• 제목/요약/키워드: complex mixture analysis

검색결과 112건 처리시간 0.026초

유한요소법을 이용한 폴리머 압출 공정해석에 관한 연구 (A Study on Analysis of Polymer Extruder Process Using Finite Element Method)

  • 예영수;김홍범;이재욱;김낙수
    • 대한기계학회논문집A
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    • 제29권1호
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    • pp.145-155
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    • 2005
  • In this study, a finite element method program code which can be accomodate boundary conditions on the complex surfaces has been developed to simulate polymer extruder processes. The analysis method includes the fractional 4-step method for efficient computation time and compact usage of memory storage to solve the velocities and the pressure values from the Navier-Stokes equation. By using the developed program which was verified with simple Poiseuille flow mixture phenomena in single-and twin-screw extruder are analyzed. It is concluded that the proposed method resulte Poiseuille Poiseuille d in fair agreement with the exact solution of simple flow and the back flow near the entrance happens in single-screw model. It is identified that the location and values of maximum pressure in the twin screw extruder model. It is expected that the Velocity field found can be used to predict the degree of mixture in the extruder barrel.

제지공정 침착이물질 및 종이내 불순물성분의 기기분석적 고찰 (The Study of Instrumental Analysis of Deposits on Paper Machine and Holes/spots in Paper)

  • 마금자;이복진
    • 펄프종이기술
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    • 제29권3호
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    • pp.7-16
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    • 1997
  • The constituents of deposits on paper machine and holes/spots in paper have been studied by consequently a combination of analytical techniques, such as FTIR, Py-GC-MS, and. EDS. FTIR spectroscopy was used prior to Py-GC-MS and EDS analysis, as preliminary analysis technique. The analysis of organic components were carried out with the use of a pyrolysis unit connected to a GC-MS, and inorganic components in ash were analysed by SEM equipped with an EDS analyzer after pyrolysis at 59$0^{\circ}C$. The deposits on the dryer section were complex pitch, which was the mixture of the organic contents of fatty acid ester and starch, and the inorganic contents of talc, clay, and calcium carbonate. The complex pitch was estimated to come from the coated broke. We knew the deposits on the metering rod of sym-sizer were associated with the interaction of unstable AKD and CaCO$_3$. The compositions of holes or spots varied considerably and were associated with chemical interaction within the system. The holes, spots, and blotches in the finished paper were PE and PP that were streamed out from pulp sources, complex pitch that were caused by the interaction of the different additives in the system, polymer such as flexible PVC that used for the prop of palette, and hot melt as adhesives that came from the inadequate handling of broke. In addition, we identified that poly(caprolactam) which is used for forming fabrics or press felts, could be mixed with the raw materials by accident and results in streak on coating.

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도시지역의 수문학적 토지피복 분류를 위한 초분광영상의 분광혼합분석 (Spectral Mixture Analysis Using Hyperspectral Image for Hydrological Land Cover Classification in Urban Area)

  • 신정일;김선화;윤정숙;김태근;이규성
    • 대한원격탐사학회지
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    • 제22권6호
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    • pp.565-574
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    • 2006
  • 넓은 면적의 유역에 대한홍수유출모형 및 수문분석에서 중요한 인자로 이용되는 토지피복 정보를 얻기 위하여 인공위성 영상이 많이 활용되고 있다. 도시지역과 같이 다양한 형태의 토지피복이 혼재하는 공간에서는 보다 세분화된 토지피복 정보가 필요하나, 기존의 다중분광영상을 이용한 수문학적 토지피복분류에는 한계가 있다. 이 연구에서는 초분광영상을 이용하여 도시지역의 수문학적 토지피복 분류에 있어서 기존의 다중분광영상 보다 분류등급을 세분화하고 분류정확도를 향상시킬 수 있는 가능성을 밝히고자 한다. 미국 농무부 토양보전국(USDA SCS)의 도시지역 수문학적 토지피복분류를 목표로 서울지역의 Hyperion 영상을 분석하였다. 도시지역의 피복특성을 감안한여 투수성 및 불투수성 표면특성을 대표하는 8개의 endmember를 선정하여 분광혼합분석을 수행하였다. 분광혼합분석 결과 얻어진 각 endmember의 점유비율을 조합하여 17개 등급의 수문학적 토지피복도를 제작하였다. 분광혼합분석을 적용하여 얻어진 토지피복도의 정확도를 10곳의 표본점에 대한 항공사진 판독 결과를 통하여 검정한 결과, 미국 농무부에서 제시한 수문학적 토지피복등급이 비교적 정확하게 분류되었다.

