• Journal of the Korean Society of Combustion
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• v.19 no.1
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• pp.39-44
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• 2014

A short reaction mechanism for premixed $CH_4/CHF_3/Air$ flames was developed with a reduction method of the combined application of simulation error minimization (SEM) which included connectivity method and principal component analysis. It consisted of 43 species and 403 elementary reactions at the condition of less than 5% of maximum error. The calculation time operated with a short mechanism was over 5 times faster than one with a detailed reaction mechanism. Good agreement was found between the flame speeds calculated by the short reaction mechanism and those by the detailed reaction mechanism for the entire range of $CHF_3/CH_4$ mole ratios and equivalence ratios. In addition excellent agreements were determined for the profiles of temperature, species concentration, and the production rates of the various species. So the short reaction mechanism was able to accurately predict the flame structure for premixed $CH_4/CHF_3/Air$ flames.

• Journal of the Korean Society of Combustion
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• v.12 no.1
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• pp.28-37
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• 2007

Numerical study is conducted to grasp the flame structure and NO emissions for a wide range of oxy-fuel combustion (covering from air blown combustion to pure oxygen combustion) and for various mole fractions of recirculated $CO_2$ in $CH4-O_2/N_2/CO_2$ counterflow diffusion flames. Special concern is given to the difference of the flame structure and NO emissions between air blown combustion and oxy-fuel combustion w/o recirculated $CO_2$ and is also focused on chemical effects of recirculated $CO_2$. Air blown combustion and oxy-fuel combustion w/o recirculated $CO_2$ are shown to be considerably different in the flame structure and NO emissions. Modified fuel oxidation reaction pathways in oxygen-enriched combustion are provided in detail compared to those in air blown combustion w/o recirculated $CO_2$. The formation and destruction of NO through Fenimore and thermal mechanisms are also compared for air blown combustion and oxyegn-enriched combustion w/o recirculated $CO_2$, and the role of the recirculated $CO_2$ and its chemical effects are discussed. Importantly contributing reaction steps to the formation and destruction of NO are also estimated in oxygen-enriched combustion in comparison to air blown combustion.

• Journal of the Korean Society of Combustion
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• v.4 no.1
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• pp.39-47
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• 1999

A combustion flame visualization system, which is used as an engine diagnostics tool, was developed in order to understand the combustion reaction mechanism in the development stage for S.I. engines. The measurement system consists of an I-CCD camera and a computer-aided image processing system. By using optically accessible engine system, the flame structure was analyzed from the acquired graylevel image and the direction of flame propagation (shape of flame) has been measured to understand combustion phenomena. And combustion radical which involves combustion information were measured. As a result, strong relation between combustion radicals intensity ratio and air excess ratio was found.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.251-255
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• 2015

Unsteady Shock-Induced Combustion has been studied for the past few decades since it is considered as one of the potential ways to reach supersonic flights. Experimental observations of Unsteady SIC were observed as early as 1960's. But Lehr was the first to report in detail the mechanisms of Shock-Induced Combustion experimentally. Numerical Studies on SIC were helpful in explaining the insight into the oscillatory behaviour in the mid 90's to early 2000's. Detailed reaction mechanisms is required to prediction the SIC flowfield more in detail. However at that time, very few reaction mechanisms on hydrogen-oxidation were reported. In the last decade, various number of hydrogen reaction mechanisms were reported. In this study, an attempt has been made to analyze the effect of various reaction mechanisms in an unsteady mode of Shock-Induced Combustion.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.92-95
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• 2011

A multi-step quasi-global mechanism is developed for the kerosene/oxygen combustion analysis including dissociation products. Reaction constants of the global reaction are determined to have agreement with experimental data. The mechanism is used for the numerical analysis of the combustion flow field of the kerosene/oxygen shear coaxial injector. The results from high-resolution numerical analysis confirmed qualitatively that the recess enhance the fuel/air mixing and combustion efficiency by the increased flow instabilities.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.77-78
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• 2011

A multi-step quasi-global mechanism is developed for the kerosene/oxygen combustion analysis including dissociation products. Reaction constants of the global reaction are determined to have agreement with experimental data. The mechanism is used for the numerical analysis of the combustion flow field of the kerosene/oxygen shear coaxial injector. The results from high-resolution numerical analysis confirmed qualitatively that the recess enhance the fuel/air mixing and combustion efficiency by the increased flow instabilities.

• Journal of ILASS-Korea
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• v.16 no.3
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• pp.126-133
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• 2011

In HCCI Engine, combustion is affected by change of compression speed corresponding to engine speed. The purpose of this study is to investigate the mechanism of influence of engine speed on HCCI combustion characteristics by using numerical analysis. At first, the influence of engine speed was shown. And then, in order to clarify the mechanism of influence of engine speed, results of kinetics computations were analyzed to investigate the elementary reaction path for heat release at transient temperatures by using contribution matrix. In results, as engine speed increased, in-cylinder gas temperature and pressure at ignition start increased. And ignition start timing was retarded and combustion duration was lengthened on crank angle basis. On time basis, ignition start timing was advanced and combustion duration was shortened. High engine speed showed higher robustness to change of initial temperature than low engine speed. Because of its high robustness, selecting high engine speed was efficient for keeping stable operation in real engine which include variation of initial temperature by various factors. The variation of engine speed did not change the reaction path. But, as engine speed increased, the temperature that each elementary reaction would be active became high and reaction speed quicken. Rising the in-cylinder gas temperature of combustion start was caused by these gaps of temperature.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.4
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• pp.64-71
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• 2011

Homogeneous charge compression ignition (HCCI) was the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process was mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, detailed kinetic reaction mechanisms of diesel surrogate was investigated to understand the diesel HCCI engine combustion. It was tested two existing mechanisms and two new mechanisms for the comparison of experimental result. The best mechanism for diesel surrogate was suggested through this comparison.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.38-41
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• 2001

The combustion characteristics of the disilicides molybdenum system have been studied experimentally. The pertinent reaction parameters that control self-propagating high temperature synthesis reactions have been examined. These include reactant particle size, powder mixing and compaction, reaction stoichiometry, diluents. The influence of experimental variables on integrity, uniformity, structure, and related material properties will be discussed. Formation mechanism of $MoSi_2$ during SHS might be different and depending on experimental conditions.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.38-41
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• 2001

The combustion characteristics of the disilicides molybdenum system have been studied experimentally. The pertinent reaction parameters that control self-propagating high temperature synthesis reactions have been examined. These include reactant particle size, powder mixing and compaction, reaction stoichiometry, diluents. The inf1uence of experimental variables on integrity, uniformity, structure, and related material properties will be discussed. Formation mechanism of MoSi$_2$ during SHS might be different and depending on experimental conditions.