• Title/Summary/Keyword: complex mixture analysis

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Fluorophotometric Determination of Basic Drugs with Lumogallion, Superchrome Garnet Y and Their Alkyl Derivatives (루모갈리온, 슈퍼크롬 가넷 와이 및 그 알킬 유도체에 의한 염기성 의약품의 형광정량)

  • 송만영;김동오;이은엽;안문규
    • YAKHAK HOEJI
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    • v.37 no.3
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    • pp.209-215
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    • 1993
  • Basic drugs could be extracted as ion-paired complexes with Lumogallion, Superchrome Garnet Y and their alkyl derivatives from aqueous acid solution, and then determined fluoro-metrically after addition of aluminum ion. The analysis was carried out as follows; To a 1 ml portion of basic drugs (10$^{-9}$~2$\times$0$^{-8}$mole/ml), 1ml of 0.01w/v% fluorescent reagent solution, and 10ml of dichloroethane are added. The mixture is stirred for 1 minute. After standing for a few minutes, the dichloroethane layer is transfered to 1 ml of 0.1w/v% Al(NO$_{3}$)$_{3}$ ethanol solution. After mixing, and standing for 30 minutes at room temperature, the fluorescence intensity is measured with each maximum excitation and emission wavelength. The reagent blank is run through the whole procedure. From the degree of enhancement of fluorescence intensity, hexyl and dodecyl lumogallion and Superchrome Garnet Y were judged to be the useful one of fluorescent reagent for basic drugs analysis.

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Experimental and Theoretical Study on Corrosion Inhibition of Mild Steel in Oilfield Formation Water Using Some Schiff Base Metal Complexes

  • Mahross, M.H.;Efil, Kursat;El-Nasr, T.A. Seif;Abbas, Osama A.
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.222-235
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    • 2017
  • First, in this study, the inhibition efficiencies of metal complexes with Cu(II), Ni(II) and Zn(II) of STSC ligand for corrosion control of mild steel in oilfield formation water were investigated. The IEs for a mixture of 500 ppm STSC and 5 ppm metal ion ($Cu^{+2}$, $Ni^{+2}$, $Zn^{+2}$) were found to be 88.77, 87.96 and 85.13 %, respectively. The results were obtained from the electrochemical techniques such as open circuit potential, linear and tafel polarization methods. The polarization studies have showed that all used Schiff base metal complexes are anodic inhibitors. The protective film has been analyzed by FTIR technique. Also, to detect the presence of the iron-inhibitor complex, UV-Visible spectral analysis technique was used. The inhibitive effect was attributed to the formation of insoluble complex adsorbed on the mild steel surface and the adsorption process follows Langmuir adsorption isotherm. The surface morphology has been analyzed by SEM. Secondly, the computational studies of the ligand and its metal complexes were performed using DFT (B3LYP) method with the $6-311G^{{\ast}{\ast}}$ basis set. Finally, it is found that the experimental results were closely related to theoretical ones.

A study on the Powder Injection Molding of Translucent Alumina via Flowability Simulation of Powder/Binder Mixture (분말사출성형 시 분말 혼합체의 유동성 시뮬레이션을 통한 투광성 알루미나 소결체의 특성 연구)

  • Kim, Hyung Soo;Byun, Jong Min;Kim, Se Hoon;Kim, Young Do
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.215-221
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    • 2014
  • Translucent alumina is a potential candidate for high temperature application as a replacement of the glass or polymer. Recently, due to the increasing demand of high power light emitting diode (LED), there is a growing interest in the translucent alumina. Since the translucent property is very sensitive to the internal defect, such as voids inside or abnormal grain growth of sintered alumina, it is important to fabricate the defect-free product through the fabrication process. Powder injection molding (PIM) has been commonly applied for the fabrication of complex shaped products. Among the many parameters of PIM, the flowability of powder/binder mixture becomes more significant especially for the shape of the cavity with thin thickness. Two different positions of the gate were applied during PIM using the disc type of die. The binder was removed by solvent extraction method and the brown compact was sintered at $1750^{\circ}C$ for 3 hours in a vacuum. The flowability was also simulated using moldflow (MPI 6.0) with two different types of gate. The effect of the flowability of powder/binder mixture on the microstructure of the sintered specimen was studied with the analysis of the simulation result.

