• 한국가스학회지
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• 제24권4호
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• pp.39-47
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• 2020

배기가스 재순환(flue gas recirculation, 이하 FGR)은 질소산화물 저감에 효과적인 연소 기법으로 저공해 연소 분야에 다양하게 응용되고 있다. 이전 연구에 이어서 메탄/공기 대향류 예혼합화염에 FGR 기법 적용 시 나타나는 화염의 특성 변화 및 NOx 생성기구를 파악하기 위한 수치해석이 진행되었다. 배출되는 질소산화물(NOx)은 4가지 주요 반응경로(열적 NO, prompt NO, N₂H 및 N₂O)로 구분하여 배기가스 재순환율에 따른 각 NO 생성률을 상대적으로 나타내었다. 그 결과 열적 NO가 전체 NO 형성에 가장 크게 차지한 반면 N₂H의 영향은 미미하였다. 또한, 열적 NO의 기여를 검토하기 위하여 본 연구에 사용된 반응기구(UC San Diego mechanism)를 수정하여 재순환율 증가에 따른 NO 배출지수(EINO)를 비교하였다.

• 한국연소학회지
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• 제12권4호
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• pp.8-13
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• 2007

Plasma assisted combustion is an old subject for the combustion society, but recently, the subject is refocused partly because techniques for non-thermal plasmas are progressed significantly, and partly because there are lots of applications which need to be overcome by a new reaction technology. In the present study, we have developed plasma assisted burner (plasma burner), which can be used as a heating source in a diesel particulate filter system. The burner can burn 20-60 cc/min of diesel fuel with 50 lpm of fresh air in an exhaust pipe of 2.0 liter diesel engine. Using 20 cc/min of diesel fuel, an exhaust temperature for 2.0 liter diesel engine can be raised up to around $600^{\circ}C$ for a wide range of engine speed (idle-3,000 rpm). The characteristics of the plasma burner are reported, and the possible operating mechanism of it will be discussed based on the effects of an electric field and a plasma on flames.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
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• pp.202-206
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• 2007

Plasma assisted combustion is an old subject for the combustion society, but recently, the subject is refocused partly because techniques for non-thermal plasmas are progressed significantly, and partly because there are lots of applications which need to be overcome by a new reaction technology. In the present study, we have developed plasma assisted burner (plasma burner), which can be used as a heating source in a diesel particulate filter system. The burner can bum 20 - 60 cc/min of diesel fuel with 50 lpm of fresh air in an exhaust pipe of 2.0 liter diesel engine. Using 20 cc/min of diesel fuel, an exhaust temperature for 2.0 liter disel engine can be raised up to around $600^{\circ}C$ for the range of engine speeds is idle - 3,000 rpm. The characteristics of the plasma burner are reported, and the possible operating mechanism of it will be discussed based on the effects of an electric field and a plasma on flames.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.169-174
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• 2014

Detonation propagation studies is recently getting more attention in these days for its feasibility in aerospace application. Another motivation for this study is the safety concern in industries, since the detonation can cause failure to the mechanical components particularly when the flame accelerates within a pipe or tubes. In this study we numerically simulated a Moderately unstable detonation case with various grid systems and fluid dynamic length scales and have compared in the contents. Moderately Unstable detonation case was selected for this study and detailed Hydrogen-Air Reaction Mechanisms proposed by Jachimowski was used in this study with N2 as inert species.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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• pp.229-235
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• 2000

Soot formation characteristics in counterflow diffusion flames of ethylene/propane/nitrogen mixtures have been studied experimentally to investigate the soot formation mechanism. The effect of HACA reaction on PAH and soot growth has been experimentally investigated by using 2-D planar LII and PAH LIF techniques.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.99-102
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• 2002

The BSCCO superconductor materials of using Self-propagating High-temperature Synthesis (SHS) were studied. Mechano-chemical activation - as a pre-treatment of the reactants mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product. In this paper as an effort for fabricating the SHSed BSCCO superconductor powder SHS method was considered to application in the synthesis of superconducting materials.

• 한국환경과학회지
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• 제22권3호
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• pp.331-339
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• 2013

Efforts were made to determine the activation energy and the reaction order by adopting Kissinger and Flynn-Wall-Ozawa analysis methods. All the data were acquired from TGA thermograms for the mixed fuels with different temperature heating rates. It could be known that both the coal and the mixed fuels decomposed thermally at temperature ranges of $300{\sim}700^{\circ}C$. The temperature at the maximum reaction rate, Tp, could be determined by DTG method, which could be obtained by differentiation of TGA thermogram. Kissinger analysis showed the linear relationship with experimental data, showing the activation energy of $319.64{\pm}4$ kJ/mol. From Flynn-Wall-Ozawa analysis, it was shown that the activation energies and the reaction orders did not undergo any significant changes with both the conversions and the heating rates. It was considered from this facts that the combustion mechanism of the mixed fuels could not be affected by the extent of conversion and heating rate. In the present study, the activation energies showed different values according to the different analysis methods. The difference might be originated from the inconsistency of the mathematical data treatment method. In other words, while the activation energies obtained from the Kissinger method indicated the average values for overall reaction, that from Flynn-Wall-Ozawa method showed the average values for the each conversion around Tp.

• 한국재료학회지
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• 제5권7호
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• pp.869-879
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• 1995

TiAi intermetallic compound has been extensively studied for possible high temperature structural applications because of its high specific strength at high temperature, high creep resistance, and good oxidation resistance at elevated temperatures. In addition to its good properties, an economic manufacturing routes should be developed for this material to be used more extensively. One of the promising route in manufacturing TiAl intermetallics is the Self-propagating High-temperature Synthesis (SHS) method. Thus in this study, an attempt was made to study the mechanism of the SHS process in TiAl synthesis. The composition of the sample was Ti-(45, 50, 53)at% Al and the microstuctures of the products were analyzed using optical microscope and scanning electron microscope. When the phases formed at the main SHS reaction of whicyh combustion temperature is higher than the melting temperature of aluminum were identified as TiAl and Ti$_3$Al ; Ti$_3$Al cores surrounded by TiAl phase. In order to increase the combustion temperature, carbon was added 5 and 10at.%. When the carbon content was 10at.%, the heat of the reaction was large enough to melt the phase formed and that is consistent with the theoretical calculation results of the adiabatic temperature. The combution temperatue, which was measured by a computer data acquisition system, increased with the carbon content. The phases formed from the reaction involving the carbon added were indentified as TiAl and Ti$_2$AlC using XRD. The vickers hardness of the reaction product increased with the carbon content.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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• pp.149-156
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• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• 한국추진공학회지
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• 제22권6호
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• pp.72-83
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• 2018

본 연구에서는 단일 전단 동축 분사기를 이용한 수소 로켓 연소기의 전산유체 해석을 수행하였다. 2차원 축대칭 형상에서 난류연소 해석을 위해 hybrid RANS/LES 난류모델을 적용하였다. 적합한 해석기법을 찾기 위해 3가지 화학 반응기구, 3가지 고해상도 기법 및 3단계 격자해상도 조합을 비교하였다. 벽면 열유속을 실험결과와 비교하여 해석 성능을 살펴보았으며, 유동장 결과 분석으로 동축 분사기를 가지는 로켓 연소기의 난류연소특성을 살펴볼 수 있었다.