • v.13 no.3
    • /
    • pp.136-138
    • /
    • 2012
  • The electrical characteristics of complex films composed of poly(ethylene oxide) (PEO) and urea as a function of the urea concentration were examined in this study. Moreover, their structural characteristics were also compared. Depending on the urea concentration, the structural phases were classified as PEO+${\beta}$-phase composite, ${\beta}$-phase+${\alpha}$-phase composites, or ${\alpha}$-phase composite+urea. At urea concentrations below ~0.064 M, the ${\beta}$-phase was dominant in the complex film. Moreover, the conductance increased rapidly with an increase in the urea concentration. For urea concentrations ranging from ~0.064 to ~0.25 M, the ${\beta}$-phase was gradually substituted by the ${\alpha}$-phase. As the film was composed entirely of the ${\alpha}$-phase at urea concentrations greater than ~0.25 M, its conductance was decreased. In this study, the electrical characteristics observed for the different phases are analyzed and discussed.