실내실험을 통한 핵석지반의 강도정수 산정연구 (Laboratory experiment on the assessment of the ground strength with corestone)

  • 이수곤;김동은;황의성
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2003년도 봄 학술발표회 논문집
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    • pp.95-102
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    • 2003
  • Corestone rock mass has complex characters because it is made up of stronger and stiffer corestone in a weaker and softer matrix. Physical model corestone rock mass made up of stiffer corestone in weaker matrix were tested in uniaxial compression and numercal modelling analysis The result of the uniaxial compression tests showed that increasing the corestone proportion generally increased the modulus of deformation. And the strength decreased in the lower corestone proportion, but it increased in the higher proportion(45%, 65% corestone by volume). The strength and the modulus of deformation were not affected by different size coretone on the same proportion. The result of the numerical modelling analysis showed similar trend compared with the result of the result of the uniaxial compression test. But though the result of th uniaxial compression test is similar to the result of the numerical modelling analysis, it's unreasonalble to apply the results of this paper to in situ corestone rock mass. So mere laboratory tests including triaxial test and the other numerical program analyses are necessary to apply the results to in situ corestone mass

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Phytochemical Compounds from the Ethanolic Extract of Gymnema sylvestre, Senna auriculata and Cissus quadrangularis through GC-MS Analysis

  • Sindhuja G;Mary Agnes A
    • Mass Spectrometry Letters
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    • 제14권2호
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    • pp.25-35
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    • 2023
  • Plants are a traditional source of many chemicals used as biochemical, flavors, food, color, and pharmaceuticals in various countries, especially India. Most herbal medicines and their derivatives are often made from crude extracts containing a complex mixture of various phytochemical chemical components (secondary metabolites of the plants). This study aimed to identify bioactive compounds from the different parts of the plant from the ethanolic extract of Gymnema sylvestre, Senna auriculata, and Cissus quadrangularis (leaves, flower, stem) by gas chromatography-mass spectroscopy (GC-MS). The gas chromatography - mass spectrometry analysis revealed the presence of various compounds like 3,4-dimethylcyclohexanol, hexanoic acid, D-mannose, and N-decanoic acid. Hence, the Gymnema sylvestre, Senna auriculata, and Cissus quadrangularis may have chemopreventive, anti-cancer, anti-microbial activity, antioxidant, anti-diabetic activity, anti-inflammatory, and antifungal due to the presence of secondary metabolites in the ethanolic extract. These phytochemicals are supported for traditional use in a variety of diseases.

복합유류 토양오염에 따른 유종 해석 (The Interpretation of Petroleum Species from Contaminated Soil by Complex Oil)

  • 임영관;김지연;김완식;이정민
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제24권1호
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    • pp.17-23
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    • 2019
  • Clean soil environment is of crucial importance to sustain lives of ecosystem and humans. With rapid industrialization, there has been a great increase of soil contamination by accidental releases of petroleum products. In general, soil remediation is an expensive and time-consuming process as compared to cleanup of water and air. Moreover, determining the source and responsible parties of soil pollution often turns into legal conflicts and that further delay the cleanup process of contaminated sites. In practice, total petroleum hydrocarbon (TPH) analysis has been employed to determine the petroleum species and to track down the responsible polluters. However, this approach often suffers from differentiating similar TPH species. In this study, we analyzed TPH chromatogram patterns of 24 domestic petroleum products in specific carbon ranges (${\sim}C_{10}$, $C_{10}-C_{12}$, $C_{12}-C_{36}$, and $C_{36}{\sim}$) and the fractional changes of THP ratio in the mixture products of gasoline, kerosene and diesel. The proposed TPH analysis method in this study could serve as a useful tool to better analyze the petroleum species in soils contaminated with complex oil mixtures, and ultimately be used to identify the polluters of soil.

바이칼린 함유 생약의 제제화 및 생체이용률 (제3보) : 황금 및 황련 공침물의 포접화합물 제조 및 생체이용률에 관한 연구 (Preparation and Bioavailability of Oriental Medicine Containing Baicalin (III) : Preparation of Inclusion Complex and Bioavailability of Coprecipitated Product of Scutellariae Radix and Coptidis Rhizoma)

  • 양재헌;신상철;류희두
    • Journal of Pharmaceutical Investigation
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    • 제27권1호
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    • pp.29-38
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    • 1997
  • Precipitation was formed during the preparation of decoction from a mixture of Scutellariae Radix and Coptidis Rhizoma. Baicalin and berberine were identified in this coprecipitated product (CPP) and these components were the active ingredients of two herbal medicine. We extracted respectively crude baicalin and berberine in Scutellariae Radix and Coptidis Rhizoma and prepared coprecipitate of crude baicalin-berberine. To increase the stability and bioavailability of coprecipitate of crude baicalin-berberine(CBB), which is slightly soluble drug, its inclusion complex was prepared and studied in this experiment. Inclusion complex of CBB with ${\beta}-cyclodextrin(CBB-{\beta}-CD)$ was prepared by freeze drying method and its characteristics were ascertained by means of solubility test, differential thermal analysis(DTA) and scanning electron microscope(SEM). The type of $CBB-{\beta}-CD$ is classified as $A_L-type$ on phase solubility diagram, and the stoichiometric ratio of CBB(baicalin in CBB) : ${\beta}-CD$ complex is 1:1 and formation constant is 151 $M^-1$. The solubility, dissolution, in situ absorption and serum concentration of $CBB-{\beta}-CD$ were significantly increased when compared to CBB. Therefore enhanced bioavailability of CBB by inclusion complexation with ${\beta}-cyclodextrin$ might be useful for dosage form design of active ingredients of two herbal medicine.