A Study on the Application building Scope for the Mixed-Use Districts (복합용도지역의 건축물 규모의 운용방안에 관한 연구)

  • Lee, Won-Geun;Kim, Young-Chan
    • Journal of The Korean Digital Architecture Interior Association
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    • v.10 no.1
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    • pp.65-74
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    • 2010
  • This study has been given careful consideration to an induction of the mixed-use districts for the efficiency of Land Use, the rational plot planning and the mixture/complex among the functions in order to complement the zoning plan with the primary purpose to purify the usage of landscape. Furthermore, it is aimed to indicate the implementations through the medium of the in-depth analysis about the cardinal factors such as the standards on the regional location, building size and building uses in the case of designating the Mixed-use districts.Abstract This study has been examined by the aspect of scope for securing the adequacy of Site Division Restriction, Floor Area Ratio, Building Coverage Ratio and Outdoor Area Ratio in the "Mixed-Use Districts" and especially, by the medium of the in-depth analysis about the actual condition of building and outdoor space scales. It has been deduced the scale standards by using the simulation and correlation analysis among the factors of those buildings and outdoor spaces. Moreover, it has been applied the analysis method of using the building scale, especially, the latter has analyzed the total 1,656 different types classified by 3 patterns of Plottage and Building Coverage Ratio, 9 patterns of the factor change on Outdoor Area Ratio and 8 different patterns of road width.

Background Subtraction in Dynamic Environment based on Modified Adaptive GMM with TTD for Moving Object Detection

  • Niranjil, Kumar A.;Sureshkumar, C.
    • Journal of Electrical Engineering and Technology
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    • v.10 no.1
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    • pp.372-378
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    • 2015
  • Background subtraction is the first processing stage in video surveillance. It is a general term for a process which aims to separate foreground objects from a background. The goal is to construct and maintain a statistical representation of the scene that the camera sees. The output of background subtraction will be an input to a higher-level process. Background subtraction under dynamic environment in the video sequences is one such complex task. It is an important research topic in image analysis and computer vision domains. This work deals background modeling based on modified adaptive Gaussian mixture model (GMM) with three temporal differencing (TTD) method in dynamic environment. The results of background subtraction on several sequences in various testing environments show that the proposed method is efficient and robust for the dynamic environment and achieves good accuracy.

Control of Shrinkage Cracking of Cement Composites with Different Length Mixture of PVA Fibers (서로 다른 길이의 PVA 섬유 혼합에 따른 시멘트 복합체의 균열제어 특성)

  • Won, Jong-Pil;Kim, Myung-Kyun;Park, Chan-Gi;Kim, Wan-Young;Park, Kyoung-Hoon;Jang, Chang-Il
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.405-408
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    • 2006
  • The purpose of this study was to determine the optimum length distribution of hybrid PVA(Poly vinyl alcohol) fiber. To produce blended PVA fiber length, first the length distribution of PVA fiber in the cement composites were identified in an experimental study based on simplex lattice design. Among the different length distributions investigated, fiber length was found to have statistically significant effect on plastic shrinkage cracking of cement composites. Subsequently, Complex analysis techniques were used to devise an experimental program that helped determine the optimum combinations of the selected fiber length distribution based on plastic shrinkage crack. The optimum blended PVA length ratio was 0.0146% 4mm fiber, 0.0060% 6-mm fiber, 0.0285% 8-mm fiber, and 0.0209% 12-mm fiber.

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A Simulation Analysis of the Discharge Characteristics with the Xe Gas Contents (Xe 가스 첨가에 따른 방전 특성 시뮬레이션 분석)

  • You, Il;Song, Young-Joo;Lee, Young-Min;Ok, Jung-Woo;Nahm, Choon-Woo;Lee, Don-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.11
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    • pp.1650-1655
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    • 2012
  • AC-PDPs have recently achieved good performance and their image quality can sufficiently compete with the LCD TV. However, it is necessary more effort to improve the luminance and luminous efficacy in the PDP technology. The gas mixture ratio plays a very important role in discharge characteristics, but the mechanism of gas discharge is complex and complicated. In this paper, we investigate the mechanism of gas discharge with Ne+Xe miture ratio through zero and two dimensional fluid simulation.