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Evaluation of Environmental Mutagens-Complex Mixture in Diesel Exhaust Respirable Particulate Matter

  • Kim, Soung-Ho;Ryu, Byung-Tak;Jang, Hyoung-Seok;Kim, Yun-Hee;Lee, Do-Han;Han, Kyu-Tae;Oh, Seung-Min;Chung, Kyu-Hyuck
    • 한국환경독성학회:학술대회논문집
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    • 한국환경독성학회 2003년도 춘계학술대회
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    • pp.194-194
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    • 2003
  • The International Agency for Research on Cancer (IARC, 1989) has classified whole diesel exhaust as probably carcinogenic to humans. Diesel exhaust particulate matter (DPM) adsorbs different chemical substances including PAHs and nitroarenes. DPM is emphasized because it is a major component of diesel exhaust, it is suspected of contributing to a health hazard. Diesel exhaust is a complex mixture of carbon particles and associated organics and inorganics, and it is not known what fraction or combination of fractions cause the health effects [cancer effects, noncancer effects (respiratory tract irritation/inflammation and changes in lung function)] that have been observed with exposure to diesel exhaust. In order to identify which chemical classes are responsible for the majority of the observed biological activities, we performed a particular biological/chemical analysis. Respirable particulate matter (PM2.5: <2.5mm) was collected from diesel engine exhaust using a high-volume sampler equipped with a cascade impactor. Particulate oganic matter was extracted by the dichloromethane/sonication method and the crude extract was fractionated according to EPA recommended procedure into seven fractions by acid-base partitioning and silica gel column chromatography. We examined genotoxic potentials of diesel exhaust particulate matter using novel genotoxicity tests, which are rapid, simple and sensitive methods for assessing DNA-damage at the DNA and chromosomal level (comet assay, in vitro MN test and Ames test). Higher genotoxic potency was observed in non polar fractions and several PAHs were detected by GC-MS, such as 1,2,5,6 dibenzanthracene, chrysene, 1,2-benzanthracene, phenanthrene and fluoranthene.

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Sensitivity Analysis of the Criticality Evaluation Concerning Pyroprocess

  • Gao, Fanxing;Ko, Won-Il;Park, Chang-Je;Lee, Ho-Hee
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2010년도 학술논문요약집
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    • pp.271-272
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    • 2010
  • Sensitivity analysis by TSUNAMI clarifies the complex effects of key nuclides on the criticality probability quantitatively. As discussed above, the $K_{eff}$ of $UO_2$ fuel reaches the maximum value with 42w% concentration of intrusion water. The concentration of hydrogen affects the complexity of reaching criticality by its competition between the concentrations of $^{235}U$. Approximately if the weight percent of $H_2O$ in the mixture is less than 42%, the moderation effect of hydrogen surpasses its dilution effect on $^{235}U$. However, the importance of $^{235}U$ increases dramatically when the weight percent of water is bigger than 42%. In the sensitivity evaluation of $UO_2$ fuel employing TSUMAMI, there is a similar crosspoint of the sensitivity of $^{235}U$ and the sensitivity of $^1H$ where the criticality reaches summit. And the optimal water weight percent is determined to be 50%.

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원통형 연소기 내의 저주파 소음특성에 관한 수치적 연구 (Numerical Study on Characteristics of Low-Frequency Noise in a Cylindrical Combustor)

  • 김재헌;이수갑
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 1998년도 춘계학술대회논문집; 용평리조트 타워콘도, 21-22 May 1998
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    • pp.492-497
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    • 1998
  • Thermoacoustic oscillation is a significant problem in cylindrical-type combustors such as common internal combustion engines, industrial furnaces, gas turbine, etc. This kind of low frequency oscillation can give rise to serious troubles such as the destruction of system or producing of a strong noise. Accurate numerical simulation of thermoacoustic phenomena is a complex and challenging problem. Especially, considering the reaction of mixture intensifies the difficulty of analysis. Like as other simulations of the aerodynamics and aeroacoustics, direct computation of thermoacoustic phenomena requires that the Navier-Stokes equations be solved using accurate numerical differentiation and time-marching schemes, with non-reflecting boundary conditions. In this study,, numerical approach aims at qualitative analysis and efficient prediction of problem, not at the development of an accurate scheme. Overally speaking, numerical prediction is reasonably matched with experimental result.

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