A Numerical Analysis of the Flow Characteristics in a Lean Premixed Gas Turbine Combustor for Power Generation (발전용 희박예혼합 가스터빈 연소기 내부유동 특성 해석)

  • Chung, Jae-Hwa;Seo, Seok-Bin;Ahn, Dal-Hong;Kim, Jong-Jin
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.847-852
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    • 2000
  • Three dimensional CFD investigations are carried out to understand the complex flow field in a gas turbine combustor with multi-element fuel injectors. The gas turbine considered here is the GE7FA model which has aye fuel injectors in each combustor can and utilizes lean-premixed combustion to meet nitric oxide emission requirements. Detailed three-dimensional flow characteristics and fuel-air mixture formation process inside the fuel nozzle and gas turbine combustor including five swirl nozzle tips are analyzed using commercial FLUENT code.

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Semi-Supervised Learning for Fault Detection and Classification of Plasma Etch Equipment (준지도학습 기반 반도체 공정 이상 상태 감지 및 분류)

  • Lee, Yong Ho;Choi, Jeong Eun;Hong, Sang Jeen
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.4
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    • pp.121-125
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    • 2020
  • With miniaturization of semiconductor, the manufacturing process become more complex, and undetected small changes in the state of the equipment have unexpectedly changed the process results. Fault detection classification (FDC) system that conducts more active data analysis is feasible to achieve more precise manufacturing process control with advanced machine learning method. However, applying machine learning, especially in supervised learning criteria, requires an arduous data labeling process for the construction of machine learning data. In this paper, we propose a semi-supervised learning to minimize the data labeling work for the data preprocessing. We employed equipment status variable identification (SVID) data and optical emission spectroscopy data (OES) in silicon etch with SF6/O2/Ar gas mixture, and the result shows as high as 95.2% of labeling accuracy with the suggested semi-supervised learning algorithm.

Analysis of the Case of Separation of Mixtures Presented in the 2015 Revised Elementary School Science 4th Grade Authorized Textbook and Comparison of the Concept of Separation of Mixtures between Teachers and Students (2015 개정 초등학교 과학과 4학년 검정 교과서에 제시된 혼합물의 분리 사례 분석 및 교사와 학생의 혼합물 개념 비교)

  • Chae, Heein;Noh, Sukgoo
    • Journal of Korean Elementary Science Education
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    • v.43 no.1
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    • pp.122-135
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    • 2024
  • The purpose of this study was to analyze the examples presented in the "Separation of Mixtures" section of the 2015 revised science authorized textbook introduced in elementary schools in 2022 and to see how the teachers and students understand the concept. To do that, 96 keywords were extracted through three cleansing processes to separate the elements of the mixture presented in the textbook. In order to analyze the teachers' perceptions, 32 teachers at elementary schools in Gyeonggi-do received responses to a survey, and a survey of 92 fourth graders who learned the separation of the mixture with an authorized textbook in 2022 was used for the analysis. As a result, as for the solids, 54 out of 96 separations (56.3%) showed the highest ratio, and the largest number of cases were presented according to the characteristics of the development stage of students. It was followed by living things, liquids, other objects and substances, and gasses. By analyzing the mixture, the structure and the interrelationships between the 96 extracted keywords were systematized through the network analysis, and the connection between the keywords, which were a part of the mixture was analyzed. The teachers partially responded to the separation of the complex mixture presented in the textbook, but most of the students did not recognize it. Because the analysis of the teachers' and students' perceptions of the seven separate categories presented in the survey was not based on a clear conceptual perception of the separation of the mixture, but rather they tended to respond differently for each characteristic of each individual category, it was decided that it was necessary to present clearer examples of the separation of the mixture, so that the students could better understand the concept of separation of mixtures that could be somewhat abstract.